Chemical and GC-MS characterization of marine dissolved lipids

The chloroform-extractable ‘lipid’ fraction of dissolved organic matter in seawater was analyzed by gravimetry, liquid chromatography, gas chromatography (GC), and gas chromatography—mass spectrometry (GC—MS). Gravimetric concentrations of dissolved lipids in the Gulf of Mexico were in the range of 60–160 μg 1^?1 in near-surface waters and 61–116 μg 1^?1 in near bottom waters and accounted for ～4% of the dissolved organic carbon. Over a 12-h sampling period and a 5-d sampling period extensive variability in dissolved lipid quantity and quality were observed. The major percentage of extractable weight was collected in the polar liquid chromatographic fraction (55–95%). Gas chromatographic concentrations of the aliphatic fractions were in the range of 0.014-0.187 μg 1^?1. Concentrations derived from gas chromatography were consistently lower than gravimetrically-derived concentrations. A number of compounds were tentatively identified by a combination of GC, GC—MS, and authentic standards. The major components of the analyzable dissolved lipids were n-alkanes (C₁₆C₃₂), pristane, phytane, methyl, ethyl and propyl esters of fatty acids. Minor components included olefins and cycloalkanes, aromatics, short-chained acids, and possibly a lactone and an alcohol. All concentrations and compounds were indicative of a fairly pristine environment. The n-alkane distribution appears to be the result of marine and terrestrial inputs superimposed on a chronic low-level background of oil pollution. It is suggested that the fatty acid esters and other fragment molecules are the résult of the degradation of humic substances. A number of potential indicators of source were isolated.     

Dynamic and Thermal Disappearance of Prominences and Their Geoeffectiveness

This paper is a qualitative study of 42 events of solar filament/prominence sudden disappearances (“disparitions brusques”; henceforth DBs) around two solar minima, 1985 – 1986 and 1994. The studied events were classified as 17 thermal and 25 dynamic disappearances. Associated events, i.e. coronal mass ejections (CMEs), type II bursts, evolution of nearby coronal holes, as well as solar wind speed, and geomagnetic disturbances are discussed. We have found that about 50% of the thermal DBs with adjacent (within 15° from the DB) coronal holes were associated with CMEs within a selected time window. All the studied thermal disappearances with adjacent coronal holes or accompanied by dynamic disappearances were associated with weak and medium geomagnetic storms. Also, nearly 64% of dynamic DBs were associated with CMEs. Ten (40%) dynamic disappearances were associated with intense geomagnetic storms, even when no CMEs was reported, six (24%) dynamic disappearances corresponded to extreme storms, and five (20%) corresponded to medium geomagnetic storms. The extreme geomagnetic storms appeared to be related to combined events, involving dynamic disappearances with adjacent coronal holes or including thermal disappearances. Furthermore, the geomagnetic activity (Dst index) increased if the source was close to the central meridian (±30°). The highest interplanetary magnetic field (B), longest duration, lowest southward direction B _z component, and lowest Dst were highly correlated for all studied events. The Sun – Earth transit time computed from the starting time of the sudden disappearance and the time its effect was measured at Earth was about 4.3 days and was mainly well correlated with the solar wind speed measured in situ (daily value).     

Deposition of atmospheric pollutant and their chemical characterization in snow pit profile at Dokriani Glacier,Central Himalaya

The uncertainty in assessing the numerous atmospheric pollutants transported via wind from arid and semi-arid regions is affecting the glacial ecosystem. In our study area due to the complexity of the system, a prominent seasonal difference noticed among major ions(Ca~(2+), Mg~(2+), SO_4~(2-), and NO_3~-). There is a need for understanding the ions cycling as a whole and the directionality of the feedback loops in the system. Therefore, we provide an appraisal of our current hypothesis for seasonal difference in major ion concentration from snow samples for two corresponding years(2013 and 2015) at Dokriani Glacier. A systematic study of chemical compositionsin the shallow snow pit from Dokriani Glacier was undertaken for the pre-monsoon season to understand the cycling of major ions from atmosphere to solute acquisition process. The intimating connections of ions cycling in snow and its temporal behavior was observed and analyzed through various statistical tests. Among major ions, the SO_4~(2-)has the highest concentration among anions on an average considered as 14.21% in 2013 and 29.46% in 2015. On the other side Ca~(2+) is the dominant cation contributing 28.22% in 2013 and 15.3% in 2015 on average. The average ratio of Na+/Cl-was higher in 2013 whereas lower in 2015. The backward trajectory analysis suggests the possible sources of the ions transported from Central Asia through the Western Disturbance(WD) as a prominent source of winter precipitation mainly in the Central Himalaya. Ionicconcentration of Ca~(2+) in cations was highly dominated while in anion SO_4~(2-)played the major role. Factor analysis and correlation matrix suggested that, the precipitation chemistry is mostly influenced by anthropogenic, crustal, and sea salt sources over the studied region. The elemental cycling through ocean, atmosphere and biosphere opens up new ways to understand the geochemical processes operating at the glacierized catchments of the Himalaya. Moreover, increasing the field-based studies in the coming decades would also have the certain advantage in overcoming the conceptual and computational geochemical modelling difficulties.     

Chemical and GC-MS characterization of marine particulate lipids

The lipid fraction of particulate organic matter in seawater was analyzed by gravimetry, liquid chromatography, gas chromatography (GS), and gas chromatography—mass spectrometry (GS—MS). Gravimetric concentrations in the Gulf of Mexico were in the range of 12–70 μg 1^?1 for near-surface samples and 9–52 μg 1^?1 for near-bottom samples. The lipids accounted for ～20% of the particulate organic carbon. Particulate lipids were found to be a much more complex mixture of organic compounds than the dissolved lipids and their composition was much more variable. The majority of the extracted weight was recovered in the polar liquid chromatography fraction (49–85%). The major components of the analyzable particulate lipids were similar to those of the dissolved lipids, namely, n-alkanes, pristane, phytane, and methyl, ethyl and propyl fatty acid esters. Often olefins, alkylated benzenes, quinones, and the unresolved GC area contribute a substantial part to the total particulate lipids. Minor components included ketones, phenols, indanes, acids, benzoates, aromatics and possibly derivatives of inositol, dioxane, and pyran. The low concentrations observed confirm that the area is relatively pristine though some evidence for chronic low-level oil pollution was present. Seasonal, diurnal, vertical and areal variations were observed in the particulate lipids. Lipid concentrations not only decreased with depth but they were also a decreased percentage of the organic carbon present. This may indicate the loss of labile carbon with depth due to reworking in the euphotic zone. Anoxic conditions appeared to promote the preservation of lipid materials in the particulate phase, n-Alkanes and fatty acid esters were common to both the particulate and dissolved phases and had similar distributions.     

Desert heat island study in winter by mobile transect and remote sensing techniques

A familiar problem in urban environments is the urban heat island (UHI), which potentially increases air conditioning demands, raise pollution levels, and could modify precipitation patterns. The magnitude and pattern of UHI effects have been major concerns of a lot of urban environment studies. Typically, research on UHI magnitudes in arid regions (such as Phoenix, AZ, USA) focuses on summer. UHI magnitudes in Phoenix (more than three million population) attain values in excess of 5°C. This study investigated the early winter period—a time when summer potential evapotranspiration >250 mm has diminished to <90 mm. An analysis of the winter magnitude of the heat island in Phoenix has been studied very little, and therefore with the aid of automobile transects, fixed stations, and remote sensing techniques, we investigated a portion of the large Phoenix metropolitan area known as the East Valley. The eastern fringes of the metropolitan area abut against breaks in sloping terrain. The highest UHI intensity observed was >8.0°C, comparable to summertime UHI conditions. Through analysis of the Oke (1998) weather factor Φ_W, it was determined thermally induced nighttime cool drainage winds could account for inflating the UHI magnitude in winter.     

δ13C analyses of oceanic particulate organic matter

Seventy-nine δ¹³C analyses of oceanic particulate matter (> 0·μ) from semi-tropical (Gulf of Mexico, Caribbean and Atlantic) and polar (South Indian Ocean) waters showed that the carbon isotope composition of the particulate matter from the cold polar surface waters was lighter ($\text{?24·7}\text{to}\text{?26·0‰}$) than that from the surface in the semi-tropical regions ($\text{?19·8}\text{to}\text{?22·3 ‰}$), reflecting the temperature effect on the photosynthetic fixation of carbon. δ¹³C for deep samples (> 330 m) were generally more negative than the surface samples, except in some well-mixed polar areas.A difference both in organic carbon isotopic composition and percentage organic carbon in the POM and the tops of sediment cores was also apparent; a loss of approximately 95 % of incoming carbon and an increase in ¹³C of several per mille being observed during deposition of particulate matter. This indicates that after settling on the bottom there is extensive diagenesis of the POM by organisms, indicating the non-refractory nature of the organic matter.     

Economic Contribution of Forestry Sector to National Economy in Nepal

Forests are major sources of energy, timber and non-timber forest products, medicinal and aromatic plants, hydrological functions, biodiversity conservation, and also fundamental sources of revenue collection to the nation. Studies indicate that forests could significantly enhance economic growth and create employment opportunities for local communities under intensive management. This paper aims to predict the contribution of the forest sector to the national economy. The economic facets of forestry considered in this paper are revenue generated from timber, non-timber forest products (NTFPs) and medicinal and aromatic plants (MAPs), and protected areas. The ARIMA model was used to forecast the economic contribution of the forestry sector. The study found that the total revenue generated from the selling of timber and fuelwood (USD 50.19 million) was higher than the total revenue collected from protected areas (USD 37.58 million) and NTFPs/MAPs (USD 6.9 million) in the past 15 years. The model projected that the mean revenue for the timber and fuelwood sale will USD 3.5 million for the next ten years. Similarly, the mean revenue will be generated about USD 0.5 million and USD 6.2 million from NTFPs/MAPs and protected areas, respectively, for the next ten years. The study limits to take account the in-kind use of forest products such as timber, fodder, fuelwood, etc., as used by community people within a forest users’ groups. Thus, practicing sustainable forest management, enabling policy documents, establishing forest-based industries, establishing forestry nurseries, conducting agroforestry practices, and tenure security could enhance the forestry sector's economic aspects.