Identifying recent sources of organic matter enrichment and eutrophication trends at coastal sites using stable nitrogen and carbon isotope ratios in sediment cores

We studied the potential for using stable carbon and nitrogen isotope ratios in sediment profiles to trace external nutrient sources and eutrophication at four coastal sites in the Baltic Sea. The sites are characterized by various present and past activities in their catchments, including residential development, sugar processing, agriculture and fish farming. Radiometrically dated sediment cores were analysed for nutrient isotope ratios, organic carbon and total nitrogen. Background information was collected from historical sources, literature and water monitoring data. Despite the multiple organic enrichment sources, it was possible to identify individual sources and processes in the sediment profiles using stable isotope analysis of bulk sediment. The largest changes in δ¹⁵N values were seen at sites receiving urban wastewaters. The site that received effluents from a sugar cane (C₄-plant) refinery in the past showed a clear effect on δ¹³C values compared to the site that received wastewater from a sugar beet (C₃-plant) factory. Fish farming produced detectable, albeit minor changes in the sediment profile. Slightly lower δ¹³C values reflected the influence of fish feed and fish metabolism, and higher δ¹⁵N values likely indicated the influence of increased sediment denitrification. The land-sea connection via river discharge was observable in the overall δ¹³C levels of the sediment cores. Our results suggest that temporal changes in sources of organic matter enrichment can be detected in well-dated coastal sediment cores using nutrient stable isotope analyses, even at sites subjected to multiple impacts. There is not, however, a simple relationship between sediment stable isotope profiles and the eutrophication history of our study sites.     

The nitrate content of Greenland ice and solar activity

Past solar activity is studied based on analysis of data on the nitrate content of Greenland ice in the period from 1576–1991. Hundred-year (over the entire period) and quasi-five-year (in the middle of the 18th century) variations in the nitrate content are detected. These reflect the secular solar-activity cycle and cyclicity in the flare activity of the Sun.     

Bioavailability and radiocarbon age of fluvial dissolved organic matter (DOM) from a northern peatland-dominated catchment: effect of land-use change

The radiocarbon age and biodegradability of dissolved organic matter (DOM) from a northern peat-dominated river system was studied and the effects of land-use were compared. Samples were obtained from streams and ditches comprising sub-catchments of the Kiiminki River, Northern Finland. Sample sites included areas of natural mire, areas subjected to moderate disturbance (ditching to enhance forestry), and areas subjected to serious land use change (agriculture and peat excavation). The study employed a 55 day bioassay that measured the biodegradation potential of surface-water DOM. We identified release of modern (mean 6–13 year old) DOM from natural sites, and material aged up to 1,553 years from disturbed sites. The proportion of biodegradable DOC ranged from 4.1 to 17.9 %, and bacterial DOC removal was modelled using twin-pool and reactivity-continuum (beta distribution) approaches. Bacterial growth efficiency ranged from 0.11 to 0.26 between areas of different land use, and these relatively low values reflect the humic-rich DOM released from boreal peatland. Despite the range of land-use types studied, including intensive peatland excavation areas, there was no detectable relationship between the biological lability of DOM and its radiocarbon age.     

Variations in tree ring stable isotope records from northern Finland and their possible connection to solar activity

Within a project on climate in Europe during the past few hundred years we have collected a record on stable isotope ratios ¹³C/¹²C and ¹⁸O/¹⁶O in tree ring cellulose from pine trees in northern Finland. The records cover the time interval 1600–2002 AD and have an annual time resolution. The carbon stable isotope record from northernmost Finland correlates quite strongly with local growth period temperature. Statistical analysis of the carbon and oxygen stable isotope records reveals variations in the periods around 100, 11 and 3 years. A century scale connection between the ¹³C/¹²C record and solar activity is most evident. These results based on stable isotope records support previous evidences of a centennial solar-climatic link obtained for northern Finland using tree ring data.     

Physical properties and stratigraphy of surface snow in western Dronning Maud Land, Antarctica

Information about the spatial variations of snow properties and of annual accumulation on ice sheets is important if we are to understand the results obtained from ice cores, satellite remote sensing data and changes in climate patterns. The layer structure and spatial variations of physical properties of surface snow in western Dronning Maud Land were analysed during the austral summers 1999/2000, 2000/01 and 2003/04 in five different snow zones. The measurements were performed in shallow (1–2 m) snow pits along a transect extending 350 km from the seaward edge of the ice shelf to the polar plateau. These pits covered at least the last annual accumulation and ranged in elevation from near sea level to 2500 m a.s.l. The ع⁸O values and accumulation rates had a good linear correlation with the distance from the coast. The mean accumulation on the ice shelf was 312±28 mm water equivalent (w.e.); in the coastal region it was 215±43 mm w.e. and on the polar plateau it was 92±25 mm w.e. The mean annual conductivity and grain size values decreased exponentially with increasing distance from the ice edge, by 48%/100 km and 18%/100 km respectively. The mean grain size varied between 1.5 and 1.8 mm. Depth hoar layers were a common phenomenon, especially under thin ice crusts, and were associated with low dielectric constant values.     

A 520 year record of summer sunshine for the eastern European Alps based on stable carbon isotopes in larch tree rings

A 520-year stable carbon isotope chronology from tree ring cellulose in high altitude larch trees (Larix decidua Mill.), from the eastern European Alps, correlates more strongly with summer temperature than with summer sunshine hours. However, when instrumental records of temperature and sunshine diverge after AD1980, the tree ring time series does not follow warming summer temperatures but more closely tracks summer sunshine trends. When the tree ring stable carbon isotope record is used to reconstruct summer temperature the reconstruction is not robust. Reconstructed temperatures prior to the twentieth century are higher than regional instrumental records, and the evolution of temperature conflicts with other regional temperature reconstructions. It is concluded that sunshine is the dominant control on carbon isotope fractionation in these trees, via the influence of photosynthetic rate on the internal partial pressure of CO₂, and that high summer (July–August) sunshine hours is a suitable target for climate reconstruction. We thus present the first reconstruction of summer sunshine for the eastern Alps and compare it with the regional temperature evolution.