Electron microscopy study of the iron meteorite Santa Catharina

Abstract— Characterization of the microstructural features of the metal of the Santa Catharina meteorite was performed using a variety of electron optical techniques. Sample USNM#6293 is chemically homogeneous on the micron scale and has a Ni content of 28.2 wt.%. Its microstructure is similar to that of the Twin City ataxite and contains clear taenite II, i.e., fcc taenite with domains of tetrataenite, < 10 nm in size. Sample USNM#3043 is a more typical Santa Catharina specimen with dark and light regions as observed with the light optical microscope. The dark regions are inhomogeneous and contain 45–50 wt.% Ni and 7–12 wt.% O. The light regions are homogeneous and contain 35 wt.% Ni and no detectable oxygen. The microstructure is that of cloudy zone, i.e., islands of tetrataenite, ～20 nm in size, in a honeycomb matrix. The honeycomb phase contains Ni rich oxide in the dark regions and contains metal, fcc taenite, in the light regions. The original metal structure of USNM#3043 is cloudy zone which formed during cooling into the low temperature miscibility gap of the Fe-Ni phase diagram. The dark regions were developed from the metal by selective corrosion of the honeycomb structure, transforming it into Ni containing oxides, possibly non-stoichiometric Fe₂NiO₄ while retaining the tetrataenite islands. Using the results of this study, many of the existing discrepancies concerning the microstructure of Santa Catharina can be explained.     

THE BLOOMINGTON (LL6) CHONDRITE AND ITS SHOCK MELT GLASSES

The Bloomington meteorite, a 67.8 gram veined, brecciated chondrite, fell during the summer of 1938 in Bloomington, Illinois. Its olivine, orthopyroxene and metal compositions (fo₆₉, en₇₄ and Fe₅₂ Ni₄₈ respectively) and its texture identify it as a brecciated LL6 chondrite of shock facies d. Shock melt glasses occur in Bloomington as sparse melt pockets and veins in clasts and as isolated masses in the black, clast-rich matrix. The vein glasses chemically resemble bulk LL-group chondrites and thus appear to reflect total melting of the host meteorite. The melt pocket and matrix glasses, like those described previously in L-group chondrites, have more varied compositions and are typically enriched in normative plagioclase. All glasses that we analyzed in Bloomington have FeO/MgO and Na/Al ratios similar to those of LL-group chondrites, indicating that melting of this meteorite involved neither a significant change in the oxidation state of iron nor loss of sodium to a vapor phase. Bloomington is a monomict breccia whose components formed in place as a result of a single episode of shock and attendant melting.     

Some peculiarities in the Asteroidal Belt

The analysis of the fine structure of the Asteroidal Belt evidenciates a group of asteroids next to the resonance 4/9 with Jupiter. In this group and in other groups associated to the Hirayama families there are indications that their orbital parameters can be represented by quantum numbers as defined here and in two of our previous works. Together with this the distribution of the eccentricities and inclinations of the orbital planes of short period comets and diverse type of asteroids indicates that they can be classified as objects with e > sin i and objects with e > sin i with a limit e = sin i which determinates geometrical properties of the orbits related with discrete states in the solar system. This study lets open the possibility of following studies in order to confirm the quantum characteristics of the Asteroidal Belt being these characteristics common to all the solar system and depending of the same fundamental constant of action per mass unit H ₀ = 1/2 ₀ × T ₀ (potential × time) because only a small part of all the available data in the Asteroid Belt is used here.     

A late Neoproterozoic paleomagnetic pole for the Congo craton: Tectonic setting, paleomagnetism and geochronology of the Nola dike swarm (Central African Republic)

New structural, geochronological and paleomagnetic data were obtained on dolerite dikes of the Nola region (Central African Republic) at the northern border of the Congo craton. In this region, metavolcanic successions were thrust southward onto the craton during the Panafrican orogenic events. Our structural data reveal at least two structural klippes south of the present-day limits of the Panafrican nappe suggesting that it has once covered the whole Nola region, promoting the pervasive hydrothermal greenschist metamorphism observed in the underlying cratonic basement and also in the intrusive dolerite dikes. Paleomagnetic measurements revealed a stable dual-polarity low-inclination magnetization component in nine dikes (47 samples), carried by pyrrhotite and magnetite. This component corresponds to a paleopole at 304.8°E and 61.8°S (dp = 5.4, dm = 10.7) graded at Q = 6. Both metamorphism and magnetic resetting were dated by the ⁴⁰Ar/³⁹Ar method on amphibole grains separated from the dikes at 571 ± 6 Ma. The Nola pole is the first well-dated paleomagnetic pole for the Congo craton between 580 and 550 Ma. It marks a sudden change in direction of the Congo craton apparent polar wander path at the waning stages of the Panafrican orogenic events.     

Formation of Zn–Ca phyllomanganate nanoparticles in grass roots

It is now well established that a number of terrestrial and aquatic microorganisms have the capacity to oxidize and precipitate Mn as phyllomanganate. However, this biomineralization has never been shown to occur in plant tissues, nor has the structure of a natural Mn(IV) biooxide been characterized in detail. We show that the graminaceous plant Festuca rubra (red fescue) produces a Zn-rich phyllomanganate with constant Zn:Mn and Ca:Mn atomic ratios (0.46 and 0.38, respectively) when grown on a contaminated sediment. This new phase is so far the Zn-richest manganate known to form in nature (chalcophanite has a Zn:Mn ratio of 0.33) and has no synthetic equivalent. Visual examination of root fragments under a microscope shows black precipitates about ten to several tens of microns in size, and their imaging with backscattered and secondary electrons demonstrates that they are located in the root epidermis. In situ measurements by Mn and Zn K-edge extended X-ray absorption fine structure (EXAFS) spectroscopy and X-ray diffraction (XRD) with a micro-focused beam can be quantitatively described by a single-phase model consisting of Mn(IV) octahedral layers with 22% vacant sites capped with tetrahedral and octahedral Zn in proportions of 3:1. The layer charge deficit is also partly balanced by interlayer Mn and Ca. Diffracting crystallites have a domain radius of 33 Å in the ab plane and contain only 1.2 layers (8.6 Å) on average. Since this biogenic Mn oxide consists mostly of isolated layers, basal 00l reflections are essentially absent despite its lamellar structure. Individual Mn layers are probably held together in the Mn–Zn precipitates by stabilizing organic molecules. Zinc biomineralization by plants likely is a defense mechanism against toxicity induced by excess concentrations of this metal in the rhizosphere.     

Paleoenvironment and sea-level change in the early Cretaceous Barents Sea—implications from near-shore marine sapropels

The late Volgian (early "Boreal" Berriasian) sapropels of the Hekkingen Formation of the central Barents Sea show total organic carbon (TOC) contents from 3 to 36 wt%. The relationship between TOC content and sedimentation rate (SR), and the high Mo/Al ratios indicate deposition under oxygen-free bottom-water conditions, and suggest that preservation under anoxic conditions has largely contributed to the high accumulation of organic carbon. Hydrogen index values obtained from Rock-Eval pyrolysis are exceptionally high, and the organic matter is characterized by well-preserved type II kerogen. However, the occurrence of spores, freshwater algae, coal fragments, and charred land-plant remains strongly suggests proximity to land. Short-term oscillations, probably reflecting Milankovitch-type cyclicity, are superimposed on the long-term trend of constantly changing depositional conditions during most of the late Volgian. Progressively smaller amounts of terrestrial organic matter and larger amounts of marine organic matter upwards in the core section may have been caused by a continuous sea-level rise.