Sea-floor observations in the tongue of the ocean,Bahamas: An Argo/SeaMARC survey

SeaMARC side-scan sonographs and Argo video and photographic data suggest that the recent sedimentary environment of the floor of the Tongue of the Ocean is controlled by an interplay of turbidity current flow from the south, sediment spill-over from the carbonate platform to the east (windward side), and rock falls from the west carbonate escarpment (lee side). The spill-over forms a sandy sedimentary deposit that acts as a topographic obstruction to the turbidity current flow from the south. This obstruction is expressed by the westward migration of a northwest-southeast oriented turbidity-current-cut channel.     

Channelized and hillslope sediment transport and the geomorphology of mountain belts

This paper uses the results of landscape evolution models and morphometric data from the Andes of northern Peru and the eastern Swiss Alps to illustrate how the ratio between sediment transport on hillslopes and in channels influences landscape and channel network morphologies and dynamics. The headwaters of fluvial- and debris-flow-dominated systems (channelized processes) are characterized by rough, high-relief, highly incised surfaces which contain a dense and hence a closely spaced channel network. Also, these systems tend to respond rapidly to modifications in external forcing (e.g., rock uplift and/or precipitation). This is the case because the high channel density results in a high bulk diffusivity. In contrast, headwaters where landsliding is an important sediment source are characterized by a low channel density and by rather straight and unstable channels. In addition, the topographies are generally smooth. The low channel density then results in a relatively low bulk diffusivity. As a consequence, response times are greater in headwaters of landslide-dominated systems than in highly dissected drainages. The Peruvian and Swiss case studies show how regional differences in climate and the litho-tectonic architecture potentially exert contrasting controls on the relative importance of channelized versus hillslope processes and thus on the overall geomorphometry. Specifically, the Peruvian example illustrates to what extent the storminess of climate has influenced production and transport of sediment on hillslopes and in channels, and how these differences are seen in the morphometry of the landscape. The Swiss example shows how the bedding orientation of the bedrock drives channelized and hillslope processes to contrasting extents, and how these differences are mirrored in the landscape. An erratum to this article can be found at     

Chemical and carbon isotopic evolution of hydrocarbons during prograde metamorphism from 100°C to 550°C: Case study in the Liassic black shale formation of Central Swiss Alps

Hydrocarbon distributions and stable isotope ratios of carbonates (δ¹³C_car, δ¹⁸O_car), kerogen (δ¹³C_ker), extractable organic matter (δ¹³C_EOM) and individual hydrocarbons of Liassic black shale samples from a prograde metamorphic sequence in the Swiss Alps were used to identify the major organic reactions with increasing metamorphic grade. The studied samples range from the diagenetic zone (<100°C) to amphibolite facies (∼550°C). The samples within the diagenetic zones (<100 and 150°C) are characterized by the dominance of C_<20n-alkanes, suggesting an origin related with marine and/or bacterial inputs. The metamorphic samples (200 to 550°C) have distributions significantly dominated by C₁₂ and C₁₃n-alkanes, C₁₄, C₁₆ and C₁₈n-alkylcyclopentanes and to a lesser extend C₁₅, C₁₇ and C₂₁n-alkylcyclohexanes. The progressive ¹³C-enrichment (up to 3.9‰) with metamorphism of the C_>17n-alkanes suggests the occurrence of cracking reactions of high molecular weight compounds. The isotopically heavier (up to 5.6‰) C_<17n-alkanes in metamorphic samples are likely originated by thermal degradation of long-chain homologous with preferential release of isotopically light C₁ and C₂ radicals. The dominance of specific even C-number n-alkylcyclopentanes suggests an origin related to direct cyclization mechanism (without decarboxylation step) of algal or bacterial fatty acids occurring in reducing aqueous metamorphic fluid conditions. The regular increase of the concentrations of n-alkylcycloalkanes vs. C_>13n-alkanes with metamorphism suggests progressive thermal release of kerogen-linked fatty acid precursors and degradation of n-alkanes. Changes of the steroid and terpenoid distributions are clearly related to increasing metamorphic temperatures. The absence of 18α(H)-22,29,30-trisnorneohopane (Ts), the occurrence of 17β(H)-trisnorhopane, 17β(H), 21α(H)-hopanes in the C₂₉ to C₃₁ range and 5α(H),14α(H),17α(H)-20R C₂₇, C₂₉ steranes in the low diagenetic samples (<100°C) are characteristic of immature bitumens. The higher thermal stress within the upper diagenetic zone (150°C) is marked by the presence of Ts, the disappearance of 17β(H)-trisnorhopane and thermodynamic equilibrium of the 22S/(22S + 22R) homohopane ratios. The increase of the ααα-sterane 20S/(20S + 20R) and 20R ββ/(ββ + αα) ratios (from 0.0 to 0.55 and from 0.0 to 0.40, respectively) in the upper diagenetic zone indicates the occurrence of isomerization reactions already at <150°C. However, the isomerization at C-20 (R → S) reaches thermodynamic equilibrium values already at the upper diagenesis (∼150°C) whereas the epimerisation at C-14 and C-17 (αα → ββ) arrives to constant values in the lower anchizone (∼200°C). The ratios Ts vs. 17α(H)-22,29,30-trisnorneohopane [(Ts/(Ts + Tm)] and 18α(H)-30-norneohopane (C₂₉Ts) vs. 17α(H),21β(H)-30-norhopane [C₂₉Ts/(C₂₉Ts + C₂₉)] increase until the medium anchizone (200 to 250°C) from 0.0 to 0.96 and from 0.0 to 0.44, respectively. An opposite trend towards lower values is observed in the higher metamorphic samples.The occurrence of specific hydrocarbons (e.g., n-alkylcyclopentanes, cadalene, hydrogenated aromatic compounds) in metamorphic samples points to kerogen degradation reactions most probably occurring in the presence of water and under reducing conditions. The changes of hydrocarbon distributions and carbon isotopic compositions of n-alkanes related to metamorphism suggest that the organic geochemistry may help to evaluate the lowest grades of prograde metamorphism.     

Thermal regime of the northwest Indian rifted margin – Comparison with predictions

We use a simple approach to estimate the present-day thermal regime along the northwestern part of the Western Indian Passive Margin, offshore Pakistan. A compilation of bottom borehole temperatures and geothermal gradients derived from new observations of bottom-simulating reflections (BSRs) allows us to constrain the relationship between the thermal regime and the known tectonic and sedimentary framework along this margin. Effects of basin and crustal structure on the estimation of thermal gradients and heat flow are discussed. A hydrate system is located within the sedimentary deep marine setting and compared to other provinces on other continental margins. We calculate the potential radiogenic contribution to the surface heat flow along a profile across the margin. Measurements across the continental shelf show intermediate thermal gradients of 38–44 °C/km. The onshore Indus Basin shows a lower range of values spanning 18–31 °C/km. The Indus Fan slope and continental rise show an increasing gradient from 37 to 55 °C/km, with higher values associated with the thick depocenter. The gradient drops to 33 °C/km along the Somnath Ridge, which is a syn-rift volcanic construct located in a landward position relative to the latest spreading center around the Cretaceous–Paleogene transition.     

An inverse method for determining wind stress from water-level fluctuations

The hydrodynamic equations governing the water-level response of a lake to wind stress are inverted to determine wind stress from water-level fluctuations. In order to obtain a unique solution, the wind-stress field is represented in terms of a finite number of spatially dependent basis functions with time-dependent coefficients. The discretized version of the inverse equation is solved by a least-squares procedure to obtain the coefficients, and thereby the stress. The method is tested for several ideal cases with Lake Erie topography. Real water-level data is then used to determine hourly values of vector wind stress over Lake Erie for the period 5 May–31 October, 1979. Results are compared with measurements of wind speed and direction from buoys deployed in the lake. Calculated stress direction agrees with observed wind direction for wind speeds > 7.5 m s⁻¹. Under neutral conditions, calculated drag coefficients increase with the wind speed from 1.53 × 10⁻³ for 7.5−10 m s⁻¹ winds to 2.04 × 10⁻³ for 15−17.5 m s⁻¹ winds. Drag coefficients are lower for stable conditions and higher for unstable conditions.     

Generation of complete theoretical seismograms for SH—

Summary. We report the initial results of our attempts to obtain theoretical seismograms for direct comparison with the experimental time series obtained with the long-period instruments of the WWSSN. The entire theoretical seismogram, including both body waves and surface waves, can be generated for a spherical, anelastic earth by simple inverse Fourier transformation of the sum of the propagating fundamental and higher-mode surface waves. The key to success in reproducing the WWSSN records involves the number of modes, and the minimum period used in these computations; here we use eight modes and a minimum period of 2 s. Efficient computational algorithms make it possible to handle up to 2000 frequency points for each mode; approximately 200 layers are used to model the radial heterogeneity of the earth; attenuation is treated exactly. Examples are given of the SH theoretical seismograms resulting from dislocation sources buried at various depths in the Earth.     

Spatially explicit measures of production of young alewives in Lake Michigan: Linkage between essential fish habitat and recruitment

The identification and protection of essential habitats for early life stages of fishes are necessary to sustain fish stocks. Essential fish habitat for early life stages may be defined as areas where fish densities, growth, survival, or production rates are relatively high. To identify critical habitats for young-of-year (YOY) alewives (Alosa pseud oharengus) in Lake Michigan, we integrated bioenergetics models with GIS (Geographic Information Systems) to generate spatially explicit estimates of potential population production (an index of habitat quality). These estimates were based upon YOY alewife bioenergetic growth rate potential and their salmonine predators’ consumptive demand. We compared estimates of potential population production to YOY alewife yield (an index of habitat importance). Our analysis suggested that during 1994–1995, YOY alewife habitat quality and yield varied widely throughout Lake Michigan. Spatial patterns of alewife yield were not significantly correlated to habitat quality. Various mechanisms (e.g., predator migrations, lake circulation patterns, alternative strategies) may preclude YOY alewives from concentrating in areas of high habitat quality in Lake Michigan.     

A search for the oceanic Lg phase

Summary. The Lg phase has been shown previously to be a collection of higher-mode surface waves guided by the continental crust (Knopoff, Schwab & Kausel). A simple scaling between continental and oceanic crustal thicknesses suggests that a search for an oceanic Lg phase should be made in the period range from 1 to 2s. In a search for SH polarized Lg arrivals over oceanic paths, we found that in addition to the fundamental mode, seismo-grams at relatively short ranges in the Pacific showed the presence of only the first higher mode with group velocities on the steep portion of the dispersion curve rather than at the group velocity minimum as expected. Numerical model analysis indicates that, contrary to the continental case, there is no strong confluence of stationary phases of higher-mode crustal waves in the appropriate period range to produce Lg wave packets; this is due to small but significant differences in scaled crustal structures. Further, lateral variations in the thickness of oceanic sediments are sufficient to scatter most of the crustal surface-wave energy within a relatively short distance. Even were this thickness uniform, attenuation in the sediments would be strong enough to absorb the Lg stationary phases in a short distance.     

Constraints on clinopyroxene/melt partitioning of REE, Rb, Sr, Ti, Cr, Zr, and Nb during mantle melting: First insights from direct peridotite melting experiments at 1.0 GPa

Earlier piston-cylinder experiments in our laboratory produced a collection of mantle melting run products at 1.0 GPa that have now been analyzed by ion probe for selected REE, Ti, Cr, Rb, Sr, Y, Zr, and Nb. Natural starting materials were used and experiments were run in graphite-lined Pt capsules with the melt separated from the residual minerals into a layer of vitreous carbon spheres (VCS) to circumvent quench modification. The glass phase in 18 run products, representing melt percentages of ∼2-20 wt%, yielded excellent data that were inverted to yield the first estimates ever of clinopyroxene/melt distribution coefficients, Ds, derived from direct peridotite partial melting experiments. Uncertainties were estimated with a Monte Carlo method.For the REE and Y, these Ds were then compared to Ds calculated with the widely-used model of Wood and Blundy (1997) and the two sets overlap at the ±2σ level in 123 of 128 cases (∼96%). This indicates to us that: 1) the experiments analyzed here are well equilibrated with respect to major and trace element distributions, thus supporting the efficacy of the VCS technique and its variation involving diamond (e.g., Baker and Stolper, “Determining the composition of high-pressure mantle melts using diamond aggregates” [1994], Geochim. Cosmochim. Acta58, 2811-2827); 2) the model of Wood and Blundy (1997), calibrated largely on the basis of large melt fraction, inverse- or sandwich-type experiments, describes REE and Y partitioning during peridotite melting well, even very near the solidus; and it suggests that the cpx/melt Ds derived here for other elements, not modeled by the Wood and Blundy formulation, are probably also correct for peridotite melting to within their ±2σ uncertainties. D^sp/liq and D^cpx/liq values for Cr calculated directly from electron microprobe data decrease by about a factor of five with increasing temperature and melt percentage.The degree to which our experiments appear to have equilibrated seems at odds with recent measurements of the diffusivities of REE in diopside which suggest that relatively small percentages of our starting mineral grains should have equilibrated diffusively. Instead, we suggest that equilibration occurs much more rapidly through the processes of recrystallization and grain coarsening, accomplished through dissolution and reprecipitation. This suggestion is supported by the observation that our final grain sizes are typically 5-10 times larger than the ∼10 μm starting sizes, indicating that substantial mass transfer occurred in our experiments, probably mediated by the melt phase in which diffusion is faster.