Contribution to the crystal chemistry of beryl

Chemical analyses and crystallographic and some optical data have been obtained for 28 samples of beryl from Bahia State, Brazil. The larger range of variability in the chemical composition is shown by Mg, Fe and Li. Sodium is the more diffuse alkali element. Potassium is always very limited. Calcium appears in noticeable amounts only in three samples. The Ti, Cr, Rb, and Cs elements were also tested. The samples studied here can be defined as sodium-potassium beryls with low alkali content. Unit cell parameters show the following ranges: a=9.210–9.245 and c=9.190–9.220 Å. From a statistical analysis of these data it may be seen that: an increase of Fe and (Fe+Mn+Mg) percentage has a positive correlation with a, but no influence on c, which in turn has a close positive correlation with Li and is negatively correlated with Be. Less negative correlations also exist between the pairs {Be, Li}, {a,Al}, {Al, Fe} and {Al, (Fe+Mn+Mg)}. A positive correlation also exists between sodium and the parameter a.     

Seasonal changes of the South American monsoon system during the Mid-Holocene in the CMIP5 simulations

The South American Monsoon System (SAMS) is a major climatic feature of South America, and its domain extends from Amazon to La Plata basin. The SAMS region is vulnerable to variations of climate and precipitation patterns, which could impact economic activities and lead to potential societal consequences. In the face of a warming future scenario, the importance of the study of the past climate with numerical simulations is to evaluate the climate models and to assure the reliability of future projections. Here we investigate the Mid-Holocene SAMS, evaluating changes in strength, life cycle and associated dynamical mechanisms in ten Earth System Models simulations. Our results show that the SAMS was weaker in the Mid-Holocene than in the pre-industrial climate in December–January–February (DJF), but stronger in September–October–November (SON). This is probably a consequence of insolation variations in the Mid-Holocene, which contributed to changes in the moisture flux from the Atlantic Ocean to the continent, the strength of the upper-level atmospheric circulation, and the amount of precipitation over the SAMS region. Moreover, we suggest that the life cycle of the SAMS was altered during the Mid-Holocene, with an earlier onset and demise. Our results also indicate that Mid-Holocene SAMS changes are connected to precipitation variations near Northeast Brazil, in a dipole configuration of precipitation between western Amazon and Northeast Brazil, due to the influence of the Walker cell. Finally, this study highlights a need for improvement of the numerical models to better simulate the amount of precipitation over South America and the upper-level circulation over western Amazon in SON, which are crucial factors for a more realistic representation of the SAMS.     

A moving magnetic dipole in a conductive medium

A thorough investigation of the role that the source velocity has in the spatial and temporal variation of the secondary electromagnetic energy scattered by the Earth is necessary because marine controlled-source electromagnetic geophysical surveys employ moving sources. A first step towards this goal is the analysis, for this type of survey, of the difference of the measured value of the secondary electromagnetic energy between two systems: one with a moving source and the other with a fixed source. The model that suffices to stress this kinematic aspect is a vertical magnetic dipole moving at a constant speed along a horizontal line in a homogeneous medium separated from two homogeneous half-spaces by horizontal boundaries both above and below the dipole. The results show that both the velocity and the relative displacement between the source and the medium may cause a measurable variation relative to the static condition. Therefore, it may be necessary to take them into account in geophysical interpretation and to adapt the concepts of time and frequency domain for electromagnetic systems with moving sources.     

Electromagnetic profiling interpretation across vertical faults and dikes

When a vertical fault or dike scatters a normally incident TE-mode plane wave, the horizontal components of the electric and the magnetic fields vary along the direction perpendicular to the strike. This scattering is also responsible for the formation of a vertical component of the magnetic field, which also varies along the direction perpendicular to the strike. Analysis of the lateral variations of the field components permits the identification of the type of geological structure, either fault or dike, as well as an estimate of the position of the geological contacts and the electrical conductivity of each medium. Previous exact analytical solutions have shown that two Fourier cosine integrals can express each field component. A series of functions specified for each model represent the kernel of each integral. From the field components obtained from the first non-zero term of each series, we calculated the following functions: the dip angle and the ellipticity of the vertical polarization ellipse in a plane perpendicular to the strike of the structure, and the azimuth and the ellipticity of the horizontal ellipse. We established master-curves of these functions for the interpretation of vertical faults and dikes for the polarization ellipsoid, for instance VLF or audio-frequency methods. This representation has as variable the induction number     , and as parameters σ ₂/ σ ₁ and     , where a denotes the half-thickness of the dike. The interpretation procedure using curve fitting is possible because the induction number is represented on a logarithmic scale. This procedure represents an important step before automatic interpretation is carried out. Two case histories using field data illustrate the effectiveness of the procedure and the type of quantitative interpretation obtained from it.     

Assessment of regional seasonal rainfall predictability using the CPTEC/COLA atmospheric GCM

This is a study of the annual and interannual variability of regional rainfall produced by the Center for Weather Forecasts and Climate Studies/Center for Ocean, Land and Atmospheric Studies (CPTEC/COLA) atmospheric global climate model. An evaluation is made of a 9-member ensemble run of the model forced by observed global sea surface temperature (SST) anomalies for the 10-year period 1982–1991. The Brier skill score and, Relative Operating Characteristics (ROC) are used to assess the predictability of rainfall and to validate rainfall simulations, in several regions world wide. In general, the annual cycle of precipitation is well simulated by the model for several continental and oceanic regions in the tropics and mid latitudes. Interannual variability of rainfall during the peak rainy season is realistically simulated in Northeast Brazil, Amazonia, central Chile, and southern Argentina–Uruguay, Eastern Africa, and tropical Pacific regions, where the model shows good skill. Some regions, such as northwest Peru–Ecuador, and southern Brazil exhibit a realistic simulation of rainfall anomalies associated with extreme El Niño warming conditions, while in years with neutral or La Niña conditions, the agreement between observed and simulated rainfall anomalies is not always present. In the monsoon regions of the world and in southern Africa, even though the model reproduces the annual cycle of rainfall, the skill of the model is low for the simulation of the interannual variability. This is indicative of mechanisms other than the external SST forcing, such as the effect of land–surface moisture and snow feedbacks or the representation of sub-grid scale processes, indicating the important role of factors other than external boundary forcing. The model captures the well-known signatures of rainfall anomalies of El Niño in 1982–83 and 1986–87, indicating its sensitivity to strong external forcing. In normal years, internal climate variability can affect the predictability of climate in some regions, especially in monsoon areas of the world.     

Sources and Transport of Urban and Biomass Burning Aerosol Black Carbon at the South–West Atlantic Coast

The total extent of the atmospheric impacts associated to the aerosol black carbon (BC) emissions from South America is not completed described. This work presents results of BC monitored during three scientific expeditions (2002, 2003 and 2004) on board of a Brazilian oceanographic vessel Ary Rongel that covered the South–West Atlantic coast between 22–62°S. This latitudinal band encloses major urban regions of South America and the outflow region of the SACZ (South Atlantic Convergent Zone), which is an important mechanism of advective transport of heat, moisture, minor gases and aerosols from the South America continental land to the Southern Atlantic Ocean. Our results showed that aerosol BC enhanced concentrations from urban/industrial origin can be transported to the South–West Atlantic Ocean due to the migration of sub-polar fronts that frequently reach tropical/subtropical regions. Despite the decrease of aerosol BC concentrations southwards (from ∼1,200 ng m⁻³ at latitude 22°S to ∼10 ng m⁻³ at latitude 62°S), several observed peak events were attributed to regional urban activities. Most of such events could be explained by the use of air mass back trajectories analysis. In addition, a global model simulation is presented (Goddard Institute for Space Studies – GISS GCM BC simulation) to explore the origins of aerosol BC in the South–West Atlantic. The model allowed isolating the biomass emissions from South America and Africa and industrial (non-biomass) pollution from other regions of the globe. This model suggests that the apportionment of about half of the aerosol BC at the South–West Atlantic may derive from South American biomass burning.     

A bin-microphysics cloud model with high-order, positive-definite advection

An axisymmetric, anelastic model of a convective cloud is described. The model comprises prognostic equations for the azimuthal vorticity, the perturbation potential temperature, the perturbation water vapor mixing ratio, 44 categories of cloud condensation nuclei, and 100 categories of liquid-phase hydrometeors. Results from a control simulation show that the model is capable to reproduce realistically the life cycle of a convective cloud including the production of warm rain.A discussion of the role of advection in bin-microphysics models is presented and sensitivity tests were performed regarding the order of advection. The results show that, although the global characteristics of all simulated clouds were similar, significant differences occur with respect to their microstructure, particularly close to the cloud edges, when the order of the advective scheme changes. The conclusion is that intermediate-order advection schemes can indeed be used in cloud-resolving simulations, as far only as the gross characteristics of the cloud/cloud system are being investigated, but not poor, low-order schemes. On the other hand, the sensitivity with respect to the advection suggests that the evaluation of cloud phenomena that occur in fine-scales, such as entrainment and certain microphysical and radiational processes, must require the use of accurate, higher-order schemes.     

Measuring and modeling vertical gradients in suspended sediments in the Solimões/Amazon River

Accurately measuring sediment flux in large rivers remains a challenge due to the spatial and temporal cross‐sectional variability of suspended sediment concentrations in conjunction with sampling procedures that fail to accurately quantify these differences. This study presents a field campaign methodology that can be used to improve the measurement of suspended sediment concentrations in the Amazon River or similarly large rivers. The turbidity signal and Rouse model are together used in this study to define the spatial distribution of suspended sediment concentrations in a river cross‐section, taking into account the different size fractions of the sediment. With this methodology, suspended sediment fluxes corresponding to each sediment class are defined with less uncertainty than with manual samples. This paper presents an application of this methodology during a field campaign at different gauging stations along a 3,000‐km stretch of the Solimões/Amazon River during low water and flood periods. Vertical concentration profiles and Rouse model applications for distinctive sediment sizes are explored to determine concentration gradients throughout a cross‐section of the river. The results show that coupling both turbidity technology and the Rouse model may improve our understanding of the spatial distribution of different sediments fractions sizes in the Solimões/Amazon River. These data are very useful in defining a pertinent monitoring strategy for suspended sediment concentrations in the challenging context of large rivers.