Organic Acid Derivatization Techniques Applied to Petroleum Hydrocarbon Transformations in Subsurface Environments

Evidence for the natural microbial remediation of subsurface fuel contamination situations should include identification and analysis of transformation or degradation products. In this way. u mass balance between fuel constituents and end products may be approached to monitor cleanup progress. Application of advanced organic acid metabolite derivatization techniques to several known sites of organic compounds and fuel mixture contamination provide valuable information on the pathways and progress of microbial transformation. Good correlation between observed metabolites and transformation pathways of aromatic fuel constituents were observed at the sites.     

Gypsum-organic interactions in natural seawater: Effect of organics on precipitation kinetics and crystal morphology

Organic compounds which are chloroform extractible from seawater affect gypsum precipitation by inhibiting the nucleation of crystals. The effect is selective towards calcium-populated crystal habit faces and results in the growth of more tabular, equidimensional crystals. Studies using model organic compounds suggest that the inhibition takes place through an adsorption mechanism and show that longer-chained n-fatty acids are more actively adsorbed. The specific adsorption mechanism (at Ca²⁺ habit faces) is also supported by the fact that the free-acid (base-soluble) fraction of the chloroform extractibles from seawater is more active than the neutral fraction. The calcium ion complexing ability of model organic compounds is not correlatable with their inhibitory effects on gypsum crystal nucleation.     

Atlas of susceptibility to pollution in marinas. Application to the Spanish coast

An atlas of susceptibility to pollution of 320 Spanish marinas is provided. Susceptibility is assessed through a simple, fast and low cost empirical method estimating the flushing capacity of marinas. The Complexity Tidal Range Index (CTRI) was selected among eleven empirical methods. The CTRI method was selected by means of statistical analyses because: it contributes to explain the system's variance; it is highly correlated to numerical model results; and, it is sensitive to marinas' location and typology. The process of implementation to the Spanish coast confirmed its usefulness, versatility and adaptability as a tool for the environmental management of marinas worldwide. The atlas of susceptibility, assessed through CTRI values, is an appropriate instrument to prioritize environmental and planning strategies at a regional scale.     

Exploration for iron ore in Agbado-Okudu,Kogi State,Nigeria

This report details the result of geophysical exploration for iron ore; which involved vertical magnetic intensity (?Z) and gravity measurements, to delineate the geometry and depth extent of the deposit and acquiring quantitative and qualitative information for pre-drilling purposes in Agbado-Okudu. It is located about 3 km from Jakura along Lokoja-Jakura marble quarry and within low latitude precambrian basement complex district of Kogi State, Nigeria. A total of 517 magnetic measurement points along 16 traverses and 330 gravity reading along 11 profiles on the deposit in northeast–southwest azimuth were undertaken. The magnetic and gravity data enhancement involved linear regression curve fitting and fast Fourier transform, which were used to construct residual magnetic (RM) and gravity (RG) anomalies, analytic signal amplitude, Euler deconvolution at varying spectral indices (SI), power spectrum, and source parameter image (SPI), using the submenu of Geosoft Oasis Montaj software. Interpretation of the RM and RG anomalies revealed a primary causative body which perfectly correlates the positive anomalies and iron ore deposit, in form of a horizontal or gently dipping dyke with strike length of 600 m and average width of 110–130 m, within the gneiss complex in the north and trending south of the area. A secondary causative body associated with the negative anomalies and inferred as a vertical/near vertical thin sheet striking northeast–southwest coincided with the granitic and quartzitic intrusion. The NW–SE and E–W lineament trend conformed Kibarian and Liberian orogeny cycles of generally known structural trends in Nigeria, which shows that the iron ore deposit is structurally controlled. Depths to sources were estimated within range ≤ 2–24 m and 37.5–60 m, regarded as shallow and relatively deep depths, respectively. Ten vertical boreholes ranging in depth between 50 and 100 m are recommended, five of which require a priority attention to ascertain the thickness of the primary causative body.     

MC-ICP-MS高精度测定Li同位素分析方法

以不同浓度Li元素标准样品和K、Ca、Na、Mg、Fe单元素标准样品的混合溶液为研究对象,采用3根阳离子交换树脂（AG 50W X8,200~400目）填充的聚丙烯交换柱和石英交换柱对Li进行分离富集,淋洗液分别为28 mol/L HCl、015 mol/L HCl以及05 mol/L HCl 30%乙醇,淋洗液体积小,仅为38 mL。分离回收率高,均大于976%。国际标样AGV 2（相对于IRMM 016）、BHVO 2（相对于IRMM 016）和IRMM 016（相对于L SVEC）的δ7Li值分别为(513±094)‰(2σ,n=10)、(408±060)‰(2σ,n=4)和(0038±073)‰(2σ,n=10),与前人分析结果吻合,分析精度与国际同类实验室水平相当。并对比了马里兰大学同位素实验室和笔者实验室对同种岩石矿物样品的分析结果,在误差范围内具有很好的一致性。此外,对美国地质调查局提供的准标样NKT 1霞石岩（相对于IRMM 016）给出了定值,δ7Li值为(871±046)‰(2σ,n=4)。因此,本方法可用于测定天然样品的Li同位素组成。