Depth distribution of radiolarians from the Chukchi and Beaufort Seas, western Arctic

The depth distributions of the radiolarian fauna in the Chukchi and Beaufort Seas, marginal seas of the western Arctic Ocean, were examined quantitatively in depth-stratified plankton tows from 4 or 5 intervals above 500 m and in surface sediments from various depths between 163 and 2907 m. The radiolarian assemblage from the water column in September 2000 was dominated by Amphimelissa setosa and followed by the Actinomma boreale/leptoderma group, Pseudodictyophimus gracilipes and Spongotrochus glacialis. These species are related to the Arctic Surface Water shallower than 150 m. This assemblage is similar to that in the Greenland Sea relating to the ice edge, but did not contain typical Pacific radiolarians in spite of the flow of water of Pacific origin in this region. The living depth of Ceratocyrtis historicosa was restricted to the relatively warm water between 300 and 500 m corresponding to the upper Arctic Intermediate Water (AIW) originating from the Atlantic Ocean. Radiolarian assemblages in the surface sediments are similar to those in the plankton tows, except for common Cycladophora davisiana in sediment samples below 500 m. C. davisiana is probably a deep-water species adapted to the lower AIW or the Canadian Basin Deep Water ventilated from the shelves.     

Excess CO2 and pHexcess in the Intermediate Water Layer of the Northwestern Pacific

Excess CO₂ and pH_excess showing an increase in dissolved inorganic carbon and a decrease in pH from the beginning of the industrial epoch (middle of the 19th century) until the present time have been calculated in the intermediate water layer of the northwestern Pacific and the Okhotsk Sea. It is concluded that: (1) The Kuril Basin (Okhotsk Sea) and the Bussol' Strait areas are characterized by the greatest concentrations of excess CO₂ at isopycnal surfaces due to the processes of formation and transformation of intermediate water mass. (2) The largest difference in excess CO₂ concentration between the Okhotsk Sea and the western subarctic Pacific (about 8 µmol/kg) is found at the = 27.0. (3) The difference in excess CO₂ between the western subarctic Pacific and subtropical regions is significant only in the upper part of the intermediate water layer ( = 26.7–27.0). (4) About 10% of the excess CO₂ accumulation in the subtropical north Pacific is determined by water exchange with the subarctic Pacific and the Okhotsk Sea.     

Air-Sea Gas Transfer Velocity in Stormy Winter Estimated from Radon Deficiency

Thirteen vertical profiles of ²²⁶Ra and ²²²Rn in the near-surface water were obtained in the western North Pacific in winter, and the gas transfer velocities across the air-sea interface were estimated. The transfer velocities found by applying a steady state model varied widely from 2.1 to 30.2 m day⁻¹ with a mean of 9.4 m day⁻¹. The mean value is almost 5 times higher than that in summer in other oceans, and the maximum value is a record high for world oceans. This is partly due to the inadequacy of the steady state model, which overestimates when stronger winds blow in more recent days than the ²²²Rn half-life of about 4 days. In fact, a strong low pressure zone passed through the station about 2 days earlier, which was one of the low pressure zones that with a period of develop once a week or so in the northwestern North Pacific in winter. Instead of steady-state removal, if half of the radon removal occurred sporadically every 7 days, and the last removal took place two days before the observation, the transfer velocity would be 26 m day⁻¹. Our mean transfer velocity, which is less than 20% different from the steady state value including both overestimated and underestimated values, 9.4 ± 4.8 m day⁻¹, seems to represent the mean state of this region in winter. This suggests that the gas exchange fluxes under extremely rough conditions in the open ocean are larger than those estimated by using a transfer velocity equation with a linear or quadratic relationship with wind speed. This revised version was published online in July 2006 with corrections to the Cover Date.     

GEK measurements in a shallow water region

Evidence for the applicability of GEK (Geomagnetic Electrokinetography) measurements to shallow water regions is provided from observations in the shelf region of the East China Sea. The reason for the effectiveness of GEK measurements in this case is investigated theoretically, and it is shown to be attributable to the existence of a thick conductive sedimentary layer. In addition, it is shown that low conductive basement rock can be regarded as a good conductor for GEK measurements if the current width is broad enough and if the ratio of current width to water depth is larger than the resistivity ratio of basement rock to sea water. This implies that barotropic tidal currents can be measured with GEK in any ocean on the earth if they have significant magnitudes.     

The structure of the kuroshio front in the vicinity of separation point where the Kuroshio leaves the Japanese coast

By using existing data obtained in the offshore area from the Boso Peninsula to the Joban Coast, it was shown that the double structure of the Kuroshio Front — which is usually found along the northern edge of the Kuroshio Extension to the east 143°E (Nagataet al., 1986 ; Shinet al., 1988) — is hardly found at the edge of the Kuroshio when it is flowing along the Japanese coast or in the area to the west of 142°E. It was suggested that the cold and fresh water core beneath the density front of the double structure originates from the fresh and cold Oyashio Water which is captured beneath the Kuroshio Front just off the Kashima Coast. The double structure of the Kuroshio Front would be generated and developed very rapidly in the region between 142°E and 143°E just after the Kuroshio leaves the Japanese coast.     

Infrared polarization of venus: Its periodic fluctuations and evidence for thin haze

Infrared polarimetry of Venus over the phase angles from 18 to 171° has been made extending previous measurements (S. Sato, K. Kawara, Y. Kobayashi, H. Okuda, K. Noguchi, T. Mukai, and S. Mukai (1980). Icarus43, 288) in both wavelength λ and phase angle θ. The results of polarization measurements at 2.25 μm ? λ ? 5.0 μm are (i) small positive and negative values at K(2.25 μm), (ii) a remarkable variation with λ in the CVF(2.2?4.2μm) filter region, (iii) a nearly smooth curve as a function of θ having a peak value of ～36% at θ ～ 90° at both 3.6 μm and L′(3.8 μm), and (iv) a decrease with increasing field of view at M(5.0 μm) due to the contamination of thermal emission from the dark crescent. Furthermore, at 3.6 μm and L′(3.8 μm), (v) higher values at the poles than at the equator and (vi) 4.5- to 5.9-day periodic fluctuations are also found. From a comparison with model calculations, the results confirm the existence of a thin haze layer consisting of submicron-size particles above the main clouds of Venus; e.g., its optical thickness is about 0.1 at λ ～ 0.94 μm. In addition, result (vi) could be explained by a variation of the optical thickness of the haze layer or that of the brightness temperature of the main clouds.     

Measuring the k–S–p relations on DNAPLs migration

Migration characteristics of dense non-aqueous phase liquids (DNAPLs) in the subsurface can be expressed as a water–DNAPL two-phase system based on mainly the k–S–p relations, which describe the relations among relative permeability (k), degree of water saturation (S), and capillary pressure head (p). The aims of this research are to develop an experimental system with new type of probes, such as the electrical conductivity probe for measuring the degree of water saturation and the hydrophilic and hydrophobic tensiometer for measuring the pore water and DNAPL pressures, and also to estimate the results obtained from the developed experimental system. From these tests, the excellent k–S–p relations were obtained and the efficiency and validity of this developed experimental system have been confirmed in terms of the concept of the scaling coefficient calculated by interfacial tensions.     

面向21世纪的煤化工

煤炭是中国的主要能源和资源，但同时也是主要的污染源。从保护环境、合理利用有限的化石资源的角度和中国的具体国情考虑，应该大力开发温和化高效煤的新工艺，使煤炭资源逐步由能源型利用转化为材料型利用，近年来，我们在煤的溶剂萃取，脱硫降灰机理，煤相关模型化合物反应，煤焦油中稠环芳香族化合物的分离精制，功能性高分子单体合成及一氧化碳高效吸附剂的制备等方面做了大量的研究工作，结合这些研究工作，本文介绍了煤化工的