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In the Rhode River estuarine/watershed area, increased acidity of precipitation from atmospheric acidic deposition has deleterious effects on the freshwater ecosystems. One of the characteristics of an acidic watershed is the mobilization of aluminum from soils to aquatic environment. Increased concentrations of aluminum in surface waters are toxic to living organisms. Detection of long-term changes of acidity and elevated Al concentrations in surface and soil waters is a central issue. In this present paper, the dynamics ofAl speciation in the shallow ground waters from Rhode River watershed 110 (la) were investigated. This research provides a unique, regional analysis of important controls on the transport of Al speciation through the rural watershed of the Chesapeake Bay. 相似文献
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基于质量守恒以及电中性条件,采用化学平衡计算法,计算模拟研究了高岭石固相平衡的酸性天然地表水中铝的缓冲作用对pH值,酸中和容量ANC和缓冲强度β的影响,讨论了影响酸性地表水pH估算的各种因素,如溶解硅酸的浓度,溶解总无机碳的浓度,溶解总氟和总有机碳的浓度及温度等。模型被用于实际水样的分析,所得结果与实验值符合较好,用MonteCarlo模拟考察了由于平衡常数的选择以及水化学参数测量误差而带来的不确 相似文献
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Application of the adsorptive stripping voltammetry using DAS A (1, 2-dihydroxy an-thraquinoine-3-sulfonic acid) in the buffer solution of triethanolamine (pH 7.6) to determine the ionic forms of aluminum in fresh waters were presented in this paper. No serious interferences from Zn, Fe, Cl and V were found. Small amounts of Ca enhanced the analytical signal. Electroactive or ionic aluminum concentrations in fresh waters sampled both from China and USA was analysed. 相似文献
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