High-reliability zircon separation for hunting the oldest material on Earth: An automatic zircon separator with image-processing/microtweezers-manipulating system and double-step dating

Despite the recent development in radiometric dating of numerous zircons by LA-ICPMS, mineral separation still remains a major obstacle, particularly in the search for the oldest material on Earth. To improve the efficiency in zircon separation by an order of magnitude, we have designed/developed a new machine-an automatic zircon separator(AZS). This is designed particularly for automatic pick-up of100 μm-sized zircon grains out of a heavy mineral fraction after conventional separation procedures. The AZS operates in three modes:(1) image processing to choose targeted individual zircon grains out of all heavy minerals spread on a tray,(2) automatic capturing of the individual zircon grains with microtweezers, and(3) placing them one-by-one in a coordinated alignment on a receiving tray. The automatic capturing was designed/created for continuous mineral selecting without human presence for many hours. This software also enables the registration of each separated zircon grain for dating, by recording digital photo-image, optical(color) indices, and coordinates on a receiving tray. We developed two new approaches for the dating; i.e.(1) direct dating of zircons selected by LA-ICPMS without conventional resin-mounting/polishing,(2) high speed U-Pb dating, combined with conventional sample preparation procedures using the new equipment with multiple-ion counting detectors(LA-MIC-ICPMS).With the first approach, Pb-Pb ages obtained from the surface of a mineral were crosschecked with the interior of the same grain after resin-mounting/polishing. With the second approach, the amount of time required for dating one zircon grain is ca. 20 s, and a sample throughput of 150 grains per hour can be achieved with sufficient precision(ca. 0.5%).We tested the practical efficiency of the AZS, by analyzing an Archean Jack Hills conglomerate in Western Australia with the known oldest(4.3 Ga) zircon on Earth. Preliminary results are positive; we were able to obtain more than 194 zircons that are over 4.0 Ga out of ca. 3800 checked grains, and 9 grains were over 4300 Ma with the oldest at 4371 ± 7 Ma. This separation system by AZS, combined with the new approaches, guarantees much higher yield in the hunt for old zircons.     

http://www.sciencedirect.com/science/article/pii/S1674987114000917

Important ecological changes of the Earth(oxidization of the atmosphere and the ocean) increase in nutrient supply due to the break-up of the super continent(Rodinia) and the appearance of multi-cellular organisms(macroscopic algae and metazoan) took place in the Ediacaran period,priming the Cambrian explosion.The strong perturbations in carbon cycles in the ocean are recorded as excursions in carbonate and organic carbon isotope ratio(δ~(13)C_(carb) and δ~(13)C_(org)) from the Ediacaran through early Cambrian periods.The Ediacaran-early Cambrian sediment records of δ~(13)C_(carb) and δ~(13)C_(org),obtained from the drill-core samples in Three Gorges in South China,are compared with the results of numerical simulation of a simple one-zone model of the carbon cycle of the ocean,which has two reservoirs(i.e.,dissolved organic carbon(DOC) and dissolved inorganic carbon(DIC).The fluxes from the reservoirs are assumed to be proportional to the mass of the carbon reservoirs.We constructed a model,referred to here as the Best Fit Model(BFM),which reproduce δ~(13)C_(carb) and δ~(13)C_(org) records in the Ediacaran-early Cambrian period noted above.BFM reveals that the Shuram excursion is related to three major changes in the carbon cycle or the global ecological system of the Earth:(1) an increase in the coefficient of remineralization by a factor of ca.100,possibly corresponding to a change in the dominant metabolism from anaerobic respiration to aerobic respiration,(2) an increase of carbon fractionation index from 25‰ to 33‰,possibly corresponding to the change in the primary producer from rock-living cyanobacteria to free-living macro algae,and(3) an increase in the coefficient of the organic carbon burial by a factor of ca.100,possibly corresponding to the onset of a biological pump driven by the flourishing metazoan and zooplankton.The former two changes took place at the start of the Shuram excursion,while the third occurred at the end of the Shuram excursion.The other two excursions are explained by the tentative decrease in primary production due to cold periods,which correspond to the Gaskiers(ca.580 Ma) and Bikonor(ca.542 Ma) glaciations.     

On-going orogeny in the outer-arc of the Timor–Tanimbar region, eastern Indonesia

The Timor–Tanimbar islands of eastern Indonesia form a non-volcanic arc in front of a 7 km deep fore-arc basin that separates it from a volcanic inner arc. The Timor–Tanimbar Islands expose one of the youngest high P/T metamorphic belts in the world, providing us with an excellent opportunity to study the inception of orogenic processes, undisturbed by later tectonic events.Structural and petrological studies of the high P/T metamorphic belt show that both deformation and metamorphic grade increase towards the centre of the 1 km thick crystalline belt. Kinematic indicators exhibit top-to-the-north sense of shear along the subhorizontal upper boundaries and top-to-the-south sense in the bottom boundaries of the high P/T metamorphic belt. Overall configuration suggests that the high P/T metamorphic rocks extruded as a thin sheet into a space between overlying ophiolites and underlying continental shelf sediments. Petrological study further illustrates that the central crystalline unit underwent a Barrovian-type overprint of the original high P/T metamorphic assemblages during wedge extrusion, and the metamorphic grade ranged from pumpellyite-actinolite to upper amphibolite facies.Quaternary uplift, marked by elevation of recent reefs, was estimated to be about 1260 m in Timor in the west and decreases toward Tanimbar in the east. In contrast, radiometric ages for the high P/T metamorphic rocks suggest that the exhumation of the high P/T metamorphic belt started in western Timor in Late Miocene time and migrated toward the east. Thus, the tectonic evolution of this region is diachronous and youngs to the east. We conclude that the deep-seated high P/T metamorphic belt extrudes into shallow crustal levels as a first step, followed by doming at a later stage. The so-called ‘mountain building’ process is restricted to the second stage. We attribute this Quaternary rapid uplift to rebound of the subducting Australian continental crust beneath Timor after it achieved positive buoyancy, due to break-off of the oceanic slab fringing the continental crust. In contrast, Tanimbar in the east has not yet been affected by later doming. A wide spectrum of processes, starting from extrusion of the high P/T metamorphic rocks and ending with the later doming due to slab break-off, can be observed in the Timor–Tanimbar region.     

Paleozoic submarine volcanoes in the high-P/T metamorphosed Chichibu system of Eastern Shikoku, Japan

The Sawadani greenstone in the Chichibu Paleozoic System is an ancient submarine volcanic complex consisting of pillow lavas and hyaloclastites. The volcanism is divided into two periods. Alkali basalt was erupted in the first period and two shield-shaped cones were formed. After a period of dormancy the volcanism of the second period took place and a cone was formed by eruptions of lavas ranging in composition from mildly alkaline to tholeiitic basalt. The top of the volcano nearly reached the sea surface and was finally about 3.7 km above the base. A limestone cap and volcanic conglomerate were deposited on the summit. The base rests conformably on upper Carboniferous sandstone and subordinate mudstone derived from a continent or mature island arc. Many feeding channels of lava cut the volcanic body and underlying sedimentary formation. Sedimentation proceeded concurrently on the surrounding sea floor, so that volcanic and sedimentary material is interlayered.The Sawadani greenstone, although it occurs in the high-P/T metamorphic belt, is not believed to be a fragment of oceanic crust (ophiolite complex) formed by oceanic ridge volcanism and later carried into a convergent zone. It is a seamount formed on and within a sedimentary sequence near a continent or island arc. The magma changed from alkaline to tholeittic as the volcano grew.It cannot be assumed that all metavolcanic rocks formed in high-pressure metamorphic terranes are fragments of oceanic crust.     

Paleogeographic maps of the Japanese Islands: Plate tectonic synthesis from 750 Ma to the present

Abstract A series of paleogeographic maps of the Japanese Islands, from their birth at ca 750–700 Ma to the present, is newly compiled from the viewpoint of plate tectonics. This series consists of 20 maps that cover all of the major events in the geotectonic evolution of Japan. These include the birth of Japan at the rifted continental margin of the Yangtze craton ( ca 750-700 Ma), the tectonic inversion of the continental margin from passive to active ( ca 500 Ma), the Paleozoic accretionary growth incorporating fragments from seamounts and oceanic plateaux ( ca 480-250 Ma), the collision between Sino-Korea and Yangtze (250–210 Ma), the Mesozoic to Cenozoic accretionary growth (210 Ma-present) including the formation of the Cretaceous paired metamorphic belts (90 Ma), and the Miocene back-arc opening of the Japan Sea that separated Japan as an island arc (25-15 Ma).     

Swelling–shrinkage properties and soil improvement of compacted expansive soil, Ning-Liang Highway, China

In this paper, the swelling–shrinkage properties of the compacted expansive soil in the Huaiyin Section of the Ning-Lian Highway are introduced, and swelling–shrinkage mechanisms are discussed based on changes in soil water content, dry density, material composition and fabric. The improvement of the compacted expansive soil by lime is also discussed briefly. It is concluded that careful attention should be paid to this type of compacted expansive soil.     

Tectonic evolution of the ultrahigh-pressure (UHP) and high-pressure (HP) metamorphic belts from central China

Abstract In the Triassic suture between the Sino-Korean and Yangtze cratons, the Dabie metamorphic Complex in central China includes three tectonic units: the northern Dabie migmatitic terrane, the central ultrahigh-P coesite- and diamond-bearing eclogite belt, and the southern high-P blueschist-eclogite belt. This complex is bounded to the north by a north-dipping normal fault with a Paleozoic accretionary complex and to the south by a north-dipping reverse fault with Yangtze basement plus its foreland fold-and-thrust sequence. Great differences in metamorphic pressure suggests that these units reached different depths during metamorphism and their juxtaposition occurred by wedge extrusion of subducted old continental fragments. These units were subsequently subjected to (i) Barrovian type regional metamorphism and deformation at shallow depths; (ii) intrusion of Cretaceous granitic plutons; and (iii) doming and segmentation into several blocks by normal and strike-slip faults. A new speculative model of tectonic exhumation of UHP rocks is proposed.     

Modification of the High-Pressure-Type Chromites into the Low- Pressure-Type: Petrological Investigation of the Podiform Chromitites in the Luobusa Ophiolite, Tibet

<正>The podiform chromitites in the Luobusa ophiolite,Southern Tibet,have received much attention because of the presence of ultrahigh-pressure minerals,such as microdiamonds(Bai et al.,1993;Yang et al.,2007;Xu et al.,2009),coesite(Yang et al.,2007)and highly reduced metal phases(Bai et al.,2000;Robinson et al.,2004).The     

http://dx.doi.org/10.1016/j.gsf.2016.09.005

We propose the nuclear geyser model to elucidate an optimal site to bear the first life.Our model overcomes the difficulties that previously proposed models have encountered.Nuclear geyser is a geyser driven by a natural nuclear reactor,which was likely common in the Hadean Earth,because of a much higher abundance of ~(235)U as nuclear fuel.The nuclear geyser supplies the following:(1)high-density ionizing radiation to promote chemical chain reactions that even tar can be used for intermediate material to restart chemical reactions,(2)a system to maintain the circulation of material and energy,which includes cyclic environmental conditions(warm/cool,dry/wet,etc.)to enable to produce complex organic compounds,(3)a lower temperature than 100℃ as not to break down macromolecular organic compounds,(4)a locally reductive environment depending on rock types exposed along the geyser wall,and(5)a container to confine and accumulate volatile chemicals.These five factors are the necessary conditions that the birth place of life must satisfy.Only the nuclear geyser can meet all five,in contrast to the previously proposed birth sites,such as tidal flat,submarine hydrothermal vent,and outer space.The nuclear reactor and associated geyser,which maintain the circulations of material and energy with its surrounding environment,are regarded as the nuclear geyser system that enables numerous kinds of chemical reactions to synthesize complex organic compounds,and where the most primitive metabolism could be generated.     

Methane-induced dolomite “chimneys” on the Kuroshima Knoll, Ryukyu islands, Japan

The Kuroshima Knoll is about 26 km south of Ishigaki Island in the southern part of the Ryukyu Arc. The area is considered to be the source area of “The 1771 Yaeyama Earthquake Tsunami”, which was due to the submarine landslide caused by an earthquake. It has been cleared from some investigations using “Dolphin 3K” and “Shinkai 2000” that there are large-scale dead Calyptogena colonies, many gravels of fallen dolomite chimneys and carbonates on the top of the Knoll [Matsumoto, T., Uechi, C., Kimura, M., 1997; Machiyama, H., Matsumoto, T., Matsumoto, R., Hattori, M., Okano, M., Iwase, R., Tomaru, H., 2001b.]. Carbonates of Kuroshima Knoll have various shapes and macroscopic textures. These have been classified into 4 types; shell crust (pavement), chimney, burrow, and nodule. It is clear that all chimney and burrow carbonates are composed of dolomite, while shell curst and nodule are composed of calcite, sometimes both calcite and dolomite. These carbonates are considered to have been formed by cold seep, because they are characterized by the light carbon isotopic ratio (semi-biogenic) and the heavy oxygen isotopic ratio. This suggests that methane hydrate layers develop under this survey area and the water that has the heavy oxygen and the light carbon isotopic ratio is derived from the dissociation of methane hydrate.