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1.
Although large loads of potentially toxic constituents are discharged from coastal urban watersheds, very little is known about the fates and eventual impacts of these stormwater inputs once they enter the ocean. The goal of this study was to examine the effects of stormwater discharges on the benthic marine environment of Santa Monica Bay. Sediment samples were collected across a gradient of stormwater impact following significantly sized storm events offshore Ballona Creek (a predominantly developed watershed) and Malibu Creek (a predominantly undeveloped watershed). Sediments offshore Malibu Creek had a greater proportion of fine-grained sediments, organic carbon, and naturally occurring metals (i.e., aluminum and iron), whereas sediments offshore Ballona Creek had higher concentrations of anthropogenic metals (i.e., lead) and organic pollutants (i.e., total DDT, total PCB, total PAH). The accumulation of anthropogenic sediment contaminants offshore Ballona Creek was evident up to 2 km downcoast and 4 km upcoast from the creek mouth and sediment concentrations covaried with distance from the discharge. Although changes in sediment texture, organic content, and an increase in sediment contamination were observed, there was little or no alteration to the benthic communities offshore either Ballona or Malibu Creek. Both sites were characterized as having an abundance, species richness, biodiversity and benthic response index similar to shallow water areas distant from creek mouths throughout the Southern California Bight. There was not a preponderance of pollution tolerant, nor a lack or pollution sensitive, species offshore either creek mouth. 相似文献
2.
M. Catherine Eimers Andrew M. Paterson Peter J. Dillon Sherry L. Schiff Brian F. Cumming Roland I. Hall 《Journal of Paleolimnology》2006,35(1):99-109
Stable isotopic compositions and concentrations of total sedimentary sulphur (S) were determined in cores from 6 lakes in
the acid-sensitive Muskoka-Haliburton region of south-central Ontario. The isotopic composition of S in deep sediment (> ~
20 cm) was approximately constant in all lakes, and indicated a pre-industrial δ 34S value between +4.0 and +5.3‰, which is similar to current bulk deposition. Similarly, total S concentrations in deep sediment
were relatively low (1.9–5 mg S g−1 dwt) and approximately constant with depth within cores. All lakes exhibited up-core increases in total S and decreases in
δ 34S at a depth corresponding to the beginning of industrialization in the Great Lakes region ( ~ 1900), resulting in a generally
reciprocal depth pattern between total S concentration and δ 34S ratios. While initial shifts in total S and δ 34S were likely due to enhanced SO4 reduction of newly available anthropogenic SO4, both the magnitude and pattern of up-core S enrichment and shifts in δ 34S varied greatly among lakes, and did not match changes in S deposition post 1900. Differences between lakes in total S and
δ 34S were not related to any single hydrologic (e.g., residence time) or physical (e.g., catchment-area-to-lake area ratio) lake
characteristic. This work indicates that sediment cores do not provide consistent records of changes in post-industrial S
deposition in this region, likely due to redox-related mobility of S in upper sediment. 相似文献
3.
We conducted a laboratory experiment to quantify nutrient (nitrogen and phosphorus) limitation of macroalgae collected along
a gradient in water column nutrient availability in Upper Newport Bay estuary, a relatively nutrient-rich system in southern
California, United States. We collectedEnteromorpha intestinalis and water for use in the experiment from five sites ranging from the lower end of the estuary to the head. Initial algal
tissue N and P concentrations and molar N∶P ratios—as well as water column NO3 and total Kjeldahl nitrogen (TKN)—increased along a spatial gradient from the lower end toward the head. Water column soluble
reactive phosphorus (SRP) varied among sites as well but did not follow a pattem of increasing from the seaward end toward
the head. Algae from each site were assigned to one of four experimental treatments: control (C), nitrogen enrichment (+N),
phosphorus enrichment (+P), and nitrogen and phosphorus enrichment (+N+P). Each week for 3 wk we replaced the water in each
unit with the appropriate treatment water to mimic a poorly flushed estuary. After 3 wk, the degree of nutrient limitation
ofE. intestinalis varied spatially with distance from the head of the estuary. Growth ofE. intestinalis collected from several sites increased with N enrichment alone and increased further when P was added in combination with
N This indicated that N was limiting and that when N was sufficient, P became limiting. Sites from whichE. intestinalis exhibited nutrient limitation spanned the range of background water column NO3 (12.9±0.4 to 55.2±2.1 μM) and SRP (0.8±0.0 to 2.9±0.2 μM) concentrations. Algae that were N limited had initial tissue N
levels ranging from 1.18±0.03 to 2.81±0.08% dry weight and molar N∶P ratios ranging from 16.75±0.39 to 26.40±1.98. 相似文献
4.
Sherry M. Lippiatt Matthew T. Brown Maeve C. Lohan Carolyn J.M. Berger Kenneth W. Bruland 《Estuarine, Coastal and Shelf Science》2010
This study examines the distribution of leachable particulate iron (Fe) in the Columbia River, estuary, and near-field plume. Surface samples were collected during late spring and summer of 2004–2006 as part of four River Influence on Shelf Ecosystems (RISE) cruises. Tidal amplitude and river flow are the primary factors influencing the estuary leachable particulate Fe concentrations, with greater values during high flow and/or spring tides. Near the mouth of the estuary, leachable particulate Fe [defined as the particulate Fe solubilized with a 25% acetic acid (pH 2) leach containing a weak reducing agent to reduce Fe oxyhydroxides and a short heating step to access intracellular Fe] averaged 770 nM during either spring tide or high flow, compared to 320 nM during neap tide, low flow conditions. In the near-field Columbia River plume, elevated leachable particulate Fe concentrations occur during spring tides and/or higher river flow, with resuspended shelf sediment as an additional source to the plume during periods of coastal upwelling and spring tides. Near-field plume concentrations of leachable particulate Fe (at a salinity of 20) averaged 660 nM during either spring tide or high flow, compared to 300 nM during neap tide, low flow conditions. Regardless of tidal amplitude and river flow, leachable particulate Fe concentrations in both the river/estuary and near-field plume are consistently one to two orders of magnitude greater than dissolved Fe concentrations. The Columbia River is an important source of reactive Fe to the productive coastal waters off Oregon and Washington, and leachable particulate Fe is available for solubilization following biological drawdown of the dissolved phase. Elevated leachable Fe concentrations allow coastal waters influenced by the Columbia River plume to remain Fe-replete and support phytoplankton production during the spring and summer seasons. 相似文献
5.
Landslides, avalanches, floods, and other geologic hazards impair natural resources management by jeopardizing public safety,
damaging or restricting resource utilization, and necessitating expenditures for corrective measures The negative impact of
geologic hazard events can be reduced by tailoring resources management to hazard potential of an area This requires assessment
of where and how frequently the events occur National forests and other managed wildlands often lack monitoring or historical
records to compute frequency of hazard occurrence Tree-ring analysis, based on internal growth response to external events
such as tilting and abrasion, can provide frequency data Two examples of the use of tree-ring analysis to date landslide activity
illustrate advantages and limitations of the technique An example from the Fishlake National Forest in central Utah illustrates
assessment for planning purposes An example from the Sierra National Forest in east-central California shows assessment applied
to project design Many geologic hazards in addition to landslides are suited to tree-ring analysis to establish frequency
of occurrence Hazard reduction efforts in natural resources management could be enhanced by careful application of tree-ring
analysis 相似文献
6.
S. Madronich D. R. Hastie B. A. Ridley H. I. Schiff 《Journal of Atmospheric Chemistry》1983,1(1):3-25
An instrument, specifically designed for measurements from a balloon platform in the stratosphere, has been used to obtain ground-level values of the atmospheric photodissociation coefficient of nitrogen dioxide, J NO 2.A typical clear-sky value is 8.0×10-3 s-1 when the solar zenith angle is 40°. Measurements were made as a function of solar zenith angle and correlated with a calibrated Eppley UV radiometer. It is shown that J NO 2may be expressed as a simple function of the radiometer output so that estimates of J NO 2can be made using just an upward looking radiometer to an accuracy of about 20%. The measurements are also found to be in good agreement with calculations of J NO 2using a simplified isotropic multiple scattering computer routine. 相似文献
7.
8.
S. Madronich D. R. Hastie H. I. Schiff B. A. Ridley 《Journal of Atmospheric Chemistry》1985,3(2):233-245
The photodissociation coefficient of NO2, J
NO
2, has been measured from a balloon platform in the stratosphere. Results from two balloon flights are reported. High Sun values of J
NO
2 measured were 10.5±0.3 and 10.3±0.3×10-3 s-1 at 24 and 32 km respectively. The decrease in J
NO
2 at sunset was monitored in both flights. The measurements are found to be in good agreement with calculations of J
NO
2 using a simplified isotropic multiple scattering computer routine. 相似文献
9.
Sherry K. Fieber-Beyer Michael J. Gaffey Michael S. Kelley Vishnu Reddy Chalbeth M. Reynolds 《Icarus》2011,213(2):524-537
We present a mineralogical assessment of 12 Maria family asteroids, using near-infrared spectral data obtained over the years 2000-2009 combined with visible spectral data (when available) to cover the spectral interval of 0.4-2.5 μm. Our analysis indicates the Maria asteroid family, which is located adjacent to the chaotic region of the 3:1 Kirkwood Gap, appears to be a true genetic family composed of assemblages analogous to mesosiderite-type meteorites. Dynamical models by Farinella et al. (Farinella, P., Gunczi, R., Froeschlé, Ch., Froeschlé, C., [1993]. Icarus 101, 174-187) predict this region should supply meteoroids into Earth-crossing orbits. Thus, the Maria family is a plausible source of some or all of the mesosiderites in our meteorite collections. These individual asteroids were most likely once part of a larger parent object that was broken apart and dispersed. One of the Maria dynamical family members investigated, ((695) Bella), was found to be unrelated to the genetic Maria family members. The parameters of (695) Bella indicate an H-chondrite assemblage, and that Bella may be a sister or daughter of Asteroid (6) Hebe. 相似文献
10.
This 2‐year study (2000, 2001) reports annual nutrient (phosphorus, nitrate) export from a first‐order agricultural watershed in southern Ontario based on an intensive monitoring programme. The importance of storm and melt events in annual export estimates is demonstrated and the temporal variability in nutrient loading during events is related to processes occurring within the catchment. The feasibility of predicting event‐related nutrient export from hydrometric data is explored. The importance of sampling frequency throughout events is also shown. Export of total phosphorus (TP), soluble reactive phosphorus (SRP) and nitrate ( ) for 2000 and 2001 averaged 0·35 kg ha?1 year?1, 0·09 kg ha?1 year?1, and 35 kg ha?1 year?1 (as N) respectively. Approximately 75% of annual TP export, 80% of annual SRP export and 70% of annual export occurred during 28 events per year. A small number of large‐magnitude events (>34 mm) accounted for 18–42% of annual TP export, 0–61% of annual SRP export and 13–33% of annual NO export. Our results show that temporal variability in nutrient export is largely governed by discharge in this basin, and export can be predicted from discharge. SRP and TP export can also be predicted from discharge, but only for events that are not large in magnitude. The sampling interval throughout events is important in obtaining precise estimates of nutrient export, as infrequent sampling intervals may over‐ or under‐estimate nutrient export by ± 45% per event for P. This study improves our understanding of and P export patterns and our ability to predict or model them by relating temporal variability in event nutrient export to discharge and processes occurring within the basin, and also by exploring the significance of sampling interval in the context of the importance of individual events, season and temporal variability during events. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献