Extended statistical entropy analysis for the evaluation of nitrogen budgets in Austria

Extended statistical entropy analysis (eSEA) is used to evaluate the nitrogen (N) budgets of two Austrian catchments, the Wulka and the Ybbs, and of entire Austria. The eSEA quantifies the extent of N dispersion in the environment. The results from the eSEA are compared to the corresponding N use efficiencies (NUEs). Application of the eSEA reveals that the Ybbs catchment, compared to the Wulka catchment leads to a greater extent of N dispersion, primarily as a result of increased losses of N compounds to the atmosphere and in leachates to the groundwater. The NUE in the Wulka catchment, at 63 %, is substantially higher than that in the Ybbs catchment, at 43 %, and confirms a more efficient N use in Wulka. Furthermore, it is shown that the adoption of a healthy, balanced diet, as defined by the German Nutrition Society, changes the N budget of Austria in a way that significantly reduces the dispersion of N. Decreased N losses to the atmosphere and to the groundwater are primarily responsible for this result. The national NUE of Austria responds only moderately to the adoption of such a diet increasing from 48 to 53 % and leads to statistically insignificant results if the uncertainty of the input data is taken into account. This study demonstrates the effectiveness of eSEA for the evaluation of N budgets in agricultural regions and suggests that statistical entropy can serve as a reliable agri-environmental indicator to support decisions regarding nutrient management.     

Upper Cisuralian palynology and palaeoclimate of Manuguru area Godavari basin,India and their global correlation

The Permian system of the Palaeozoic Erathem is divided into three series, the Early Permian Cisuralian Series, the Middle Permian Guadalupian Series, and the Late Permian Lopingian Series. The Cisuralian Series encompasses the Asselian to Kungurian stages which constitute the basal part of the Gondwana supersequence I. In India, they are represented lithostratigraphically by the Talchir, Karharbari, and Barakar formations. This paper presents the palynological results from the Barakar Formation of the Upper Cisuralian Series from Manuguru which lies in the southeastern part of the Godavari basin. The succession studied comprises 35 subsurface samples from bore hole 1007 represented by clay, shale, sandstone, and coal. The palynofloras in this sequence have a homogenous composition demonstrating that not many significant floral changes took place through the considered stratigraphic range. The entire sequence is characterized by the dominance of nonstriate bisaccate genus Scheuringipollenites and sub-dominance of striate bisaccate genus Faunipollenites(=Protohaploxypinus). The other pollen genera among the nonstriate bisaccates are Rhizomaspora, Primuspollenites, Ibisporites, and Platysaccus. The striate bisaccates include Striatites, Striatopodocarpites, and Stroterosporites. The taeniate taxa are represented by Lueckisporites and Lunatisporites. The common monosaccate genera include Caheniasaccites, Potoniesporites, and Barakarites. Spores are less common and include Latosporites, Brevitriletes, Horriditriletes, Microbaculispora, and Callumispora. They characterize the palynofloral composition of the Lower Barakar Formation. The correlation of this assemblage with some of the biostratigraphic palynozones proposed previously for the Cisuralian sequences of the Paraná Basin of South America, Kalahari Karoo Basin of South Africa, Ruhuhu Basin of Tanzania, East Africa as well as palynoassemblages from South Victoria Land and Dronning Maud Land, Antarctica and Collie Basin of west Australia point out to their Early Permian (Late Sakmarian–Early Artinskian) age. Palynomorphs such as Botryococcus sp., Tetraporinia sp., Balmeela sp. and Leiosphaeridia sp. are also recorded which suggest that these sediments were deposited during post-glacial near shore, cool and humid environment.     

Luminescence and other spectroscopic properties of purple and green Cr-clinochlore

For the first time ever, the luminescence spectra of Cr³⁺ centers in two chlorite crystals are presented. Chromium ions occupy the strong crystal-field site M4 in the brucite sheet and the intermediate crystal-field site in the inner octahedral sheet for purple and green chlorite, respectively. We discuss the influence of an effective positive charge on the Cr³⁺ ion and an effective negative charge of ligands on the differences in the values of the Dq and B parameters. It is concluded that the presence of Fe²⁺ ions and other point defects, as well as concentration quenching, causes the very short luminescence lifetimes of chromium ions.     

The effect of lithology on valley width,terrace distribution,and bedload provenance in a tectonically stable catchment with flat‐lying stratigraphy

How rock resistance or erodibility affects fluvial landforms and processes is an outstanding question in geomorphology that has recently garnered attention owing to the recognition that the erosion rates of bedrock channels largely set the pace of landscape evolution. In this work, we evaluate valley width, terrace distribution, and bedload provenance in terms of reach scale variation in lithology in the study reach and discuss the implications for landscape evolution in a catchment with relatively flat‐lying stratigraphy and very little uplift. A reach of the Buffalo National River in Arkansas was partitioned into lithologic reaches and the mechanical and chemical resistance of the main lithologies making up the catchment was measured. Valley width and the spatial distribution of terraces were compared among the different lithologic reaches. The surface grain size and provenance of coarse (2–90 mm) sediment of both modern gravel bars and older terrace deposits that make up the former bedload were measured and defined. The results demonstrate a strong impact of lithology upon valley width, terrace distribution, and bedload provenance and therefore, upon landscape evolution processes. Channel down‐cutting through different lithologies creates variable patterns of resistance across catchments and continents. Particularly in post‐tectonic and non‐tectonic landscapes, the variation in resistance that arises from the exhumation of different rocks in channel longitudinal profiles can impact local base levels, initiating responses that can be propagated through channel networks. The rate at which that response is transmitted through channels is potentially amplified and/or mitigated by differences between the resistance of channel beds and bedload sediment loads. In the study reach, variation in lithologic resistance influences the prevalence of lateral and vertical processes, thus producing a spatial pattern of terraces that reflects rock type rather than climate, regional base level change, or hydrologic variability. Copyright © 2017 John Wiley & Sons, Ltd.     

Cristobalite in a rhyolitic lava dome: evolution of ash hazard

Prolonged and heavy exposure to particles of respirable, crystalline silica-rich volcanic ash could potentially cause chronic, fibrotic disease, such as silicosis, in individuals living in areas of frequent ash fall. Here, we show that the rhyolitic ash erupted from Chaitén volcano, Chile, in its dome-forming phase, contains increased levels of the silica polymorph cristobalite, compared to its initial plinian eruption. Ash erupted during the initial, explosive phase (2–5 May 2008) contained approximately 2 wt.% cristobalite, whereas ash generated after dome growth began (from 21 May 2008) contains 13–19 wt.%. The work suggests that active obsidian domes crystallise substantial quantities of cristobalite on time-scales of days to months, probably through vapour-phase crystallisation on the walls of degassing pathways, rather than through spherulitic growth in glassy obsidian. The ash is fine-grained (9.7–17.7 vol.% <4 μm in diameter, the respirable range) and the particles are mostly angular. Sparse, fibre-like particles were confirmed to be feldspar or glass.     

Palynological dating and correlation of surface and subsurface sediments from Wardha valley coalfield,Maharashtra

42 genera of palynomorphs have been reported from the qualitative and quantitative analysis of the palynoflora from both open cast mine and bore holes viz., Ballarpur open cast mine, Durgapur open cast mine and Bore hole CMWNM-57 on barrier between Kawadi/Majri open cast and Hindustan Lalpeth Colliery from the Wardha valley coalfield of Wardha basin. Two palynoassemblages have been recorded i.e., an Upper Karharbari palynoassemblage comprising dominance of radial monosaccate genus Parasaccites and subdominance of nonstriate disaccate genus Scheuringipollenites and a Lower Barakar palynoassemblage consisting of dominance of Scheuringipollenites and subdominance of striate disaccates chiefly Faunipollenites, suggesting an Early Permian age (Late Sakmarian to Early Artinskian) to the sediments. It is further authenticated by the occurrence of palynotaxa viz., Crucisaccites, Caheniasaccites, Indotriradites and Tiwariasporis. Upper Karharbari Formation has been demarcated for the first time in lithologically designated Barakar Formations in Ballarpur, Durgapur, Majri and Hindustan Lalpeth Colliery while the sample 57/2 of bore hole CMWNM from Kawadi area may belong to the Kamthi Formation on the basis of pinkish yellowish coarse grained to medium grained sandstone. An attempt has been made to correlate these palynoassemblages with other Lower Gondwana basins of Early Permian affinity.     

Population dynamics and natural hazard risk management: conceptual and practical linkages for the case of Austrian policy making

Natural Hazards - This contribution explores the conceptual and empirical linkages between population dynamics and natural hazard risk management (NHRM). Following a review of the international...     

An ice-core based history of Siberian forest fires since AD 1250

Forest fires play a key role in the global carbon cycle and thus, can affect regional and global climate. Although fires in extended areas of Russian boreal forests have a considerable influence on atmospheric greenhouse gas and soot concentrations, estimates of their impact on climate are hampered by a lack of data on the history of forest fires. Especially regions with strong continental climate are of high importance due to an intensified development of wildfires. In this study we reconstruct the fire history of Southern Siberia during the past 750 years using ice-core based nitrate, potassium, and charcoal concentration records from Belukha glacier in the continental Siberian Altai. A period of exceptionally high forest-fire activity was observed between AD 1600 and 1680, following an extremely dry period AD 1540–1600. Ice-core pollen data suggest distinct forest diebacks and the expansion of steppe in response to dry climatic conditions. Coherence with a paleoenvironmental record from the 200 km distant Siberian lake Teletskoye shows that the vegetational shift AD 1540–1680, the increase in fire activity AD 1600–1680, and the subsequent recovery of forests AD 1700 were of regional significance. Dead biomass accumulation in response to drought and high temperatures around AD 1600 probably triggered maximum forest-fire activity AD 1600–1680. The extreme dry period in the 16th century was also observed at other sites in Central Asia and is possibly associated with a persistent positive mode of the Pacific Decadal Oscillation (PDO). No significant increase in biomass burning occurred in the Altai region during the last 300 years, despite strongly increasing temperatures and human activities. Our results imply that precipitation changes controlled fire-regime and vegetation shifts in the Altai region during the past 750 years. We conclude that high sensitivity of ecosystems to occasional decadal-scale drought events may trigger unprecedented environmental reorganizations under global-warming conditions.