Submicron scale imaging of soil organic matter dynamics using NanoSIMS - From single particles to intact aggregates

The specific features of the nano-scale secondary ion mass spectrometry (NanoSIMS) technology with the simultaneous analysis of up to seven ion species with high mass and lateral resolution enables us to perform multi-element and stable isotope measurements at the submicron scale. To elucidate the power of this technique, we performed an incubation experiment with soil particles of the fine silt and clay fractions (from an Albic Luvisol), with occluded particulate organic material and intact soil aggregates (from a Haplic Chernozem), using a ¹³C and ¹⁵N labelled amino acid mixture as tracer. Before and during 6-day incubation after the addition of the label, samples were consecutively prepared for NanoSIMS analysis. For this purpose, two different sample preparation techniques were developed: (i) wet deposition and (ii) the sectioning of epoxy resin embedded samples. Single soil particles (fine silt/clay fraction) showed an enrichment of ¹³C and ¹⁵N after label addition that decreased over time. On aggregates of particulate organic matter, re-aggregated during the 6-day incubation experiment, we could show a spatially heterogeneous enrichment of ¹³C and ¹⁵N on the particle surface. The enrichment in ¹⁵N demonstrated the diffusion of dissolved organic matter into intact soil aggregate interiors. The prospects of NanoSIMS for three dimensional studies of stable C and N isotopes in organo-mineral associations is demonstrated by the recorded depth profiles of the organic matter distribution on mineral particles.     

Projected changes in tropical cyclone climatology and landfall in the Southwest Indian Ocean region under enhanced anthropogenic forcing

The conformal-cubic atmospheric model, a variable-resolution global model, is applied at high spatial resolution to perform simulations of present-day and future climate over southern Africa and over the Southwest Indian Ocean. The model is forced with the bias-corrected sea-surface temperatures and sea-ice of six coupled global climate models that contributed to Assessment Report 4 of the Intergovernmental Panel on Climate Change. All six simulations are for the period 1961–2100, under the A2 emission scenario. Projections for the latter part of the 21st century indicate a decrease in the occurrence of tropical cyclones over the Southwest Indian Ocean adjacent to southern Africa, as well as a northward shift in the preferred landfall position of these systems over the southern African subcontinent. A concurrent increase in January to March rainfall is projected for northern Mozambique and southern Tanzania, with decreases projected further south over semi-arid areas such as the Limpopo River Basin where these systems make an important contribution as main cause of widespread heavy rainfall. It is shown that the projected changes in tropical cyclone attributes and regional rainfall occur in relation to changes in larger scale atmospheric temperature, pressure and wind profiles of the southern African region and adjacent oceans.     

Marine connections in North America during the late Maastrichtian: palaeogeographic and palaeobiogeographic significance ofJeletzkytes nebrascensisZone cephalopod fauna from the Elk Butte Member of the Pierre Shale, SE South Dakota and NE Nebraska

The Elk Butte Member of the Pierre Shale of southeast South Dakota and northeast Nebraska yields a late Maastrichtian cephalopod fauna of nautiloids, belemnites and ammonites of theFeletzkytes nebrascensisZone, best known from the near-shore facies of the Fox Hills Formation. ThenebrascensisZone is the highest distinct marine assemblage that can be recognised in the Western Interior, although ammonites occur as rarities high in the Lance Formation in Wyoming. Elements of the fauna occur in the Gulf Coast and Atlantic Seaboard, and extend into the highest Maastrichtian nannofossil Subzone CC26b, ofMicula prinsii, in Texas. These occurrences point to the existence of a southerly marine route for migration into and out of the northern Interior during the late late Maastrichtian. An analysis of Maastrichtian ammonite occurrences in West Greenland reveals no evidence for a marine link to the western Interior at this time, but rather indicates an open marine link to the North Atlantic region.The presence of upper upper Maastrichtian Pierre Shale in southeast South Dakota and northeast Nebraska, deposited in water depths that are conservatively estimated at 100-200 m, suggests that marine conditions (evidence for which has been removed by post-Cretceous erosion) may have extended well to the north of the shoreline position indicated in recent palaeogeographic reconstructions.     

Energy use, climate change and folk psychology: Does sustainability have a chance? Results from a qualitative study in five European countries

Citizens’ support for policies that aim to curb carbon emissions and energy use is often seen as informed by their values, attitudes and perceptions of the environmental problem in question. We argue that we also need to understand how people conceptualise policies and the governance approaches underpinning them to be able to judge the likely acceptance of policy change.In this study, we draw on qualitative interviews (n = 202) from five European countries to explore citizens’ views on governance approaches to stimulate behavioural change in the field of resource use, including regulations, price changes, collective action, technological change and education.We found that many of our interviewees referred to generalised characteristics of humankind and contemporary society to back up their arguments for or against specific governance approaches. In particular, many interviewees concurred that people in general were so self-centred, driven by habit and money- and consumption-oriented that only strict regulations, drastic price changes and technological innovation could possibly achieve widespread behavioural change. As a consequence, such ‘folk psychologies’ can have substantial impact not only on public acceptance, but also on the success of policy measures that aim to reduce citizens’ resource use.     

An exploration of potential raw materials for prehistoric pottery production in the Tao River Valley,Gansu Province,China

Northwest China is known for its Majiayao-style Neolithic painted pottery which has received much praise for its high level of craftsmanship, yet its chain of production, in particular the step of raw material selection, is still poorly understood. To fill this lacuna, the present study explores the raw materials used in producing these wares from a geological and technological perspective. At its core stands the first geoarchaeological survey conducted around the eponymous site of Majiayao which collected 47 samples of raw materials suitable for ceramic production including clay, loess and rocks, which were all analysed macroscopically. A selection was analysed using thin-section petrography, and a subset of the clay and loess samples were subjected to firing experiments. Additionally, three clay samples were analysed by scanning electron microscope with energy-dispersive X-ray spectrometer to understand their composition and behaviour in ceramic production. These were then compared to archaeological ceramics, thus providing insights into raw-material availability and selection that will be of importance not only for research on Majiayao-style pottery but also for later-period ceramics produced in the area. This research shows how an archaeologically informed geological survey can contribute insights into human–environment interaction in early pottery production, especially the interplay between raw-material availability, technological know-how and potters' choices.     

Additional measurements of the high-latitude sunspot rotation rate

We report measurements of the sunspot rotation rate at high sunspot latitutdes for the years 1966–1968. Ten spots at ¦latitude¦ 28 deg were found in our Mees Solar Observatory H patrol records for this period that are suitable for such a study. On the average we find a sidereal rotation rate of 13.70 ± 0.07 deg day^-1 at 31.05 ± 0.01 deg. This result is essentially the same as that obtained by Tang (1980) for the succeeding solar cycle, and significantly larger than Newton and Nunn's (1951) results for the 1934–1944 cycle. Taken together, the full set of measurements in this latitude regime yield a rotation rate in excellent agreement with the result =14^°.37₇–2^°.77 sin², derived by Newton and Nunn from recurrent spots predominatly at lower latitudes throughout the six cycles from 1878–1944.Summer Research Assistant.     

Identification of mid-latitudinal regional and urban temperature variabilities based on regional reanalysis data

The objective of the study is to detect geographical and temporal variations of near surface air temperatures over Minnesota and Wisconsin, USA derived from the North American Regional Reanalysis (NARR) dataset. In addition, the study serves to assess the usefulness of NARR temperature data to analyze regional and local temperature variations. Particular emphasis was placed on the analyses on the temperature-modifying effects of the Great Lakes and large urban environments. We analyzed annual mean, daily maximum and minimum, and January minimum and July maximum temperatures for the period 1979–2006 by using methods such as ordinary kriging, principal component analysis, and the Mann–Kendall test. On a regional scale, we found significant effects of the latitude and the Great Lakes on the spatial variability of the data. Furthermore, we found clearly identifiable effects of large urban areas in the study region (Minneapolis—Saint Paul and Milwaukee), which are more evident in the principal component scores than in the temperature data themselves. While we failed to detect significant July maximum temperature trends, we detected significantly increasing trends in January minimum and mean annual temperature datasets in the eastern part of the region. Overall, the present study has demonstrated the potential of using NARR data for urban climate research.     

Differential aerobic and anaerobic oxidation of hydrocarbon gases discharged at mud volcanoes in the Nile deep-sea fan

The present study investigates hydrocarbon oxidation processes at Isis and Amon mud volcanoes (MV’s), in the eastern Nile deep-sea fan. In the water column, molecular and carbon isotopic signatures of light hydrocarbons indicate that gases rapidly dissolve in seawater and are partially oxidized.In the upper sediments, anaerobic oxidation of the light hydrocarbons takes place, as clearly shown by their molecular and isotopic composition. These processes lead to the presence of a distinct Sulfate-Hydrocarbon Interface at 120-145 cm and 20-50 cm below the seafloor, for Isis and Amon MV’s, respectively. In contrast to processes occurring in the water column, a clear preferential oxidation of methane, propane and n-butane over ethane and i-butane is observed in the anoxic sediments. Furthermore, for the first time, fractionation factors have been determined for the anaerobic oxidation of propane and butane, being respectively −4.80‰ and −0.7‰ for δ¹³C, and −43.3‰ for δ²H of propane.