The supergene origin of ruthenian hexaferrum in Ni‐laterites

For two decades, the nature of Fe‐rich, oxygen‐bearing, Ru–Os compounds found in the supergene environment has been debated. Ru–Os–Fe‐oxides and nano‐intergrowths of ruthenium with magnetite have been proposed. We applied FE‐SEM, EMPA, μ‐Raman spectroscopy and synchrotron tts‐μXRD to Ru–Os–Fe compounds recovered from Ni‐laterites from the Dominican Republic. The results demonstrate that a significant portion of Fe exists in a common structure with the Ru–Os alloy, that is, ruthenian hexaferrum. This mineral occurs both as nanoparticles and as micrometric patches within a matrix of Fe‐oxide(s). Our data suggest that supergene ruthenian hexaferrum with a (Ru_0.4(Os,Ir)_0.1Fe_0.5)_?1.0 stoichiometry represents the most advanced weathering product of primary laurite within Ni‐laterites from the Dominican Republic.     

Vorticity and intermittency within the pre-breaking region of spilling breakers

This paper presents measurements and analysis of fluid velocity within the context of spilling waves. The data have been collected using 2-D Laser Doppler Velocimetry in pre-breaking monochromatic waves generated in a wave tank. The analysis is performed using orthogonal wavelets and, in addition to the classical criterion adopted in applying Taylor's hypothesis, a new algorithm is proposed for the eduction of eddies at different length scales. The contribution of different scale vortices is computed, and phase is resolved. Microvortices (smaller than the breaker height but larger than the dissipative vortices) and mid-size vortices (with length ranging from the breaker height to the wave length) carry out most turbulence energy under wave crest. The phase average vorticity and strain rate is computed at different wave lengths, with the analysis of intermittence. The intermittency factor shows spikes in the wave crest, especially for turbulence in small vortices.     

The dynamics of phytoplankton, bacteria and heterotrophic flagellates at two Banks near Magdeburg in the River Elbe (Germany)

The main objectives of this study were to describe the seasonal standing stock dynamics of phytoplankton, bacterioplankton and heterotrophic flagellates in the highly eutrophic River Elbe (Germany), and to compare the seasonal patterns observed with other streams. Emphasis was placed on examining and assessing abiotic and biotic controlling factors influencing the structure and dynamics of the riverine plankton. All the physico-chemical and biological parameters determined were within the range or somewhat higher (in the case of phytoplankton abundance and biomass) than reported for other large streams. The underwater light conditions resulting from atypically short phytoplankton growth periods of about 6 months per year and the low phytoplankton carbon to chl a ratio of 23 were identified as a major limiting factor for phytoplankton development in the River Elbe. The seasonal distribution pattern of bacterioplankton indicated probable tight trophodynamical coupling both with phytoplankton and with heterotrophic flagellates, whereas heterotrophic flagellates showed a more trophic link with bacterial densities. Although approximately constant DOC and DON levels throughout the year sustained bacterial growth rates, during the phytoplankton growing season an increase of bacterial standing stocks was observed. Although the left-bank sampling site of the Elbe is strongly influenced by the tributaries Mulde and Saale containing higher concentrations of chloride, nitrogen nutrients, heavy metals and organic pollutants, no clear differences were observed between the two sides of the river concerning the biological parameters measured. Possible reasons and the slightly higher phytoplankton abundance and diversity at the right bank are discussed.     

Influence of Particle Morphology on the Hydraulic Behavior of Coal Ash and Sand

Flexible-wall hydraulic conductivity tests were carried out on bottom ash, fly ash and compacted specimens of sand with additions of 0, 3, 6, 9 and 18% of bentonite. In order to study the effect of bentonite inclusion and particle morphology on the hydraulic conductivity of the admixtures, an investigation was undertaken based on thin section micrographs. It was found that, for both bottom and fly ash admixtures, bentonite addition reduced only one order of magnitude the hydraulic conductivity, from 1.78 × 10⁻⁶ m/s to 1.39 × 10⁻⁷ m/s. On the other hand, the sand hydraulic conductivity was reduced five orders of magnitude, from 3.17 × 10⁻⁵ m/s to 5.15 × 10⁻¹⁰ m/s. Among several factors that can be responsible for the difficulty in reducing hydraulic conductivity, such as ash grain size distribution and elevated cation concentration (leached from the ash) in pore water, it can also be recalled the high particle voids observed in the ash by means of microscopic analysis. The same is not true with the sand, which has solid particles, without inner voids.     

Metals in eggs and hatchlings of Dermochelys coriacea (testudines) in Espírito Santo,Brazil and their relation to hatching and emergence success

Certain concentration of metal may influence survival in embryonic stages, reducing the birthrate and hatching emergence. This study aimed to evaluate concentration of metal in eggs and hatchlings of Dermochelys coriacea and correlate metal concentrations in eggs with hatching and emergence success. The samples were collected at Biological Reserve Station, ES, Brazil. At the nests' opening, unhatched eggs and stillborn hatchlings were collected to survey the successful hatching and emergence of D. coriacea. The eggs shell, egg content, and dead hatchlings metal concentrations were compared to hatching and emergence success. A positive correlation was found between the concentration of copper (Cu) in the hatchlings and the success of the emergence (r² = .28, p < .05), and a moderate positive correlation between the concentrations of iron (Fe) and barium (Ba; r² = .44, p < .05) and success hatching. The concentrations of metals in eggs and hatchlings of D. coriacea in the Espírito Santo are below the levels that could be considered harmful to the species. In summary, there is a positive correlation between metals levels and hatching and emergence success.     

A depth average SPH model including μ(I) rheology and crushing for rock avalanches

Classical depth-integrated smoothed particle hydrodynamics (SPH) models for avalanches are extended in the present work to include a μ(I)− rheological model enriched with a fragmentation law. With this improvement, the basal friction becomes grain distribution dependent. Rock avalanches, where grain distribution tends to change with time while propagating, are the appropriate type of landslide to apply the new numerical proposal. The μ(I)− rheological models considered in the present work are those of Hatano and Gray, combined with two different fragmentation laws, a hyperbolic and a fractal-based law. As an application, Frank avalanche, which took place in Canada in 1903, is analyzed under the scope of the present approach, focusing in the influence of the rheological and fragmentation laws in the evolution of the avalanche.     

Theory of plastic mechanism control for MRF–CBF dual systems and its validation

In this paper the theory of plastic mechanism control is presented for moment resisting frame–concentrically braced frames dual systems, i.e. for structural systems combined by moment resisting frames and concentrically braced frames. It is aimed at the design of structures failing in global mode, i.e. whose collapse mechanism is characterised by the yielding of all the tensile diagonals and the occurrence of buckling in the compressed ones, and by plastic hinge formation at all the beam ends and at the base of first storey columns. The proposed methodology is based on the application of the kinematic theorem of plastic collapse, by imposing that the global mechanism equilibrium curve has to lie below all the other equilibrium curves corresponding to undesired mechanisms. The practical application of the design methodology is illustrated by means of a worked example. In addition, the results of a non-linear static pushover and dynamic analyses of the designed structure are also discussed in order to demonstrate the effectiveness of the proposed design procedure.     

Exploratory seismic site response surveys in a complex geologic area: a case study from Mt. Etna volcano (southern Italy)

A preliminary study targeting to evaluate the local seismic response was performed in the eastern flank of Mt. Etna (southern Italy) using ambient noise measurements. The obtained spectral ratios were subdivided through cluster analysis into different classes of fundamental frequency permitting to draw an iso-frequency contour map. The analysis set into evidence the extreme heterogeneity of lava sequences, which makes difficult to identify a single seismic bedrock formation. Another important outcome, concerning the local seismic effects in terms of frequency and azimuth, is the important role played by the fracture fields associated with the main structural systems of the area. The existence of two zones with strong directional effects striking WNW–ESE and NW–SE, nearly orthogonal to the orientation of the main fracture fields, corroborate such hypothesis.