Future changes of the atmospheric composition and the impact of climate change

The development of the future atmospheric chemical composition is investigated with respect to NO _y and O₃ by means of the off‐line coupled dynamic‐chemical general circulation model ECHAM3/CHEM. Two time slice experiments have been performed for the years 1992 and 2015, which include changes in sea surface temperatures, greenhouse gas concentrations, emissions of CFCs, NO _x and other species, i.e., the 2015 simulation accounts for changes in chemically relevant emissions and for a climate change and its impact on air chemistry. The 2015 simulation clearly shows a global increase in ozone except for large areas of the lower stratosphere, where no significant changes or even decreases in the ozone concentration are found. For a better understanding of the importance of (A) emissions like NO _x and CFCs, (B) future changes of air temperature and water vapour concentration, and (C) other dynamical parameters, like precipitation and changes in the circulation, diabatic circulation, stratosphere‐troposphere‐exchange, the simulation of the future atmosphere has been performed stepwise. This method requires a climate‐chemistry model without interactive coupling of chemical species. Model results show that the direct effect of emissions (A) plays a major rôle for the composition of the future atmosphere, but they also clearly show that climate change (B and C) has a significant impact and strongly reduces the NO _y and ozone concentration in the lower stratosphere.     

Geochemistry and Intrusive History of the Ashland Pluton, Klamath Mountains, California and Oregon

The Ashland pluton is a calc-alkaline plutonic complex thatintruded the western Paleozoic and Triassic belt of the KlamathMountains in late Middle Jurassic time. The pluton comprisesa series of compositionally distinct magma pulses. The oldestrocks are hornblende gabbro and two-pyroxene quartz gabbro withinitial ⁸⁷Sr/⁸⁶Sr = 0{dot}7044, ¹⁸O = 8{dot}7%, and REE patternswith chondrite normalized La/Lu = 7. These units were followedby a suite of tonalitic rocks (La_N/Lu_N = 7) and then by a suiteof K₂O- and P₂O₅ rocks of quartz monzodioritic affinity (La_N/Lu_N= 13–21; La_N/Sm_N = 2{dot}4–3{dot}) The quartz monzodioriticrocks were then intruded by biotite granodiorite and granitewith lower REE abundances but more fractionated LREE(La_N/Lu_N= 13–19; La_N/Sm_N = 4{dot}3–6 and they, in turn,were host to dikes and bosses of hornblende diorite. The latestintrusive activity consisted of aplitic and granitic dikes.Combined phase equilibria and mineral composition data, indicateemplacement conditions of approximately P_total = 2{dot}3kb,P_H2O between 1{dot}5 and 2{dot}2 kb, and f_O2 between the nickel-nickeloxide and hematite-magnetite buffers. Successive pulses of magma display increasing SiO₂ togetherwith increasing ¹⁸O and decreasing initial ⁸⁷Sr/⁸⁶Sr. The isotopicdata are consistent with either (1) combined fractional crystallizationof andesitic magma and concurrent assimilation of crustal materialcharacterized by low Sr₁ and high (¹⁸O or, more probably, (2)a series of partial melting events in which sources were successivelyless radiogenic but richer in ¹⁸O Each intrusive stage displaysevidence for some degree of crystal accumulation and/or fractionalcrystallization but neither process adequately accounts fortheir compositional differences. Consequently, each stage appearsto represent a distinct partial melting or assimilation event. The P₂O₅-rich nature of the quartz monzodiorite suite suggestsaccumulation of apatite. However, the suite contains abundantmafic microgranitoid enclaves and most apatite in the suiteis acicular. These observations suggest that magma mixing affectedthe compositional variation of the quartz monzodiorite suite.Mass balance calculations are consistent with a simple mixingprocess in which P₂O₅-rich alkalic basalt magma (representedby the mafic microgranitoid enclaves) was combined with a crystal-poorfelsic magma (represented by the tonalite suite), yielding aquartz monzodioritic magma that then underwent differentiationby crystal fractionation and accumulation.     

The influence of the organic aerosol component on CCN supersaturation spectra for different aerosol types

Abstract This paper describes the effect of the presence of water-soluble organic compounds (WSOC) in aerosol particles on the aerosol critical supersaturation as defined by the Köhler theory and on cloud condensation nuclei (CCN) number concentration. Taking into account both the soluble mass increase and the surface tension depression due to WSOC, we calculated a substantial decrease of the aerosol critical supersaturation, which results in a large increase in CCN number concentration. CCN supersaturation spectra were computed for three different aerosol types: marine, rural and urban. The increase of CCN number concentration in the presence of WSOC (with respect to the case when only the inorganic aerosol compounds are considered) varies with aerosol type, with an increase up to 13% in the marine case, up to 97% in the rural case, and up to 110% in the urban case, for the supersaturation range typical of atmospheric conditions.     

An integrated regionalization of earthquake, flood, and drought hazards in China

Earthquake, flood, and drought data from different sources are combined in a single data set using the same data structure, projection, and scale. The intensity and frequency of each hazard is classified into severe, heavy, modest, and light, producing a classification with 64 combined states for the three kinds of hazard. These classes are then ranked according to severity. The three hazard coverages arc overlaid and the polygons that are produced are coded by the classification system. A map is produced that shows the distribution of these 64 classes in regions and their areas measured from the spatial topological data file in the GIS. Spatial analysis reveals the spatial association among the three hazards and between the three hazards and human factors. There is a brief discussion of the implications of the regionalized map for hazard monitoring.     

Egg laying, chick growth and food of kittiwakes Rissa tridactyla at Hopen, Svalbard

In 1984, kittiwakes at Hopen laid eggs ca. 14 days later than previously found in North Norway and on the Kola Peninsula. The mean clutch size, egg volume, and hatching success were otherwise very similar to those documented on the mainland. Although feeding trips were very long, a rapid chick growth and high rate of chick survival suggested that food availability was not a limiting factor in 1984. In contrast to other sites at Svalbard where polar cod Boreogadus saida and crustaceans dominate kittiwake diets, the diets of chicks at Hopen consisted mainly of capelin Mallotus villosus which the adults probably collected at or beyond the polar front southeast of the island.     

TURBULENCE STRUCTURE IN A STRATIFIED BOUNDARY LAYER UNDER STABLE CONDITIONS

Turbulence structure in stably stratified boundary layers isexperimentally investigated by using a thermally stratified wind tunnel. Astably stratified flow is created by heating the wind tunnel airflow to atemperature of about 50 °C and by cooling the test-section floor to asurface temperature of about 3 °C. In order to study the effect ofbuoyancy on turbulent boundary layers for a wide range of stability, thevelocity and temperature fluctuations are measured simultaneously at adownwind position of 23.5 m from the tunnel entrance, where the boundarylayer is fully developed. The Reynolds number, Re, ranges from 3.14× 104 to 1.27 × 105, and the bulk Richardson number, Ri,ranges from 0 to 1.33. Stable stratification rapidly suppresses thefluctuations of streamwise velocity and temperature as well as the verticalvelocity fluctuation. Momentum and heat fluxes are also significantlydecreased with increasing stability and become nearly zero in the lowest partof the boundary layer with strong stability. The vertical profiles ofturbulence quantities exhibit different behaviour in three distinct stabilityregimes, the neutral flows, the stratified flows with weak stability(Ri = 0.12, 0.20) and those with strong stability (Ri= 0.39,0.47, 1.33). Of these, the two regimes of stratified flows clearly showdifferent vertical profiles of the local gradient Richardson number Ri,separated by the critical Richardson number Ri cr of about 0.25. Moreover,turbulence quantities in stable conditions are well correlated with Ri.     

Re-evaluation of coquinoid sandstone depositional model, Upper Jurassic of central Wyoming and south-central Montana

The most extensive Jurassic marine transgression in North America reached its maximum limits during the Oxfordian Age. At this time, siliciclastic sediments were being brought into the North American seaway from an uplifted zone to the west. Within this setting, complexes of sand ridges and coquinoid sands layers were deposited. Coquinoid sandstones appear to fill erosional scours and were interpreted as channel fills. Re-evaluation of these features in the light of recently discovered attributes of modern shelf sediments and processes has produced a revised model of coquinoid sand deposition in this setting. Coquinoid sandstones which fill ‘channel-like’ scours in the Oxfordian (Upper Jurassic) rocks of central Wyoming and south-central Montana, appear to have formed through the migration of sand waves across the crests of inner shelf sand ridges during periods of storm and tidal flow. Erosion in the zone of flow reattachment in the troughs between sand waves resulted in the development of shell lags. Migration of these scour zones as the sand waves advanced resulted in the deposition of sheet-like coquinoid sandstone bodies. Sand waves crossing the ridge crest tended to migrate more slowly and to be overstepped by later sand waves. Sand wave troughs thus buried have channel-like geometries with apparent epsilon bedding.