Ore and Skarn Mineralogy of the Yamato Mine,Yamaguchi Prefecture,Japan, with Emphasis on Silver‐, Bismuth‐, Cobalt‐, and Tin‐bearing Sulfides

Assemblages and chemical compositions of ore minerals from the Yamato mine, Yamaguchi Prefecture, Japan, were investigated in detail to clarify its characteristics as a skarn deposit. Special attention was paid to silver‐, bismuth‐, cobalt‐, and tin‐bearing sulfide minerals and native gold at the mine, which are described here for the first time. Samples of arsenopyrite‐dominant massive ore, and garnet‐rich, clinopyroxene‐garnet‐rich, and wollastonite‐bearing skarn ores were collected from the mine dump. Arsenopyrite is the most abundant ore mineral (>80 vol.%) in the massive ore, in association with both As‐poor/free and As‐bearing pyrite. The major ore minerals in the skarn specimens are pyrite, pyrrhotite, arsenopyrite, chalcopyrite, galena, and sphalerite, along with minor argentite, Ag‐Pb‐Bi sulfate, matildite, bismuthinite, native bismuth, molybdenite, scheelite, stannite, stannoidite, cassiterite, cobaltite, gersdorffite, and Co‐rich violarite. In addition, native gold is observed in the interstices of gangue minerals. Based on the mineral assemblages and textures of the specimens examined, the major ore minerals formed in the early stage of mineralization, and the Bi‐, Ag‐, Co‐, Ni‐, As‐ and Sn‐mineralization occurred in the middle stage. Native gold was deposited in the late stage. The estimated formation temperature of the middle mineralization stage was 312±5 °C, according to iron and zinc partitioning between stannite and coexisting sphalerite. The mineralogical properties and mineralization process of the Yamato mine are consistent with those of common skarn‐ and vein‐type ore deposits associated with ilmenite‐series granitoids in the San‐yo and San‐in districts.     

The Cretaceous Ofuku Pluton and Its Relation to Mineralization in the Western Akiyoshi Plateau,Yamaguchi Prefecture,Japan

The relationship between the magmatism of the Cretaceous Ofuku pluton and mineralization in and around the Akiyoshi Plateau, Yamaguchi Prefecture, Japan was investigated using a combination of field observation, petrographic and geochemical analyses, K–Ar geochronology, and fluid inclusion data. The Ofuku pluton has a surface area of 1.5 × 1.0 km, and was intruded into the Paleozoic accretionary complexes of the Akiyoshi Limestone, Ota Group and Tsunemori Formation in the western part of the Akiyoshi Plateau. The pluton belongs to the ilmenite‐series and is zoned, consisting mainly of early tonalite and granodiorite that share a gradational contact, and later granite and aplite that intruded the tonalite and granodiorite. Harker diagrams show that the Ofuku pluton has intermediate to silicic compositions ranging from 60.4 to 77.9 wt.% SiO₂, but a compositional gap exists between 70.5 to 73.4 wt.% SiO₂ (anhydrous basis). Modal and chemical variations indicate that the assumed parental magma is tonalitic. Quantitative models of fractional crystallization based on mass balance calculations and the Rayleigh fractionation model using major and trace element data for all crystalline phases indicate that magmatic fractionation was controlled mainly by crystal fractionation of plagioclase, hornblende, clinopyroxene and orthopyroxene at the early stage, and quartz, plagioclase, biotite, hornblende, apatite, ilmenite and zircon at the later stage. The residual melt extracted from the granodiorite mush was subsequently intruded into the northern and western parts of the Ofuku pluton as melt lens to form the granite and aplite. The age of the pluton was estimated at 99–97 Ma and 101–98 Ma based on K–Ar dating of hornblende and biotite, respectively. Both ages are consistent within analytical error, indicating that the Ofuku pluton and the associated Yamato mine belong to the Tungsten Province of the San‐yo Belt, which is genetically related to the ilmenite‐series granitoids of the Kanmon to Shunan stages. The aplite contains Cl‐rich apatite and REE‐rich monazite‐(Ce), allanite‐(Ce), xenotime and bastnäsite‐(Ce), indicating that the residual melt was rich in halogens and REEs. The tonalite–granodiorite of the Ofuku pluton contains many three‐phase fluid inclusions, along with daughter minerals such as NaCl and KCl, and vapor/liquid (V/L) volume ratios range from 0.2 to 0.9, suggesting that the fluid was boiling. In contrast, the granite and aplite contain low salinity two‐phase inclusions with low V/L ratios. The granodiorite occupies a large part of the pluton, and the inclusions with various V/L ratios with chloride daughter minerals suggest the boiling fluids might be related to the mineralization. This fluid could have carried base metals such as Cu and Zn, forming Cu ore deposits in and around the Ofuku pluton. The occurrence and composition of fluid inclusions in the igneous rocks from the Akiyoshi Plateau are directly linked to Cu mineralization in the area, demonstrating that fluid inclusions are useful indicators of mineralization.     

Effectiveness of Living Shorelines as an Erosion Control Method in North Carolina

Living shorelines are a shoreline stabilization strategy encompassing a range of vegetative to structural materials and serve as an alternative approach to the use of structures like bulkheads, which are known to aggravate erosion. Living shorelines are often installed with little to no long-term monitoring for effectiveness; specifically, there is a lack of quantitative data regarding their performance as a shoreline stabilization strategy. This study sought to assess the performance of living shorelines with sills, with respect to shoreline protection, by determining shoreline change rates (SCR) using geospatial analysis. Shoreline surveys were conducted using a real-time kinematic (RTK)-GPS unit at a total of 17 living shoreline projects and nine control segments at 12 sites along the coast of North Carolina. Current shoreline position was compared to historic (pre-installation) shoreline positions obtained from aerial imagery, dating to 1993. The average SCR among northern sites before installation was ??0.45?±?0.49 m year^?1, and in southern sites, it was ??0.21?±?0.52 m year^?1. After installation, average SCR was significantly less erosive at northern and southern sites with living shorelines, 0.17?±?0.47 and ??0.01?±?0.51 m year^?1, respectively. Of the 17 living shoreline project segments, 12 exhibited a reduction in the rate of erosion; of those 12, six were observed to be accreting. This study supports the convention that living shorelines can reduce the rate of erosion and potentially restore lost shore zone habitat.     

Phase-lagged warming and the disruption of climatic rhythms during the Matuyama–Brunhes magnetic polarity transition

The influence of the geomagnetic field on climate, a long hotly disputed issue, was examined for the Matuyama–Brunhes (MB) magnetic polarity transition using palynological and paleomagnetic data sets from a high accumulation rate (ca. 50 cm/kyr) sediment core from Osaka Bay. During the period from marine oxygen isotope stages (MIS) 20 to 18, climate change is well correlated with global ice volume variation in the precession cycle, with the exception of the early half of MIS 19. The postglacial warming after substage 20.2 was interrupted by cooling that began just before the sea-level highstand correlated with substage 19.3 and persisted until about a mid-point between 19.3 and 19.2, followed by a rapid warming. The thermal maximum clearly postdates the highest sea-level highstand by 6–7 kyr, and the connection between orbital forcing and climate was disrupted. The cooling event coincided with the center of the paleointensity low during the MB transition. This unusual climate cooling across a sea-level peak is very likely related to the field intensity decrease. The data from Osaka Bay may suggest an instance where the geomagnetic field has influenced climate in the past.     

Comparison of the soil physical properties and hydrological processes in two different forest type catchments

Water Resources - Soil physical properties and hydrological processes were analyzed in two experimental catchments with different forest types: one catchment is covered mostly with conifer type...     

The phase transitions of superdense matter and supernova explosions

Effects of the phase transitions of superdense matter on supernova explosions are investigated with the aid of an idealized equation of state on the assumptions of adiabatic collapse. It is found that in the case of strong phase transitions explosions become weaker, while in the case of weak phase transitions explosions become stronger. However, the increment of the ejected energy is not so large as suggested by Migdalet al. (1979).Paper presented at the IAU Third Asian-Pacific Regional Meeting, held in Kyoto, Japan, between 30 September–6 October, 1984.     

Crystal chemistry and oxidation state of Fe-rich prehnite from a hydrothermally altered dolerite

Mineralogy and Petrology - Fe-rich prehnite, Ca2(Al,Fe)(AlSi3)O10(OH)2, in a hydrothermally altered dolerite sill from Mitsu, Shimane Peninsula, Japan, was studied using 57Fe Mössbauer...     

Comparison of different methods for estimating soil surface evaporation in a bare field

In this paper, three methods for estimating soil evaporation in a bare field were evaluated: evaporation ratio method (k ratio), complementary relationship and bulk equation. Micro-lysimeters were used to measure the actual evaporation for validation of the three methods. For the k ratio method, pan evaporation was used as the reference evaporation instead of the value obtained from the Penman–Monteith equation. This result is important for areas where meteorological data are unavailable. The results showed that, for daytime evaporation, the k ratio and bulk equation produced a good fit with the observation data, while the complementary relationship generated a larger deviation from the measured data. We recommend that the k ratio method and bulk equation could be used to calculate daytime soil evaporation with high accuracy when soil water content and pan evaporation data or meteorological data are available, while the complementary relationship could be used for a rough estimation when pan evaporation is available. All the methods could be applied to calculate cumulative evaporation.     

Factors controlling nitrogen and dissolved organic carbon exports across timescales in two watersheds with different land uses

Investigating factors controlling the temporal patterns of nitrogen (N) and dissolved organic carbon (DOC) exports on the basis of a comparative study of different land uses is beneficial for managing water resources, especially in agricultural watersheds. We focused our research on an agricultural watershed (AW) and a forested watershed (FW) located in the Shibetsu watershed of eastern Hokkaido, Japan, to investigate the temporal patterns of N and DOC exports and factors controlling those patterns at different timescales (inter‐annual, seasonal, and hydrological event scales). Results showed that the annual patterns of N and DOC exports significantly varied over time and were probably controlled by climate. Higher discharge volumes in 2003, a wet year, showed higher N and DOC loadings in both watersheds. However, this process was also regulated by land use associated with N inputs. Higher concentrations and loadings were shown in the agricultural watershed. At the seasonal scale, N and DOC exports in the AW and the FW were more likely controlled by sources associated with land use. The Total N (TN) and Nitrate‐N (NO₃^?‐N) had higher concentrations during snowmelt season in the AW, which may be attributed to manure application in late autumn or early winter in the agricultural watershed. Concentrations of TN, NO₃^?‐N, dissolved organic nitrogen (DON), and DOC showed higher values during the summer rainy season in the FW, related to higher litter decomposition during summer and autumn and the fertilizer application in the agricultural area during summer. Higher DOC concentrations and loadings were observed during the rainy season in the AW, which is probably attributed to higher DOC production related to temperature and microbial activity during summer and autumn in grasslands. Correlations between discharge and concentrations differed during different periods or in different watersheds, suggesting that weather discharge can adequately represent the fact that N export depends on N concentrations, discharge level, and other factors. The differing correlations between N/DOC concentrations and the Si concentration indicated that the N/DOC exports might occur along different flow paths during different periods. During baseflow, the high NO₃^?‐N exports were probably derived from deep groundwater and might have percolated from uplands during hydrological events. During hydrological events, NO₃^?‐N exports may occur along near‐surface flow paths and in deep groundwater, whereas DOC exports could be related to near‐surface flow paths. At the event scale, the relationships between discharge and concentrations of N and DOC were regulated by antecedent soil moisture (shallow groundwater condition) in each watershed. These results indicated that factors controlling N and DOC exports varied at different timescales in the Shibetsu area and that better management of manure application during winter in agricultural lands is urgently needed to control water pollution in streams. Copyright © 2013 John Wiley & Sons, Ltd.