Oxygen Isotope Evidence for Chemical Interaction of Ki lauea Historical Magmas with Basement Rocks

Klauea historical summit lavas have a wide range in matrix ¹⁸O_VSMOWvalues (4·9–5·6) with lower values in rockserupted following a major summit collapse or eruptive hiatus.In contrast, ¹⁸O values for olivines in most of these lavasare nearly constant (5·1 ± 0·1). The disequilibriumbetween matrix and olivine ¹⁸O values in many samples indicatesthat the lower matrix values were acquired by the magma afterolivine growth, probably just before or during eruption. BothMauna Loa and Klauea basement rocks are the likely sources ofthe contamination, based on O, Pb and Sr isotope data. However,the extent of crustal contamination of Klauea historical magmasis probably minor (< 12%, depending on the assumed contaminant)and it is superimposed on a longer-term, cyclic geochemicalvariation that reflects source heterogeneity. Klauea's heterogeneoussource, which is well represented by the historical summit lavas,probably has magma ¹⁸O values within the normal mid-ocean ridgebasalt mantle range (5·4–5·8) based on thenew olivine ¹⁸O values. KEY WORDS: Hawaii; Klauea; basalt; oxygen isotopes; crustal contamination     

Depth distribution of radiolarians from the Chukchi and Beaufort Seas, western Arctic

The depth distributions of the radiolarian fauna in the Chukchi and Beaufort Seas, marginal seas of the western Arctic Ocean, were examined quantitatively in depth-stratified plankton tows from 4 or 5 intervals above 500 m and in surface sediments from various depths between 163 and 2907 m. The radiolarian assemblage from the water column in September 2000 was dominated by Amphimelissa setosa and followed by the Actinomma boreale/leptoderma group, Pseudodictyophimus gracilipes and Spongotrochus glacialis. These species are related to the Arctic Surface Water shallower than 150 m. This assemblage is similar to that in the Greenland Sea relating to the ice edge, but did not contain typical Pacific radiolarians in spite of the flow of water of Pacific origin in this region. The living depth of Ceratocyrtis historicosa was restricted to the relatively warm water between 300 and 500 m corresponding to the upper Arctic Intermediate Water (AIW) originating from the Atlantic Ocean. Radiolarian assemblages in the surface sediments are similar to those in the plankton tows, except for common Cycladophora davisiana in sediment samples below 500 m. C. davisiana is probably a deep-water species adapted to the lower AIW or the Canadian Basin Deep Water ventilated from the shelves.     

Risk assessment of TBT in the Japanese short-neck clam (Ruditapes philippinarum) of Tokyo Bay using a chemical fate model

A risk assessment of Tributyltin (TBT) in Tokyo Bay was conducted using the Margin of Exposure (MOE) method at the species level using the Japanese short-neck clam, Ruditapes philippinarum. The assessment endpoint was defined to protect R. philippinarum in Tokyo Bay from TBT (growth effects). A No Observed Effect Concentration (NOEC) for this species with respect to growth reduction induced by TBT was estimated from experimental results published in the scientific literature. Sources of TBT in this study were assumed to be commercial vessels in harbors and navigation routes. Concentrations of TBT in Tokyo Bay were estimated using a three-dimensional hydrodynamic model, an ecosystem model and a chemical fate model. MOEs for this species were estimated for the years 1990, 2000, and 2007. Estimated MOEs for R. philippinarum for 1990, 2000, and 2007 were approximately 1–3, 10, and 100, respectively, indicating a declining temporal trend in the probability of adverse growth effects.A simplified software package called RAMTB was developed by incorporating the chemical fate model and the databases of seasonal flow fields and distributions of organic substances (phytoplankton and detritus) in Tokyo Bay, simulated by the hydrodynamic and ecological model, respectively.     

The characteristic distribution of silica over the East China Sea shelf slope

The localized near-bottom water with silica content higher than that in the adjacent shelf water was observed to exist at the eastern margins of the East China Sea continental shelf. The core of the high silica water possessed the silica content corresponding to that in the Kuroshio at depths greater than on the shelf. The mixing analysis of water masses using temperature (T) and silica (Si) showed that the core water can be produced through the vertical mixing of intermediate water of the Kuroshio deeper than 100 m. This study provides us a conclusion that the intermediate water of the Kuroshio is strongly mixed on the shelf slope and then upwelled to form the ridge-like distribution of water masses with low temperature and high silica content at the shelf edge.     

A study of microearthquake seismicity and focal mechanisms within the Sea of Marmara (NW Turkey) using ocean bottom seismometers (OBSs)

We have carried out seismological observations within the Sea of Marmara (NW Turkey) in order to investigate the seismicity induced after Gölcük–İzmit (Kocaeli) earthquake (M_w 7.4) of August 17, 1999, using ocean bottom seismometers (OBSs). High-resolution hypocenters and focal mechanisms of microearthquakes have been investigated during this Marmara Sea OBS project involving deployment of 10 OBSs within the Çınarcık (eastern Marmara Sea) and Central-Tekirdağ (western Marmara Sea) basins during April–July 2000. Little was known about microearthquake activity and their source mechanisms in the Marmara Sea. We have detected numerous microearthquakes within the main basins of the Sea of Marmara along the imaged strands of the North Anatolian Fault (NAF). We obtained more than 350 well-constrained hypocenters and nine composite focal mechanisms during 70 days of observation. Microseismicity mainly occurred along the Main Marmara Fault (MMF) in the Marmara Sea. There are a few events along the Southern Shelf. Seismic activity along the Main Marmara Fault is quite high, and focal depth distribution was shallower than 20 km along the western part of this fault, and shallower than 15 km along its eastern part. From high-resolution relative relocation studies of some of the microearthquake clusters, we suggest that the western Main Marmara Fault is subvertical and the eastern Main Marmara Fault dips to south at 45°. Composite focal mechanisms show a strike-slip regime on the western Main Marmara Fault and complex faulting (strike-slip and normal faulting) on the eastern Main Marmara Fault.     

The effects of possible contamination by sample holders on samples to be returned by Hayabusa2

Chemical compositions of materials used for new sample holders (vertically aligned carbon nanotubes [VACNTs] and polyimide film), which were developed for the analysis of Hayabusa2‐return samples, were determined by instrumental neutron activation analysis and/or instrumental photon activation analysis, to estimate contamination effects from the sample holders. The synthetic quartz plate used for the sample holders was also analyzed. Ten elements (Na, Al, Cr, Mn, Fe, Ni, Eu, W, Au, and Th) and 14 elements (Na, Al, K, Sc, Ti, Cr, Zn, Ga, Br, Sb, La, Eu, Ir, and Au) could be detected in the VACNTs and polyimide film, respectively. The VACNT data show that contamination by this material with respect to the Murchison meteorite is negligible in terms of the elemental ratios (e.g., Fe/Mn, Na/Al, and Mn/Cr) used for the classification of meteorites due to the extremely low density of VACNTs. However, for the Au/Cr ratio, even small degrees (1.7 wt%) of contamination by VACNTs will change the Au/Cr ratio. Elemental ratios used for the classification of meteorites are only influenced by large amounts of contamination (>60 wt%) of polyimide film, which is unlikely to occur. In contrast, detectable effects on Ti isotopic compositions are caused by >0.1 and >0.3 wt% contamination by VACNTs and polyimide film, respectively, and Hf isotopic changes are caused by >0.1 wt% contamination by VACNTs. The new sample holders (VACNTs and polyimide film) are suitable for chemical classification of Hayabusa2‐return samples, because of their ease of use, applicability to multiple analytical instruments, and low contamination levels for most elements.     

Sensitive response of desert vegetation to moisture change based on a near-annual resolution pollen record from Gahai Lake in the Qaidam Basin, northwest China

We present a 50-year pollen record at near-annual resolution from Gahai Lake in the Qaidam Basin on the northeastern Tibetan Plateau. Chronology of a 22-cm short core was established by ²¹⁰Pb and ¹³⁷Cs analysis. The pollen results at 0.5 cm intervals show large changes in Artemisia/Chenopodiaceae (A/C) ratios from < 0.2 to 0.95 in the last 50 years. High (low) A/C ratios represent increase (decrease) in steppe pollen production, which correspond to high (low) relative humidity observed at nearby Delingha weather station. On the basis of good correspondence with instrumental records and carbonate content from Gahai Lake, we conclude that A/C ratio is sensitive to moisture change and can be a very useful index in reconstructing paleoclimate of arid regions. Comparison with pollen and snow accumulation data from Dunde ice core suggests that effective moisture at low and high elevations shows the opposite relationship when mountain precipitation was extremely high, possibly due to topography-induced uplifting and subsiding air dynamics.     

Transition enthalpies and entropies of high pressure zinc metasilicates and zinc metagermanates

The enthalpies of transition at T= 298 K between zinc metasilicate assemblages, measured by molten oxide solution calorimetry, are:

Relationship of the landslide distribution to geology in Hokkaido, Japan

The island of Hokkaido, Japan, is subdivided into nineteen regions on the basis of regional geology and landslide distribution. Four major geologic zones characterize these regions, as follows: (1) Volcanic Rock Zone, (2) “Green Tuff” Zone, (3) Mudstone Zone, and (4) Serpentinite “Green Rock” Zone. Each zone is marked by landslides of a distinctive type. In addition, we have analyzed the relationship between landslide distribution and geologic structure for several areas.     

模糊数学方法在分析日本东海地区地震前兆中的应用

本文把模糊模式识别的直接方法用于检测日本东海地区地震活动性、体积应变、地下水位、地下水氡含量、地倾斜和潮位中的前兆变化。此方法可消除诸如降雨和气温变化等干扰,使我们能更清晰地识别出地震前兆。此外,还把模糊相似方法和模糊聚类方法应用于识别地震空区及检验地震活动随时间变化的相似性。上述方法在日本其他地区同样有效,即将编入日本气象研究所板内地震预报计划中的计算机系统内。