High-sensitive measurement of uranium LIII-edge X-ray absorption near-edge structure (XANES) for the determination of the oxidation states of uranium in crustal materials

The uranium L_III-edge XANES spectra for natural rocks at the concentration range of 0.96–124 mg kg⁻¹ were measured using a log spiral bent crystal Laue analyzer (BCLA) combined with a multi-element Ge detector. It was found that the quality of the XANES spectra using the BCLA was greatly improved due to a reduction of interfering fluorescence from major components such as Rb and Sr. The ratio of signal to background intensities in the U L_III-edge XANES spectra increased by a factor of 2.9–17 with the use of the BCLA, which greatly enhanced the detection limit for the speciation of the oxidation states of U or the U(IV)/U(VI) ratio of natural samples. In addition, it was demonstrated that the fluorescence XANES method coupled with the BCLA enable determination of the speciation of U for various natural samples such as acidic igneous rocks, ferromanganese nodules, sediments, and some sedimentary rocks such as shale and limestone.     

The Role of History-Dependent Rheology in Plate Boundary Lubrication for Generating One-Sided Subduction

We have developed a two-dimensional dynamical model of asymmetric subduction integrated into the mantle convection without imposed plate velocities. In this model we consider that weak oceanic crust behaves as a lubricator on the thrust fault at the plate boundary. We introduce a rheological layer that depends on the history of the past fracture to simulate the effect of the oceanic crust. The thickness of this layer is set to be as thin as the Earth's oceanic crust. To treat 1-kilometer scale structure at the plate boundary in the 1000-kilometer scale mantle convection calculation, we introduce a new numerical method to solve the hydrodynamic equations using a couple of uniform and nonuniform grids of control volumes. Using our developed models, we have systematically investigated effects of basic rheological parameters that determine the deformation strength of the lithosphere and the oceanic crust on the development of the subducted slab, with a focus on the plate motion controlling mechanism. In our model the plate subduction is produced when the friction coefficient (0.004–0.008) of the modeled oceanic crust and the maximum strength (400 MPa) of the lithosphere are in plausible range inferred from the observations on the plate driving forces and the plate deformation, and the rheology experiments. In this range of the plate strength, yielding induces the plate bending. In this case the speed of plate motion is controlled more by viscosity layering of the underlying mantle than by the plate strength. To examine the setting of the overriding plate, we also consider the two end-member cases in which the overriding plate is fixed or freely-movable. In the case of the freely-movable overriding plate, the trench motion considerably changes the dip angle of the deep slab. Especially in the case with a shallow-angle plate boundary, retrograde slab motion occurs to generate a shallow-angle deep slab.     

High-resolution observations of dissolved isoprene in surface seawater in the Southern Ocean during austral summer 2010–2011

We measured dissolved isoprene (2-methyl-1,3-butadiene; C₅H₈) concentrations in a broad area of the southern Indian Ocean and in the Indian sector of the Southern Ocean from 35°S to 64°S and from 37°E to 111°E during austral summer 2010–2011. Isoprene concentrations were continuously measured by use of a proton-transfer-reaction mass spectrometer combined with a bubbling-type equilibrator. Concentrations of isoprene and its emission flux throughout the study period ranged from 0.2 to 395 pmol L^?1 and from 181 to 313 nmol m^?2 day^?1, respectively, the averages being generally higher than those of previous studies. Although we found a significant linear positive relationship between isoprene and chlorophyll-a concentrations (r ² = 0.37, n = 36, P < 0.001), the correlation coefficient was lower than previously reported. In contrast, in the high-latitude area (>53°S) we identified a significant negative correlation (r ² = 0.59, n = 1263, P < 0.001) between isoprene and the temperature-normalized partial pressure of carbon dioxide (n-pCO₂), used as an indicator of net community production in this study. This suggests that residence times and factors controlling variations in isoprene and n-pCO₂ are similar within a physically stable water column.     

Interactive visualization of 3D mantle convection

The current availability of thousands of processors at many high performance computing centers has made it feasible to carry out, in near real time, interactive visualization of 3D mantle convection temperature fields, using grid configurations having 10–100 million unknowns. We will describe the technical details involved in carrying out this endeavor, using the facilities available at the Laboratory of Computational Science and Engineering (LCSE) at the University of Minnesota. These technical details involve the modification of a parallel mantle convection program, ACuTEMan; the usage of client–server socket based programs to transfer upwards of a terabyte of time series scientific model data using a local network; a rendering system containing multiple nodes; a high resolution PowerWall display, and the interactive visualization software, DSCVR. We have found that working in an interactive visualizastion mode allows for fast and efficient analysis of mantle convection results. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Influences of channelization on discharge of suspended sediment and wetland vegetation in Kushiro Marsh, northern Japan

The effects of wetlands on hydrology, water quality, and wildlife habitat are internationally recognized. Protecting the remaining wetlands is one of the most important environmental issues in many countries. However wetlands in Japan have been gradually shrinking due to agricultural development and urbanization, which generally lowers the groundwater level and introduces suspended sediment and sediment-associated nutrients into wetlands. We examined the influences of channelization on discharge of suspended sediment and wetland vegetation in Hokkaido, northern Japan. The impact of river channelization was confirmed not only by the sediment budgets but also by river aggradation or degradation after the channelization and by the resultant vegetational changes. The budgets of suspended sediment demonstrated that wash load was the predominant component accounting for 95% of the total suspended load delivered into the wetland. This suspended sediment was primarily transported into the wetland by flooding associated with heavy rainfall. Twenty-three percent of the wash load and 63% of the suspended bed material load were deposited in the channelized reach, which produced aggradation of about 2 m at the end of the reach. A shorting of the length of the channel, due to channelization of a meandering river, steepened the slope and enhanced the stream power to transport sediment. This steepening shifted the depositional zones of fine sediment 5 km downstream and aggraded the riverbed. Development of the watershed may increase not only the water discharge but also the amount of suspended sediments. The aggradation reduced the carrying capacity of the channel and caused sediment ladened water to flood over the wetlands. The fine sediment accumulated on the wetlands gradually altered the edaphic conditions and wetland vegetation. A low percentage (10 to 15%) of organic contents of wetlands' soil is more evidence indicating that the present condition is far different from normal. Original vegetation such as sedges and Alnus japonica were disappearing from the adjacent areas of the river channel and were being replaced by willow trees (Salix spp.).     

Comparison between thermal–viscous coupling and frictional sliding

We investigated the similarity between thermal–viscous coupling (TVC) and frictional sliding, proposed by Kameyama and Kaneda [Pure Appl. Geophys. 159 (2002) 2011]. We consider a one-dimensional layer composed of viscous material, which is sandwiched and sheared by two thick elastic layers. The rate of viscous deformation depends on the temperature T_c in the viscous layer as well as shear stress τ. The temperature T_c changes owing to heating by viscous dissipation and conductive cooling. We carried out velocity-stepping tests for the steady-state deformation both numerically and analytically, and compared the temporal evolution of small perturbations with that of the spring-block model with rate- and state-dependent friction (RSF). We found that, as is the case of frictional slip stability, the manner of temporal evolution is classified into four regimes depending on whether it is stable or not and whether it is monotonous or oscillatory with time. By further interpreting TVC in terms of general RSF theory by Ruina [J. Geophys. Res. 88 (1983) 10359], we obtained the relations between the parameters appearing in the phenomenological RSF law and the nondimensional parameters which characterize the nature of TVC. A further improvement of this approach might be important for estimating the actual values of frictional constitutive parameters at the deeper portion of seismogenic faults of interplate or inland earthquakes where a ductile deformation is expected to be significant.     

A practical model to estimate photosynthetically active radiation using general meteorological elements in a temperate humid area and comparison among models

Although accurately evaluating photosynthetically active radiation is important, much effort is required to measure this radiation using a quantum sensor. We develop a new model that makes estimates using only general meteorological data—solar radiation, atmospheric pressure, air temperature, and relative humidity. Root mean square deviations for eight datasets at five sites in Japan were smaller than 5.2 %, similar to error in other studies and to individual differences of quantum sensors. Most root mean square deviations of nine previous models and our eight datasets are larger than that of the new estimation model, which performed well. This suggests that the model is useful for estimating photosynthetically active radiation in a temperate, humid area of Japan.     

Pre-Japan-ARGO: Experimental Observation of Upper and Middle Layers South of the Kuroshio Extension Region Using Profiling Floats

We deployed two profiling floats in the region south of the Kuroshio Extension in March 2000. Temperature and salinity profiles from a depth of 1500 × 10⁴ Pa to the surface are reported every two and four weeks, respectively. The floats performed very well for first four months after deployment. Later they failed in surfacing for a few months when the sea surface temperature in the region was high. The salinity sensors seemed to suffer from some damage during their failure-in-surfacing period. Despite this trouble, the results clearly demonstrate that the profiling float is a very useful and cost-effective tool for physical oceanographic observation in the open sea. This revised version was published online in July 2006 with corrections to the Cover Date.     

Ubiquitous interactive visualization of 3D mantle convection using a web-portal with Java and Ajax framework

We have developed a new strategy and espouse a novel paradigm for large-scale computing and real-time interactive visualization. This philosophy calls for intense interactive sessions for a couple of hours at a time at the expense of storing data on many disk drives during regular or heroic runs on massively parallel systems. We have already carried out successfully real-time volume-rendering visualization by employing hundreds of processors for a grid with over 25 million unknowns. Both Cartesian and spherical 3D mantle convection are visualized. The volume-rendered images are viewed on a large display device, with many panels holding around 13 million pixels. We will employ a software strategy involving an hierarchical rendering service, which will have as software an Ajax interface for interactive visualization of large data sets on many different platforms from desktop PC’s to hand-held devices, such as the OQO and the Nokia N-800. An option for stereo viewing is also implemented. We have installed a user interface as web application, using Java and Ajax framework in order to achieve over the Internet reasonable accessibility to our ongoing runs. Our goal is to expand the array of interactive devices, which will make it feasible to carry out ubiquitous visualization and monitoring of large-scale simulations or onsite events and to allow for collaborations across oceans.