Phase transition in K2Cd2(SO4)3: Order parameter and microscopic distortions

The transition from P2₁3(T ⁴) to P2₁2₁2₁(D ₂ ⁴ ) in the langbeinite K₂Cd₂(SO₄)₃ has been analyzed using group theoretical methods and previously published structural data above and below the transition. We find that because the transition is strongly first-order, the primary-order parameter has relatively large values at the transition temperature, and higher order terms which involve the order parameter, the strain, and the coupling of the two must be included in the Landau expansion for the free energy. Complex displacements occur at the transition for all atoms of the unit cell, but these displacements can be resolved into contributions which can be shown from symmetry considerations to transform as the _{2 3} irrep of P2 ₁ 3(T ⁴) as well as contributions from symmetry-preserving displacements which transform under the irrep ₁. Therefore, the transition is not a simple one and involves sulfate rotations and cadmium and potassium ion displacements.     

Holocene record of productivity in the NW Iberian continental shelf

A multiproxy approach (textural characteristics, heavy metal concentrations and benthic foraminifera data) was adopted to study the OMEX core KSGX 40, collected at the Galicia Mud Deposit (NW Iberian outer continental shelf) and recording the last ca. 4.8 ka cal BP. Geochemical profiles of Fe, Mn, Zn, Co, Cr, Cu, Ni, Pb, Al and Ca show significant temporal variations. Benthic foraminifera productivity proxy suggests that the recorded muddy events were contemporaneous of a higher C_org flux to the marine benthic environment. The higher flux of organic matter, following a long-term intensification of the upwelling and coinciding with a finer sedimentation, led to depressed levels of oxygen beneath the water-sediments interface and to early diagenetic processes of several redox-sensitive elements.     

Seismic studies of the Brasília fold belt at the western border of the São Francisco Craton, Central Brazil, using receiver function, surface-wave dispersion and teleseismic tomography

The Tocantins Province in Central Brazil is composed of a series of SSW–NNE trending terranes of mainly Proterozoic ages, which stabilized in the Neoproterozoic in the final collision between the Amazon and São Francisco cratons. No previous information on crustal seismic properties was available for this region. Several broadband stations were used to study the regional patterns of crustal and upper mantle structure, extending the results of a recent E–W seismic refraction profile. Receiver functions and surface wave dispersion showed a thin crust (33–37 km) in the Neoproterozoic Magmatic Arc terrane. High average crustal Vp/Vs ratios (1.74–1.76) were consistently observed in this unit. The foreland domain of the Brasília foldbelt, on the other hand, is characterized by thicker crust (42–43 km). Low Vp/Vs ratios (1.70–1.72) were observed in the low-grade foreland fold and thrust zone of the Brasília belt adjacent to the São Francisco craton. Teleseismic P-wave tomography shows that the lithospheric upper mantle has lower velocities beneath the Magmatic Arc and Goiás Massif compared with the foreland zone of the belt and São Francisco craton. The variations in crustal thickness and upper mantle velocities observed with the broadband stations correlate well with the measurements along the seismic refraction profile. The integration of all seismic observations and gravity data indicates a strong lithospheric contrast between the Goiás Massif and the foreland domain of the Brasília belt, whereas little variation was found across the foldbelt/craton surface boundary. These results support the hypothesis that the Brasília foreland domain and the São Francisco craton were part of a larger São Francisco-Congo continental plate in the final collision with the Amazon plate.     

The Flat Dilatometer Test in an Unsaturated Tropical Soil Site

The site characterization of unsaturated soils is well stablished based on laboratory tests, which are expensive and time-consuming. In-situ testing methods, such as the flat dilatometer test (DMT), are an alternative to the traditional approach of drilling, sampling, and laboratory testing. The literature on DMT interpretation is well established on saturated and well-behaved soils. Only few studies deal with DMT interpretation in unusual soils, and little is known about the influence of soil suction on this test. This paper presents and discusses the influence of soil suction on four DMT campaigns carried out in an unsaturated tropical soil site, also incorporating the soil suction influence on the DMT interpretation. Soil suction was estimated by the soil–water characteristic curve (SWCC) and water content profiles. The water content profiles range from 11.3 to 19.7% which corresponds to a suction range estimated by SWCCs mostly between 6 and 200 kPa. Soil suction significantly influenced DMT data up to 5 m depth at the studied site (the unsaturated active zone) increasing the intermediate DMT parameters. The average horizontal stress index (K_D) was equal to about 1.7 and the average dilatometer modulus (E_D) was about 4.7 MPa in the active zone and practically doubled their values due to in situ soil suction. The estimated peak friction angle (?) was 20–30% higher due to soil suction influence on DMT assuming the soil behaves as a sand like material. Soil suction must be considered to assess the behavior of the investigated soil by the DMT. The suction influence should be incorporated in the effective stress and this approach considerably improved the site characterization of the studied site.

     

A land-use-based modelling chain to assess the impacts of Natural Water Retention Measures on Europe’s Green Infrastructure

This article details the process of integrating models to answer a specific policy-driven question: ‘What could be the impact of proposed Natural Water Retention Measures (NWRMs) on Europe’s Green Infrastructure (GI)?’ It describes the new Land Use Modelling Platform (LUMP), now enabling a high spatial scale (100-m) and large coverage (pan-European), whereby several sector-specific models contribute to assessing the impact of regional-level policy on a given spatial topic of concern. The configuration (land claims and land allocations modules) and calibration (accessibility and biophysical suitability) of the LUMP are explained. Four NWRM scenarios (riparian areas, afforestation, grassland and baseline scenario) are configured to run the simulations. For the reference: year 2006, the spatial representation of GI is based on land-use features of a refined version of the CORINE Land Cover (CLC), and resumed as connected components made of nodes and links.

Mathematical morphological image processing and network graph theory model, available from the free software package GUIDOS (the Joint Research Center of the European Commission), enabled the measurement of the GI connectivity and identified most critical links. Results show that the competition for land claimed by different economic sectors, combined with policy-driven rule-sets for the implementation of different NWRMs, yields very different results for the 2030 land-use projections, and subsequently for the morphology of GI. Three indicators associated with the morphology of GI are computed in order to assess the model outputs for 2030. The indicators are computed to answer the following questions: (1) How is the quantity of GI affected by each of the NWRM, and what proportion of that GI is most valuable? (2) What is the location of the most critical nodes and connectors of GI, and what land-use conversions occur under these? (3) Are the average components getting larger or smaller?

Whereas the grassland measure results in the largest net increase of GI, the afforestation measure results in the overall largest number of hectares of key nodes and links within the network. Land conversions occur under the critical GI nodes and links, with a large increase in agricultural areas, especially for the riparian measure under critical nodes and the grassland measure under critical links. Also predominant is the swapping of land from pasture to forest under critical links with the afforestation measure. The riparian measure most increases the average size of GI components, and all three measures contribute to bridging two large components which were divided in the 2006 land-use map, thus increasing the size of the largest component by more than 50%.     

North Atlantic Oscillation sensitivity to the El Niño/Southern Oscillation polarity in a large-ensemble simulation

A large ensemble modeling experiment with the Melbourne University General Circulation Model is presented. Thirty 17-year-long independent simulations were performed. All integrations were forced by the same observed sea surface temperatures, obtained from the Atmospheric Model Intercomparison Project II. The simulations were analyzed to assess the sensitivity of the North Atlantic Oscillation (NAO) to the El Niño/Southern Oscillation (ENSO) polarity. The results show signals of the ENSO phases both in the mean strength of the NAO as well as in its internal variability. During the cold ENSO phase, the probability density function of the NAO index presents a small but positive mean value, whereas it is negative during the warm ENSO phase. Also, the NAO variability associated with each ENSO phase shows a different behavior: during the warm phase the probability density function of the NAO index presents a larger variance and suggests a bimodality, whereas no bimodality is suggested in the cold phase.     

Clay minerals from the sedimentary cover from the Northwest Iberian shelf

The Northern Iberian margin is a typical example of a continental margin subjected to seasonal highly energetic regime (waves and tides) and receiving inputs of continental sediments via riverine discharges. The principal goal of this study has been to use clay minerals as indicators of sedimentary dynamics in the open shelf system. The distributions of clay mineral in the top layer of the sedimentary cover are shown to be related to their continental sources, but also reflect the influences of winter storms and longshore currents in determining the pathways of sediment transport.The mineralogical composition of the material issuing from the rivers is very similar to the general mineralogical composition of the fine fractions of the seabed sediments. Those deposits that are directly influenced by riverine discharges have higher contents of kaolinite (>20%), whereas those that are not have higher contents of illite (>80%). The available data indicate no significant quantities of terrigenous particles are being discharged from the Spanish rias. Therefore, we conclude that physical processes are controlling the clay mineral distributions and that, despite contributions from the Minho River, the main source of fine detrital particles to the shelf region is the Douro River discharge. These particles settle on the middle shelf, below the 60 m isobath. During storm events these particles are re-suspended and advected northwards to the Galician shelf or into deeper domains. Thus the distributions of the clays indicate there is a net transport of fine sediments both northwards and off-shelf.