Atomistic simulation of the mechanisms of noble gas incorporation in minerals

Atomistic simulations have been carried out to investigate the mechanisms of noble gas incorporation in minerals using both the traditional two-region approach and the “supercell” method. The traditional two-region approach has been used to calculate defect energies for Ne, Ar, Kr and Xe incorporation in MgO, CaO, diopside and forsterite in the static limit and at one atmosphere pressure. The possibilities of noble gas incorporation via both substitution and interstitial mechanisms are studied. The favored mechanism varies from mineral to mineral and from noble gas to noble gas. In all minerals studied, the variation of the solution energies of noble gas substitution with atomic radius appears approximately parabolic, analogous to those for 1⁺, 2⁺, 3⁺ and 4⁺ trace element incorporation on crystal lattice sites. Noble gas solution energies thus also fall on a curve, similar to those previously observed for cations with different charges, but with much lower curvature.The “supercell” method has been used to investigate the pressure dependence of noble gas incorporation in the same systems. Results indicate a large variation of the solubility of the larger noble gases, Kr and Xe with pressure. In addition, explicit simulation of incorporation at the (0 0 1) surface of MgO shows that the solubility of the heavier noble gases may be considerably enhanced by the presence of interfaces.     

Characterization and cycling of atmospheric mercury along the central US Gulf Coast

Concentrations of atmospheric Hg species, elemental Hg (Hg^°), reactive gaseous Hg (RGM), and fine particulate Hg (Hg-PM_2.5) were measured at a coastal site near Weeks Bay, Alabama from April to August, 2005 and January to May, 2006. Mean concentrations of the species were 1.6 ± 0.3 ng m⁻³, 4.0 ± 7.5 pg m⁻³ and 2.7 ± 3.4 pg m⁻³, respectively. A strong diel pattern was observed for RGM (midday maximum concentrations were up to 92.7 pg m⁻³), but not for Hg^° or Hg-PM_2.5. Elevated RGM concentrations (>25 pg m⁻³) in April and May of 2005 correlated with elevated average daytime O₃ concentrations (>55 ppbv) and high light intensity (>500 W m⁻²). These conditions generally corresponded with mixed continental-Gulf and exclusively continental air mass trajectories. Generally lower, but still elevated, RGM peaks observed in August, 2005 and January–March, 2006 correlated significantly (p < 0.05) with peaks in SO₂ concentration and corresponded to periods of high light intensity and lower average daytime O₃ concentrations. During these times air masses were dominated by trajectories that originated over the continent. Elevated RGM concentrations likely resulted from photochemical oxidation of Hg^° by atmospheric oxidants. This process may have been enhanced in and by the near-shore environment relative to inland sites. The marine boundary layer itself was not found to be a significant source of RGM.     

Instrument calibration of ocean bottom seismographs

To increase the accuracy of measuring sea floor motion with ocean bottom seismometers, we calibrate the seismometer system on the ocean floor. Data from the sea floor calibration, augmented with electronic and land calibration data, enables us to find the OBS transfer function to an accuracy of 0.5% in the frequency range of 0.1 to 32 Hz. We are able to distinguish between temperature, instrument and OBS ground coupling effects, all of which alter the transfer function. This paper reviews our method of calibration and discusses the effects of temperature and some of the instrument design features on the vertical seismometer transfer function.     

A dipole field model for axisymmetric alfvén waves with finite ionosphere conductivities

An axisymmetric model for approximate solution of the magnetospheric Alfvén wave problem at latitudes above the plasmapause is proposed, in which a realistic dipole geometry is combined with finite anisotropic ionosphere conductivities, thus bringing together various ideas of previous authors. It is confirmed that the axisymmetric toroidal and poloidal modes interact via the ionospheric Hall effect, and an approximate method of solution is suggested using previously derived closed solutions of the uncoupled wave equations.A solution for zero Hall conductivity is obtained, which consists of sets of independent shell oscillations, regardless of the magnitude of the Pedersen conductivity. One set reduces to the classical solutions for infinite Pedersen conductivity, while another predicts a new set of harmonics of a quarter-wave fundamental, with longer eigenperiods than the classical solutions for a given L-shell.     

Enacting geographies

We conclude the editorial by glancing ahead to the individual papers. This overview seeks only to highlight motifs, themes, arcs and trajectories (since the papers will obviously exceed anything we might say about them).John Wylie's paper, An essay on ascending Glastonbury Tor, draws upon the work of Merleau Ponty and Heidegger to illustrate how the act of visualizing itself is always a making of seer and seen. The paper thus seeks to speak of a subjectivity produced and performed via practices of ascension and elevation, and, in doing so, to move towards a new understanding of visible landscape in terms of sensuous practices. Cataloguing his own ascent of Glastonbury Tor, Wylie seeks to enact the Tor for the reader, engendering its visibility, its cultural histories, and thus its sensuous reality through his narrative.Motifs of landscape and practice recur in Mitch Rose's paper, Landscape and Labyrinths, which seeks to sketch out a conceptual and methodological approach to cultural landscape beyond the structuralism of cultural geography, which, Rose argues, skewers landscape through stabilisations of meaning. An ontology of overdetermination and surplus, as elaborated by Althusser and Bataille, is offered by Rose as a possible means of becoming attentive to the excessiveness of landscape.Derek McCormack's A paper with an interest in rhythm moves from the false problematic of representing movement to become an exposition of movement within the folds of writing. In a virtuosic exploration of rhythm McCormack produces an animated space that moves, folds and achieves consistency via both non-subjectifying and subjectifying forces. Theoretical considerations are not side-stepped by this performance; rather, the particular rhythms of Deleuze, Guattari and Lefebvre are engaged and enfolded by the paper.Paul Harrison's paper The Caesura: Remarks on Wittgenstein's interruption of theory, or, why practices elude explanation, presents a precise and exacting philosophical exposition of the work of Ludwig Wittgenstein. Harrison uses the work of Wittgenstein to offer a diagnosis of idealism within much contemporary social analysis. Linking up with the special issue's concerns, Harrison suggests that it is the performative which occupies the space vacated by Idealism; a replacement of the Cartesian Ideals of certainty for 'infinitive', and distinctly geographic, understandings––taking -place, making -sense––which speak of the time of the present, not of all Time.