WATEQB – BASICA REVISION OF WATEQF FOR IBM PERSONAL COMPUTERS

Abstract. WATEQB is a BASICA revision for IBM PC of WATEQF, a geochemical model for chemical equilibrium and saturation of natural waters. This model computes the speciation of inorganic ions and complex species in solution for a given water analysis.
WATEQB is identical to the FORTRAN IV version from the standpoint of chemical process; however, the structure of the program differs from the original version. The structure of the program is not complex and allows the user to try some new modifications, if necessary.
Due to the limited memory of personal computers and in contrast to the large volume of the original version of the program, the author has created four data files, one of which is of random access type. Reading the thermochemical data is possible through these four data files.
This paper demonstrates how to set up the input data to execute WATEQB and describes the program rather than the model. The users of WATEQB will increase as personal computers become more common.     

Occurrence of Phthalates in Sewage Sludge from Three Wastewater Treatment Plants in Istanbul,Turkey

Phthalates are considered priority pollutants because of their potential adverse effects on ecosystems and human health. The objectives of this study were to determine the occurrence of five phthalates (DMP, DEP, DBP, BBP, and DEHP) in sewage sludge and to determine the seasonal variability of these contaminants at three (Bahçe?ehir, Pa?aköy, and Tuzla) full‐scale municipal and domestic wastewater treatment plants (WWTP) in Istanbul, Turkey. Mass balance was also calculated for DEHP at Tuzla WWTP sludge treatment units. DMP, DEP, DBP, BBP, and DEHP concentrations in sewage sludge ranged from 1.4 to 2.7 mg/kg dry weight (dw), 1.1 to 2.8, 0.6 to 4.6, 2.8 to 6.2, 18 to 490 mg/kg dw, respectively. Phthalate concentrations from the Bahçe?ehir and Pa?aköy WWTPs met the limit (100 mg/kg dw) of Turkey national sludge regulation and the Europe Union draft of sludge directive for land application, whereas phthalate concentrations from Tuzla WWTP exceeded the maximum permissible concentration. Phthalate concentrations did not show seasonal variations for Bahçe?ehir and Pa?aköy WWTPs, which receive mainly household wastewater while some fluctuations were observed DEP, DBP, and DEHP at Tuzla WWTP which has a lot of industrial wastewater contribution. The mass balance showed that approximately 17% of DEHP in the primary and secondary sludge was removed by anaerobic digestion, while 43% returned back to the beginning of the WWTP and 40% remained in the dewatered sludge. This study suggests that phthalates in sludge from WWTPs with industrial wastewater contribution may limit the use of sludge for land application.     

Comparative Assessment of Sludge Pre‐Treatment Techniques to Enhance Sludge Dewaterability and Biogas Production

Effectiveness of ultrasonication, microwave technologies, and enzyme addition prior to anaerobic digestion is investigated using sludge samples taken from the secondary settling tank of a domestic wastewater treatment plant to improve methane production, enhance dewaterability characteristics of the sludge, and to reduce excess sludge. Microwave pre‐treatment (1500 W, 10 min at 175 °C) results in better extra digester performance (compared to the control reactor) in terms of methane production (25 m³ ton^?1 suspended solids (SS)) than ultrasound (no improvement) and enzyme pre‐treatment (11 m³ ton^?1 SS). While methane production is not improved as a result of ultrasonication pre‐treatment (15 000 kJ kg^?1 SS), a noticeable increase (19%) is observed in the case of microwave pre‐treatment. Higher compactibility values are obtained after ultrasonication and microwave application compared to the control (i.e., from 7.1 to 8.7 and 9.2%, respectively) before anaerobic digestion. Although ultrasonication and microwave application decrease the dewaterability of the raw sludge (capillary suction time (CST) from 827 to 1364 and 2290 s, respectively), similar dewaterability results are obtained at the end of the anaerobic digestion process for all pre‐treated sludge samples. An economic assessment of this study shows that pre‐treatment with microwave results in more than 10‐fold less net cost compared to the enzyme application.     

A GIS model for settlement suitability regarding disaster mitigation, a case study in Bolu Turkey

A GIS (Geographic Information Systems) model was developed for Bolu Province in Turkey primarily for earthquake disaster mitigation purposes. The model served as the basis for investigating earthquake disaster vulnerability of existing settlements and identifying areas for new settlements in the Bolu Provincial Center and its counties. The set of criteria investigated in the GIS model was the following: distance from the main fault, ground acceleration, geologic basement type and terrain slope. Based on these criteria, a settlement suitability map was created, which classified the province into low, medium and high settlement suitable areas. This map was then augmented with other criteria for refinement purposes. These included the land use capability classes map of the province, the contemporary land use map derived from satellite images and the historical and contemporary earthquake occurrences within the region. Finally, the road network of the province derived from satellite images was overlaid on the settlement suitability map so that the provincial administrators could leave an evacuation zone of 200 m around the roads. This settlement suitability map is also intended to assist provincial administrators in making plans for reinforcement of existing settlements in low settlement suitable regions and opening new areas for urbanization and industrialization in high settlement suitable regions.     

Geotechnical assessments of the stability of slopes at the Cakmakkaya and Damar open pit mines (Turkey): a case study

The on-site observations, monitoring data, and results of back analyses of failures showed that large-scale failures occurred along both the interconnected sliding surfaces, consisting of (a) discontinuities in the dacites and the contact zone and (b) the circular surfaces through the weathered soil-like dacites at the Cakmakkaya and Damar open pit mines. Surface water infiltration through the weathered soil-like material after a short duration of rainfall contributed to the circular-shaped failures. After a heavy rainy period, an increase in the groundwater table above the contact zone played a major role in the initiation of bi-planar wedge failures. In addition, the stability of the slopes is likely to have been controlled by the orientation of this zone. The results of back analyses indicated that the shear strengths of the soil-like materials in the weathered dacites and the contact zone had reduced to their residual values at the time of initial sliding. The flattening of the slope angles with an effective surface drainage and long-term monitoring of the groundwater level is proposed as the most suitable remedial measure.