Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.     

Simulation of adaptive optics for the Vacuum Tower Telescope

A simulation model of the adaptive optics of the German Vacuum Tower Telescope (VTT), Observatorio del Teide, Tenerife, is presented. The model uses modules from the integrated model of the Euro50 extremely large telescope, and includes submodels of a Shack-Hartmann wavefront sensor, a de-formable mirror, a tip-tilt mirror, high-voltage amplifier low-pass filters, a reconstructor and a controller. We investigate the impact on the closed loop bandwidth of changes in controller configuration and certain system parameters, such as low pass filter bandwidth and camera integration and readout time. Control strategies were tested on simple models before implementation on the full VTT model. Using the models, different control strategies are compared.     

Longitudinal dispersion compensation for the Very Large Telescope Interferometer

The Very Large Telescope Interferometer [1,13] will be operated in air which will introduce small optical path fluctuations due to internal turbulence [4,6] and dispersion effects. Both may contribute to fringe contrast decrease. Longitudinal dispersion effects can be corrected by inserting an appropriate glass of variable thickness in one arm of the interferometer [3,5,11,12]. This paper presents a new method applied to VLTI in order to select the optimum glass, according to both the observing wavelength and the spectral bandpath, and to calculate its thickness. Results are presented in terms of improvement on the fringe contrast.     

平阳矾山明矾石矿床岩石学特征及其成因浅析

在野外地质工作的基础上，通过对浙江平阳研山明矾石矿床的岩石学及地球化学特征进行认真的研究，进一步证实了矾山明矾山矿床是酸性火山气热液与中酸性火山碎屑岩内的碱性长石的交代中形成的。为了解释矿床的均一性，成矿的周期性和矿床单向依变分带等重要特征，我们重点研究了矿床中明矾石化和叶蜡石化的热力学性质，得出了K 活度和pH值是控制交代产物的重要因素的新结论，提出了该矿床交代成矿作用的新模型，并据此成功地解释了矿床的一些重要特征。     

Wolf-Rayet stars

Summary Recent literature on Population I Wolf-Rayet star research extending from the Milky Way to blue compact dwarf galaxies is reviewed, broken down into inventory, basic parameters and galactic distribution, atmospheres, binaries, intrinsic variability, mass loss, enrichment and evolution. Also the incidence of Wolf-Rayet stars with variable non-thermal radio emission, excess X-ray fluxes, and episodic/periodic IR excesses is reviewed. These phenomena appear to be associated with wind-wind interaction in wide long-period WR+OB binaries and with wind-compact object interaction in WR+c binaries, with orbit sizes of the order of magnitude of the WR radio photosphere sizes or larger.     

On least squares estimation of generalized covariance functions

Least squares estimation (LSE) is theoretically related to quadratic unbiased estimation of variance components. It is argued that these methods of estimation of variance components essentially generalize LSE though they are not formally equivalent.     

A search for the optical and near-infrared counterpart of the accreting millisecond X-ray pulsar XTE J1751−305

We have obtained optical and near-infrared images of the field of the accreting millisecond X-ray pulsar XTE J1751−305. There are no stars in the 0.7-arcsec error circle (0.7 arcsec is the overall uncertainty arising from tying the optical and X-ray images and from the intrinsic uncertainty in the Chandra X-ray astrometric solution). We derive limiting magnitudes for the counterpart of   R > 23.1, I > 21.6, Z > 20.6, J > 19.6  and   K > 19.2  . We compare these upper limits with the magnitudes one would expect for simple models for the possible donor stars and the accretion disc subject to the reddening observed in X-rays for XTE J1751−305 and when put at the distance of the Galactic Centre (8.5 kpc). We conclude that our non-detection does not constrain any of the models for the accretion disc or possible donor stars. Deep, near-infrared images obtained during quiescence will, however, constrain possible models for the donor stars in this ultracompact system.