Isotope fractionation of neon during stepheating extraction?: a comment on ‘Re‐interpretation of the existence of a primitive plume under Australia based on neon isotope fractionation during step heating’ by Gautheron and Moreira (2003)

Using a Rayleigh distillation fractionation model, we calculate that the maximum isotope fractionation potentially achievable is less than 5% during the early stages of gas release from a sample. Our calculation corrects the erroneous conclusions of Gautheron and Moreira (2003), who re‐interpreted the plume‐like neon isotopic compositions found in metasomatic apatite from a south‐eastern Australian xenolith (Matsumoto et al., 1997) to be the result of Rayleigh‐type isotope fractionation of originally MORB‐type neon during stepheating gas extraction. We stress that the modelling of neon isotopic fractionation by Gautheron and Moreira (2003) is incorrect, and that the finding of a plume‐like neon isotopic composition in the apatite by Matsumoto et al. (1997) remains a quite valid and robust conclusion.     

K-Ar Ages of Granitic Magmatism and Related Pegmatite Formation at the Umanotani-Shiroyama Mine, Shimane Prefecture, SW Japan and Their Bearings on Cooling History

Abstract. The Umanotani-Shiroyama pegmatite deposits, the largest producer of K-feldspar and quartz in Japan, are of typical granitic pegmatite. Ilmenite-series biotite granite and granite porphyry, hosting the ore deposits, and biotites separated from these rocks yielded K-Ar ages ranging from 89.0 to 81.4 Ma and 95.2 to 93.7 Ma, respectively. Muscovite and K-feldspar separated from the ore zone yielded K-Ar ages with the range of 96.2 to 93.1 Ma and 87.3 to 80.7 Ma, respectively. Muscovites from quartz-muscovite veins in the ore zone and in the granite porphyry yielded K-Ar ages of 90.4 and 76.3 Ma, respectively. K-feldspar is much younger in age than coexisting muscovite. It is noted that the K-Ar ages of biotite separates and the whole-rock ages are identical to those of muscovite and K-feldspar in the ore zone, respectively. These time relations, as well as field occurrence, indicate that the formation of the pegmatite deposits at the Umanotani-Shiroyama mine is closely related in space and time to a series of granitic magmatism of ilmenite-series nature. Using closure temperatures of the K-Ar system for biotite and K-feldspar (microcline), cooling rate of the pegmatite deposits is estimated to be about 82C/m.y. at the beginning, but slowed down to about 15C/m.y. in the later period.     

Strain and tilt changes measured during a water injection experiment at the Nojima Fault zone, Japan

Abstract In order to make geophysical and geological investigations of the Nojima Fault on Awaji Island, Japan, three boreholes measuring 1800 m, 800 m and 500 m deep were drilled into the fault zone. The fault is one of the seismic source faults of the 1995 Hyogo-ken Nanbu earthquake of M 7.2. A new multicomponent borehole instrument was installed at the bottom of the 800 m borehole and continuous observations of crustal strain and tilt have been made using this instrument since May 1996. A high-pressure water injection experiment within the 1800 m borehole was done in February and March 1997 to study the geophysical response, behavior, permeability, and other aspects of the fault zone. The injection site was located approximately 140 m horizontally and 800 m vertically from the instrument. Associated with the water injection, contraction of approximately 0.7 × 10⁻⁷ str (almost parallel to the fault) and tilt of approximately 1 × 10^-7 rad in the sense of upheaval toward the injection site were observed. In addition to these controlled experiments, the strainmeter and tiltmeter also recorded daily variations. We interpret strain and tilt changes to be related to groundwater discharge and increased ultra-micro seismicity induced by the injected water.     

Evolution of Mount Fuji,Japan: Inference from drilling into the subaerial oldest volcano,pre‐Komitake

A buried, old volcanic body (pre‐Komitake Volcano) was discovered during drilling into the northeastern flank of Mount Fuji. The pre‐Komitake Volcano is characterized by hornblende‐bearing andesite and dacite, in contrast to the porphyritic basaltic rocks of Komitake Volcano and to the olivine‐bearing basaltic rocks of Fuji Volcano. K‐Ar age determinations and geological analysis of drilling cores suggest that the pre‐Komitake Volcano began with effusion of basaltic lava flows around 260 ka and ended with explosive eruptions of basaltic andesite and dacite magma around 160 ka. After deposition of a thin soil layer on the pre‐Komitake volcanic rocks, successive effusions of lava flows occurred at Komitake Volcano until 100 ka. Explosive eruptions of Fuji Volcano followed shortly after the activity of Komitake. The long‐term eruption rate of about 3 km³/ka or more for Fuji Volcano is much higher than that estimated for pre‐Komitake and Komitake. The chemical variation within Fuji Volcano, represented by an increase in incompatible elements at nearly constant SiO₂, differs from that within pre‐Komitake and other volcanoes in the northern Izu‐Bonin arc, where incompatible elements increase with increasing SiO₂. These changes in the volcanism in Mount Fuji may have occurred due to a change in regional tectonics around 150 ka, although this remains unproven.     

Thermal equation of state of magnesite to 32 GPa and 2073 K

Pressure–volume–temperature relations have been measured to 32 GPa and 2073 K for natural magnesite (Mg_0.975Fe_0.015Mn_0.006Ca_0.004CO₃) using synchrotron X-ray diffraction with a multianvil apparatus at the SPring-8 facility. A least-squares fit of the room-temperature compression data to a third-order Birch–Murnaghan equation of state (EOS) yielded K₀ = 97.1 ± 0.5 GPa and K′ = 5.44 ± 0.07, with fixed V₀ = 279.55 ± 0.02 Å³. Further analysis of the high-temperature compression data yielded the temperature derivative of the bulk modulus (∂K_T/∂T)_P = −0.013 ± 0.001 GPa/K and zero-pressure thermal expansion α = a₀ + a₁T with a₀ = 4.03 (7) × 10⁻⁵ K⁻¹ and a₁ = 0.49 (10) × 10⁻⁸ K⁻². The Anderson–Grüneisen parameter is estimated to be δ_T = 3.3. The analysis of axial compressibility and thermal expansivity indicates that the c-axis is over three times more compressible (K_Tc = 47 ± 1 GPa) than the a-axis (K_Tc = 157 ± 1 GPa), whereas the thermal expansion of the c-axis (a₀ = 6.8 (2) × 10⁻⁵ K⁻¹ and a₁ = 2.2 (4) × 10⁻⁸ K⁻²) is greater than that of the a-axis (a₀ = 2.7 (4) × 10⁻⁵ K⁻¹ and a₁ = −0.2 (2) × 10⁻⁸ K⁻²). The present thermal EOS enables us to accurately calculate the density of magnesite to the deep mantle conditions. Decarbonation of a subducting oceanic crust containing 2 wt.% magnesite would result in a 0.6% density reduction at 30 GPa and 1273 K. Using the new EOS parameters we performed thermodynamic calculations for magnesite decarbonation reactions at pressures to 20 GPa. We also estimated stability of magnesite-bearing assemblages in the lower mantle.     

Recent hydrological and geochemical research for earthquake prediction in Japan

Hydrological and geochemical studies for earthquake prediction in Japan during the last two decades are reviewed. Following the 1995 Hyogo-ken Nanbu (Kobe) earthquake, the central approach to research on earthquake prediction was modified. Instead of precursory detection, emphasis was placed on understanding the entire earthquake cycle. Moreover, the prediction program for the anticipated Tokai earthquake was revised in 2003 to include the detection of preslip-related precursors. These changes included the promotion of the following hydrological and geochemical studies for earthquake prediction: (1) development and/or application of statistical methods to extract small fluctuations from hydrological/geochemical data, (2) evaluation of the detectability of preslip-related anomalies in terms of groundwater levels in wells in the Tokai region, and (3) establishment of a new groundwater and borehole strain observation network for Nankai and Tonankai earthquake prediction research. The following basic geochemical studies were carried out: (1) development of a new monitoring system using a quadrupole mass spectrometer, (2) experimental studies on hydrogen generation by the grinding of rock and crystal powders, (3) comprehensive monitoring of groundwater gas and precise crustal deformation, and (4) mantle-derivative helium observation to compare with seismic velocity structures and the distribution of non-volcanic tremors. Moreover, hydrological and geochemical investigations related to the evolution of fault zones were introduced within the framework of fault zone drilling projects.     

Attenuation of coda waves and Q c value beneath the Chengdu telemetered seismic network

Based on the single scattering model of coda power spectrum analysis, digital waveform data of 50 events recorded by the real-time processing system of the Chengdu telemetry network are analyzed to estimate the Q _c values of earth medium beneath the Chengdu telemetry network for several specified frequencies. It is found that the Q _c shows the frequency dependency in the form of Q _c = Q ₀ f ⁿ in the range of 1.0 to 20.0Hz. Estimated Q ₀ ranges from 60.83 to 178.05, and n is found to be 0.713 to 1.159. The average value of Q ₀ and n are 117 and 0.978 respectively. This result indicates the strong frequency dependency of the attenuation of coda waves beneath the Chengdu telemetry network. Comparing with the results obtained in other regions of the world, it is found that Q ₀ ⁻¹ value and its change with frequency are similar to those in regions with strong tectonic activity. This subject is supported by the Ministry of Personnel, China for partly sponsoring.     

Changing grading of soil: effect on critical states

Examples of situations are presented where the grading of a soil changes during its lifetime either by crushing of particles leading to an increase of fine material or by slow transport of fine particles with seepage leading to a decrease of fine material. Such grading changes influence the basic constitutive properties of the soil, in particular properties such as critical states which are dependent on the available range of densities of packing. Discrete element modelling is used to show the dependence of critical state conditions on grading and the way in which the particle assembly seeks out new critical state conditions as the grading changes.     

Barrier Layer and Relevant Variability of the Salinity Field in the Equatorial Pacific Estimated in an Ocean Reanalysis Experiment

This paper investigates the feasibility of an ocean data assimilation system to analyze the salinity variability associated with the barrier layer in the equatorial Pacific. In order to validate reproducibility of the temperature and salinity fields, we perform an assimilation run where some temperature and salinity observations by TRITON buoys and Argo floats are withheld. The assimilation run reproduces interannual variability of salinity in the equatorial Pacific exhibited in the data that are withheld. Statistics shows that salinity values and variations in the assimilation run are closer to the data than the climatology and in the model free run. We also confirm that zonal currents in the equatorial Pacific in the reanalysis, where all available temperature and salinity data are assimilated, are consistent with an observation-based mapping and the data of the Acoustic Doppler Current Profiler mounted on TAO buoys. Variability of the barrier layer and relevant salinity field in the reanalysis is consistent with former studies. A thick barrier layer area generally exists west of the equatorial salinity front and is displaced zonally with the migration of the front in the response to El Niño-Southern Oscillation, although the area moved to the east over the front in the 1997 El Niño. It is confirmed that the barrier layer thickness is closely correlated with the near-surface temperature in the equatorial Pacific.     

Bottom pressure change associated with the 2004–2005 large meander of the Kuroshio south of Japan

A large meander of the Kuroshio was generated in the region off the southern coast of Japan in August 2004 and continued until approximately July 2005. The formation and decay of the large-meander (LM) path was observed by bottom pressure (BP) sensors installed on inverted echo sounders (PIESs) and a seismic observing system off Shikoku. The variation in BP was examined focusing on the development, persistence, and decay of the LM path. The BP was found to be depressed associated with a Kuroshio path disturbance, called a small meander, and this BP depression led the sea surface height (SSH) depression by up to approximately two months. The temporal phase shift between the sea surface and deep disturbances was significantly greater than those of other small meanders that did not develop into large meanders. After the formation of the LM path, the BP beneath the Kuroshio increased with a lag of approximately two months behind the SSH elevation along with the upward displacement of the main thermocline. The increase in BP is associated with that of the positive southward BP gradient anomaly, i.e., the eastward deep Kuroshio current anomaly, which suggests an enhancement of the topographic steering and stability of the LM path. This is consistent with the fact that no small meanders occurred in the early LM period from late July 2004 to late January 2005.