Prolonged postcollisional shoshonitic magmatism in the southern Svecofennian domain – a case study of the Åva granite–lamprophyre ring complex

The Åva ring complex is one of four Paleoproterozoic postcollisional shoshonitic ring complexes in southwestern Finland. It is composed of ring dykes of K-feldspar megacryst-bearing granite, mingled in places with a shoshonitic monzonite, and lamprophyre dykes crosscutting all the rocks in a radial pattern. A survey was undertaken to trace the magma chamber beneath the ring complex to date it and measure some intensive parameters to clarify the crystallisation conditions at depth before the granite was emplaced in the upper crust. Mineral separates were extracted from the core zones of K-feldspar megacrysts in the granite, heavy mineral fractions (including zircons) from these separates were used for P-T assessment and age determinations, and the results were compared to data obtained from bulk rock samples. It appears that magma differentiation took place in a midcrustal magma chamber (at 4 to 7 kbar) possibly 30 Ma before the emplacement of the ring complex in the upper crust (deep assemblage 1790 Ma, shallow assemblage 1760 Ma). Relatively high activity of the alkalies and a low oxygen fugacity characterised the midcrustal chamber. The juvenile Svecofennian crust was invaded by shoshonitic magmas from an enriched lithospheric mantle over a long period of time. Some of these magmas were stored and differentiated in the middle crust before transportation to the upper crust. The results also show that coarse-grained granites may provide evidence for several magmatic evolutionary episodes, e.g., differentiation and crystallisation in different environments prior to final emplacement.     

The role of aerosols and greenhouse gases in Sahel drought and recovery

Climatic Change - We exploit the multi-model ensemble produced by phase 5 of the Coupled Model Intercomparison Project (CMIP5) to synthesize current understanding of external forcing of Sahel...     

Authigenic rhodochrosite from a gas hydrate-bearing structure in Lake Baikal

International Journal of Earth Sciences - Early diagenetic carbonates are rare in Lake Baikal. Siderite (Fe carbonate) concretions in the sediments were discovered only recently. Here, we discuss...     

Model-based remote sensing algorithms for particulate organic carbon (POC) in the Northeastern Gulf of Mexico

Hydrographic data, including particulate organic carbon (POC) from the Northeastern Gulf of Mexico (NEGOM) study, were combined with remotely-sensed SeaWiFS data to estimate POC concentration using principal component analysis (PCA). The spectral radiance was extracted at each NEGOM station, digitized, and averaged. The mean value and spurious trends were removed from each spectrum. De-trended data included six wavelengths at 58 stations. The correlation between the weighting factors of the first six eigenvectors and POC concentration were applied using multiple linear regression. PCA algorithms based on the first three, four, and five modes accounted for 90, 95, and 98% of total variance and yielded significant correlations with POC with R ² = 0.89, 0.92, and 0.93. These full waveband approaches provided robust estimates of POC in various water types. Three different analyses (root mean square error, mean ratio and standard deviation) showed similar error estimates, and suggest that spectral variations in the modes defined by just the first four characteristic vectors are closely correlated with POC concentration, resulting in only negligible loss of spectral information from additional modes. The use of POC algorithms greatly increases the spatial and temporal resolution for interpreting POC cycling and can be extrapolated throughout and perhaps beyond the area of shipboard sampling.     

Reflected waves in finely layered tilted orthorhombic media

Upscaling in seismics is a homogenization of finely layered media in the zero-frequency limit. An upscaling technique for arbitrary anisotropic layers has been developed by Schoenberg and Muir. Applying this technique to a stack of layers of orthorhombic (ORT) symmetry whose vertical symmetry planes are aligned, results in an effective homogeneous layer with orthorhombic symmetry. If the symmetry planes in a horizontal orthorhombic layer are rotated with respect to vertical, the medium is referred to as tilted orthorhombic (TOR) medium, and the stack composed of TOR layers in zero-frequency limit will produce an effective medium of a lower symmetry than orthorhombic. We consider a P-wave that propagates through a stack of thin TOR layers, then it is reflected (preserving the mode) at some interface below the stack, and then propagates back through the same stack. We propose to use a special modified medium for the upscaling in case of this sequential down- and up-propagation: each TOR layer in the stack is replaced by two identical TOR layers whose tilt angles have the opposite algebraic sign. In this modified medium, one-way propagation of a seismic wave (any wave mode) is equivalent to propagation of a pure-mode reflection in the original medium. We apply this idea to study the contribution from an individual layer from the stack and show how the approach can be applied to a stack of TOR layers. To demonstrate the applicability of the model, we use well log data for the upscaling. The model we propose for the upscaling can be used in well-seismic ties to correct the effective parameters obtained from well log data for the presence of tilt, if latter is confirmed by additional measurements (for example, borehole imaging).     

Molecular and isotopic characteristics of gas hydrate-bound hydrocarbons in southern and central Lake Baikal

We investigated the molecular composition (methane, ethane, and propane) and stable isotope composition (methane and ethane) of hydrate-bound gas in sediments of Lake Baikal. Hydrate-bearing sediment cores were retrieved from eight gas seep sites, located in the southern and central Baikal basins. Empirical classification of the methane stable isotopes (δ¹³C and δD) for all the seep sites indicated the dominant microbial origin of methane via methyl-type fermentation; however, a mixture of thermogenic and microbial gases resulted in relatively high methane δ¹³C signatures at two sites where ethane δ¹³C indicated a typical thermogenic origin. At one of the sites in the southern Baikal basin, we found gas hydrates of enclathrated microbial ethane in which ¹³C and deuterium were both highly depleted (mean δ¹³C and δD of –61.6‰ V-PDB and –285.4‰ V-SMOW, respectively). To the best of our knowledge, this is the first report of C₂ δ¹³C–δD classification for hydrate-bound gas in either freshwater or marine environments.     

Remote sensing and surface POC concentration in the South Atlantic

Several SeaWiFS products have been compared with shipboard data to assess the possibility of using remote sensing to estimate particulate organic carbon (POC) concentration in surface waters. Transmissometer data were collected during six South Atlantic Ventilation Experiment (SAVE) hydrographic expeditions conducted between November 1987 and March 1989 from R/V Knorr, and Melville. A total of 361 beam attenuation profiles were made with a SeaTech transmissometer interfaced with a CTD/rosette. In order to calculate the POC concentration from transmissometer profiles, a regression between beam attenuation and POC for open Atlantic Ocean waters derived from our research in the North Atlantic (North Atlantic Bloom Experiment, NABE) and enhanced by data from the Bermuda Atlantic Time Series Station (BATS) was applied. The profiles were processed and examined as vertical sections of the surface 250 m. The data were collected in two successive years, during the same season, which allowed us to compile a combined data set over the austral summer for examination. Beam attenuation/POC concentrations were integrated down to one attenuation depth with the intent of making comparisons with satellite optical data. No satellite optical data were available for 1987–1989, so the only option was to compare our integrated data with SeaWiFS-derived variables from later years averaged over the same season as SAVE data. Analysis of four SeaWiFS products acquired from 1997 to 2002 demonstrated very low variations from year to year for seasonally averaged data, suggesting that making comparisons of the beam attenuation/POC fields with averaged satellite optical products from later years is a valid (though not optimal) approach for this area. The highest correlation between beam attenuation/POC concentration and remotely derived products was found with normalized water-leaving radiance at 555 nm. Other SeaWiFS-derived variables—chlorophyll concentration, diffuse attenuation coefficient at 490 nm and integral chlorophyll (integrated over one attenuation depth)—were also compared but showed a slightly less satisfactory correlation.     

Stability of phlogopite in ultrapotassic kimberlite-like systems at 5.5–7.5 GPa

Hydrous K-rich kimberlite-like systems are studied experimentally at 5.5–7.5 GPa and 1200–1450?°C in terms of phase relations and conditions for formation and stability of phlogopite. The starting samples are phlogopite–carbonatite–phlogopite sandwiches and harzburgite–carbonatite mixtures consisting of Ol?+?Grt?+?Cpx?+?L (±Opx), according to the previous experimental results obtained at the same P–T parameters but in water-free systems. Carbonatite is represented by a K- and Ca-rich composition that may form at the top of a slab. In the presence of carbonatitic melt, phlogopite can partly melt in a peritectic reaction at 5.5 GPa and 1200–1350?°C, as well as at 6.3–7.0 GPa and 1200?°C: 2Phl?+?CaCO₃ (L)?Cpx?+?Ol?+?Grt?+?K₂CO₃ (L)?+?2H₂O (L). Synthesis of phlogopite at 5.5 GPa and 1200–1350?°C, with an initial mixture of H₂O-bearing harzburgite and carbonatite, demonstrates experimentally that equilibrium in this reaction can be shifted from right to left. Therefore, phlogopite can equilibrate with ultrapotassic carbonate–silicate melts in a?≥?150?°C region between 1200 and 1350?°C at 5.5 GPa. On the other hand, it can exist but cannot nucleate spontaneously and crystallize in the presence of such melts in quite a large pressure range in experiments at 6.3–7.0 GPa and 1200?°C. Thus, phlogopite can result from metasomatism of peridotite at the base of continental lithospheric mantle (CLM) by ultrapotassic carbonatite agents at depths shallower than 180–195 km, which creates a mechanism of water retaining in CLM. Kimberlite formation can begin at 5.5 GPa and 1350?°C in a phlogopite-bearing peridotite source generating a hydrous carbonate–silicate melt with 10–15 wt% SiO₂, Ca# from 45 to 60, and high K enrichment. Upon further heating to 1450?°C due to the effect of a mantle plume at the CLM base, phlogopite disappears and a kimberlite-like melt forms with SiO₂ to 20 wt% and Ca#?=?35–40.     

Plio-Pleistocene geological record and small mammal faunas, eastern shore of the Azov Sea, Southern European Russia

The shoreline of the Taganrog Gulf of the Azov Sea at the mouth of Don River provides a series of extended Upper Pliocene and Quaternary sections that have been actively studied in the last century. This extraglacial region had a complex sedimentary history combining subaerial aggradation with marine, fluvial, and deltaic sedimentation. The well-exposed stratigraphical sequence and abundant palaeontological record continuously attract geologists and highlight the region as one of international importance for the addressing of numerous problems of Late Pliocene and Quaternary stratigraphy and palaeogeography. Fossil mammalian faunas of the region include important Eurasian biostratigraphical markers such as Stenocranius ex gr. hintoni-gregaloides, Lagurini spp., and Mimomys savini. For many years, fossil remains of mammals provide decisive clues to the geological history of the region. Recent geological studies of reference sections have provided data on small mammals, palaeomagnetism and palaeogeographical reconstructions in the northeastern part of the Azovian Region. Mammalian assemblages indicate the presence of the Late Pliocene, late Early Pleistocene, Middle Pleistocene and Late Pleistocene levels and, in addition, provide a clear biostratigraphical context for the Early Middle Pleistocene transition.