A depleted, not ideally chondritic bulk Earth: The explosive-volcanic basalt loss hypothesis

It has long been customary to assume that in the bulk composition of the Earth, all refractory-lithophile elements (including major oxides Al₂O₃ and CaO, all of the REE, and the heat-producing elements Th and U) occur in chondritic, bulk solar system, proportion to one another. Recently, however, Nd-isotopic studies (most notably Boyet M. and Carlson R. W. (2006) A new geochemical model for the Earth’s mantle inferred from ¹⁴⁶Sm-¹⁴²Nd systematics. Earth Planet. Sci. Lett.250, 254-268) have suggested that at least the outer portion of the planet features a Nd/Sm ratio depleted to ∼0.93 times the chondritic ratio. The primary reaction to this type of evidence has been to invoke a “hidden” reservoir of enriched matter, sequestered into the deepest mantle as a consequence of primordial differentiation. I propose a hypothesis that potentially explains the evidence for Nd/Sm depletion in a very different way. Among the handful of major types of differentiated asteroidal meteorites, two (ureilites and aubrites) are ultramafic restites so consistently devoid of plagioclase that meteoriticists were once mystified as to how all the complementary plagioclase-rich matter (basalt) was lost. The explanation appears to be basalt loss by graphite-fueled explosive volcanism on roughly 100-km sized planetesimals; with the dispersiveness of the process dramatically enhanced, relative to terrestrial experience, because the pyroclastic gases expand into vacuous space (Wilson L. and Keil K. (1991) Consequences of explosive eruptions on small Solar System bodies: the case of the missing basalts on the aubrite parent body. Earth Planet. Sci. Lett.104, 505-512). By analogy with lunar pyroclastic products, the typical size of pyroclastic melt/glass droplets under these circumstances will be roughly 0.1 mm. Once separated from an asteroidal or planetesimal gravitational field, droplets of this size will generally spiral toward the Sun, rather than reaccrete, because drag forces such the Poynting-Robertson effect quickly modify their orbits (the semimajor axis, in a typical scenario, is reduced by several hundred km during the first trip around the Sun). Assuming a similar process occurred on many of the Earth’s precursor planetesimals while they were still roughly 100 km in diameter, the net effect would be a depleted composition for the final Earth. I have modeled the process of trace-element depletion in the planetesimal mantles, assuming the partial melting was nonmodal and either batch or dynamic in terms of the melt-removal style. Assuming the process is moderately efficient, typical final-Earth Nd/Sm ratios are 0.93-0.96 times chondritic. Depletion is enhanced by a relatively low assumed residual porosity in batch-melting scenarios, but dampened by a relatively high value for “continuous” residue porosity in dynamic melting scenarios. Pigeonite in the source matter has a dampening effect on depletion. There are important side effects to the Nd/Sm depletion. The heat-producing elements, Th, U and K, might be severely depleted. The Eu/Eu^∗ ratio of the planet is unlikely to remain precisely chondritic. One of the most inevitable side effects, depletion of the Al/Ca ratio, is consistent with an otherwise puzzling aspect of the composition of the upper mantle. A perfectly undepleted composition for the bulk Earth is dubious.     

Cometary collisions and the dark material on Iapetus

Iapetus (S8) is unique in our solar system in that the albedo of its leading hemisphere is only 0.05 while that of the trailing side is 0.5. Several existing hypotheses are examined and found inadequate. Photometric studies of the dark side are compared to comet nuclei and class D asteroids. It is hypothesized that in the last 10⁶–10⁸ yrs the leading side suffered a high-velocity collision with a cometary body of mass 10¹³–10¹⁵ kg and traveling at a speed of 20 km s^–1. About 5–16% of the excavated material was ejected into space, where the vaporized ices dissipated while the dark carbonaceous/silicate material was reaccreted on the leading side. The collision, although not sufficient to break Iapetus' tidal lock, resulted in a period of oscillation of about 5 yr. Until tidal friction reasserted a lock, the oscillation gave rise to the longitude effect, viz., the observed fact that the dark material covers more than 220 of longitude but only 110 of latitude.     

Solar limb brightening at the extreme limb from photoelectric eclipse observations

Photoelectric observations of the light intensity from the solar crescent before and after totality were made during the eclipses of 7 March, 1970 and 26 February, 1979. Effective wavelengths were determined by interference filters of 20 nm bandwidth. To obtain the limb darkening function, the resulting intensity curves were analyzed by an extension of the method of Julius in which we take into account the actual lunar limb profile. The limb darkening function at 433 nm was obtained for the region 0.937 < sin < 0.9999. Our results are in good agreement with existing center-to-limb measurements in the region of overlap which extends to sin = 0.99. Additional data were obtained at 600 nm for 0.994 < sin < 0.9999. The curves at both wavelengths show a distinctive limb brightening effect at sin = 0.999.     

The Effects of Climate Change on Water Resources in the West: Introduction and Overview

The results of an experimental `end to end' assessment of the effects of climate change on water resources in the western United States are described. The assessment focuses on the potential effects of climate change over the first half of the 21st century on the Columbia, Sacramento/San Joaquin, and Colorado river basins. The paper describes the methodology used for the assessment, and it summarizes the principal findings of the study. The strengths and weaknesses of this study are discussed, and suggestions are made for improving future climate change assessments.     

A preliminary investigation into the use of ochre as a remedial amendment in arsenic-contaminated soils

Ochre is an unwanted waste product that accumulates in wetlands and streams draining abandoned coal and metal mines. A potential commercial use for ochre is to remediate As contaminated soil. Arsenic contaminated soil (605 mg kg⁻¹) was mixed with different ochres (A, B and C) in a mass ratio of 1:1 and shaken in 20 mL of deionised water. After 72 h As concentration in solution was ca. 500 μg kg⁻¹ in the control and 1–2.5 μg kg⁻¹ in the ochre treated experiments. In a second experiment soil:ochre mixtures of 0.05–1:1 were shaken in 20 mL of deionised water for 24 h. For Ochres A and C, as solution concentration was reduced to ca. 1 μg kg⁻¹ by 0.2–1:1 ochre:soil mixtures. For Ochre B, as concentration only reached ca. 1 μg kg⁻¹ in the 1:1 ochre:soil mix. Sorption of As was best modelled by a Freundlich isotherm using As sorption per mass of goethite in the ochre (log K = 1.64, n = 0.79, R² = 0.76, p 0.001). Efficiency of ochre in removing As from solution increased with increasing total Fe, goethite, citrate dithionite extractable Fe and surface area.     

Taxonomic Studies on a New Marine Ciliate, Apocoleps magnus gen. nov., spec. nov. （Ciliophora, Colepidae）, Isolated from Qingdao, China

The morphology and infraciliature of a new marine colepid ciliate, Apocoleps magnus gen. nov., spec. nov., are described based on living observations and silver impregnations. The new genus Apocoleps is characterized by having 8 (vs. 6 in most other related genera) armour tiers, spines at both ends of the cell, 3 adoral organelles and plates with 4 reniform uni-windows. Apocoleps magnus spec. nov. is defined by the following features: body elongated and slightly curved, about 100–120μm× 35–45 μm in vivo; an...