Mg and Sr distribution in carbonate rocks from the Maastrichtian/Danian boundary of the Danish subbasin and the North Sea Central Graben

Examination of the Mg and Sr concentrations in carbonate rocks in a number of sections provides the basis for the establishment of two geochemical facies within the region studied: (1) a basinal facies, including the axial part of the Danish Subbasin and the North Sea Central Graben, indicating relatively stable geochemical conditions; and (2) an eastern marginal facies in the Danish Subbasin reflecting unstable geochemical conditions and distinguished by partial cementation and increasing Mg and Sr concentrations towards the northeastern limits of the basin. A slight microtextural variation in the chalk between the basinal and marginal facies indicates that the origin and composition of the biogenic carbonate components strongly influence the bulk-rock geochemistry.

The elemental distribution reveals a negative correlation between the Mg and Sr concentrations in the topmost Maastrichtian chalk, expressed by increasing Mg and decreasing Sr upwards towards the Maastrichtian/Danian boundary. This relation occurs in both geochemical facies and in all sections studied and is believed to have been governed by changing physicochemical conditions in the late Maastrichtian sea.     

Toward policy integration: Assessing carbon capture and storage policies in Japan and Norway

The objective of this paper is to develop independent and systematic criteria for assessing CCS policy in terms of its level of policy integration. We believe that we should assess CCS policy in terms of the distance to an ideal integrated CCS policy in order to keep track of its trajectory toward sustainable development. After reviewing the existing literature of environmental policy integration, an assessment framework for integrated CCS policy is developed based on Arild Underdal's notion of ‘integrated policy’ then, its usefulness is demonstrated by applying it to CCS policies in Japan and Norway. In the final part, we summarize the findings of the cases and conclude with some observations regarding explanatory factors of the difference in terms of the achieved level of policy integration between Japan and Norway's CCS policies, and some policy implications derived from the analysis based on the framework.     

Investigation of hydrochemical characteristics of groundwater from the Cretaceous-Eocene limestone aquifer in southern Ghana and southern Togo using hierarchical cluster analysis

The most relevant controls on the water quality within the Cretaceous-Eocene limestone aquifer of the Keta Basin, Ghana, and the coastal sedimentary basin of Togo were assessed using Q-mode hierarchical cluster analysis (HCA) and mass-balance modelling. The pattern recognition technique of HCA was employed for partitioning hydrochemical data from a total of 65 surface and borehole samples from the study area into water groups. A spatial plot of the water groups consisting of samples from the limestone aquifer shows that the vast majority of samples belonging to the same group are located in close proximity to one another, suggesting the same processes and/or flow paths in the limestone aquifer system. Geochemical reaction models of selected water groups were constructed using PHREEQC-2. The hydrochemical compositions of the water groups and the mass-balance calculations indicate that the dominant processes and reactions responsible for the hydrochemical evolution in the system are: (1) carbonate equilibria, (2) silicate weathering reactions, (3) limited mixing with saline water, and (4) ion exchange. The combined use of HCA and mass-balance modelling has shown to be a useful approach in interpreting groundwater hydrochemistry in an area where large uncertainties exist in the understanding of the groundwater flow system.     

Strontium-isotope studies of “brown water” (organic-rich groundwater) from Denmark

 Groundwater from some Quaternary and upper Tertiary aquifers in western Jutland, Denmark, is heavily influenced by "brown water", i.e., groundwater with a high content of naturally occurring dissolved organic matter. Stable-isotope analyses (¹⁸O/¹⁶O and D/H) indicate that both Quaternary and upper Tertiary aquifers are dominated by meteoric water. However, strontium-isotope analyses make it possible to distinguish between water samples from Quaternary and Miocene aquifers. Relatively low ⁸⁷Sr/⁸⁶Sr ratios, i.e., ∼0.7083, in Sr-rich water samples indicate that the majority of dissolved Sr in groundwater from Miocene as well as Quaternary strata is probably derived from Miocene marine skeletal carbonate matter in the subsurface. This situation is probably the result of Quaternary glacial reworking of upper Tertiary material and/or hydraulic contact between Quaternary and Miocene aquifers. A positive correlation between Sr contents and non-volatile organic carbon indicates that the remarkably high contents of organic matter recorded in these aquifers almost certainly are derived from Miocene sources as well. Received, February 1999 / Revised, July 1999 / Accepted, July 1999