Paleosol at the Archean—Proterozoic contact in NW India revisited: Evidence for oxidizing conditions during paleo-weathering?

A number of fine-grained sericite bearing pelitic, schistose lithologies occur along the Archean (Banded Gneiss Complex)-Proterozoic (Aravalli Supergroup) contact (APC) in the Udaipur valley in NW Indian craton. These Al-rich lithologies (subsequently metamorphosed) have been described as ‘paleosols’, developed over a 3.3 Ga old Archean gneissic basement and are overlain by Paleoproterozoic Aravalli quartzite. The paleosol was developed between 2.5 and 2.1, coincident with the globally recognized Great Oxidation Event (GOE). In previous studies these paleosol sections were interpreted to have developed under reducing environment, however, the finding of a ‘ferricrete’ zone in the upper part of Tulsi Namla section (east of Udaipur) during the present study (in addition to earlier reported lithologies) has led to an alternative suggestion of oxygen-rich conditions during paleosol development. The Tulsi Namla paleosol section shows all the features characteristic of a complete paleosol section described from other Archean cratons. The paleosol includes sericite schist with kyanite as the prevalent Al-silicate in the lower part of profile while chloritoid and Fe-oxides typify the Fe-rich upper part. Alumina has remained immobile during the weathering process while Fe and Mn show a decrease in the lower part of the section and an abrupt rise in the upper part, in the ferricrete zone. The field and geochemical data indicate that the Tulsi Namla section is an in situ weathering profile and at least the upper part shows evidence of oxidizing conditions.     

Feature

Numerous world class mineral deposits make the Kola Peninsula a 'Mecca' for mineralogists, and key economic deposits make it one of Russia's most important industrial areas. For geologists there is the challenge of explaining how this situation has come about.     

Hybrid mafic dykes from Delwara Shear Zone,Mt. Abu,NW India

Mafic dykes intrude the composite Mt. Abu granite batholith as a minor and the last phase of magmatism. The dykes are sub-vertical, variable in width and visibly compact, however, features of alteration and shearing can be seen. The dykes occurring within the recently identified and described, Delwara Shear Zone (DWSZ), from the western margin of the Mt. Abu batholith are intensely to moderately sheared and intricately mixed with the host granitoids. The mafic dykes occurring within the shear zone bear evidence of assimilating the host granitoids during their ascent, seen as relicts, streaks and sub-rounded K-feldspar clasts in mafic dykes. The hybridization has resulted in unusual geochemical signatures of the mafic dykes such as higher silica levels, erratic and high incompatible trace element abundances and lack of any systematic trends. Mixing line calculations on the mafic dyke samples reveal between 30 to 60% felsic input into the mafic dykes. Mafic dykes outside the shear zone in the Mt. Abu are meter scale in width and generally free of felsic inclusions owing to small volumes of mafic melts. Large volume of mafic melts are required for assimilating up to 60% felsic component which has been identified as approximately 100 m wide zone within the DWSZ. Shearing has played an important role in providing the channel ways and for sustained high temperatures to allow such hybridization.     

Policy options to streamline the carbon market for agricultural nitrous oxide emissions

The majority of emissions of nitrous oxide – a potent greenhouse gas (GHG) – are from agricultural sources, particularly nitrogen fertilizer applications. A growing focus on these emission sources has led to the development in the United States of GHG offset protocols that could enable payment to farmers for reducing fertilizer use or implementing other nitrogen management strategies. Despite the development of several protocols, the current regional scope is narrow, adoption by farmers is low, and policy implementation of protocols has a significant time lag. Here we utilize existing research and policy structures to propose an ‘umbrella’ approach for nitrogen management GHG emissions protocols that has the potential to streamline the policy implementation and acceptance of such protocols. We suggest that the umbrella protocol could set forth standard definitions common across multiple protocol options, and then modules could be further developed as scientific evidence advances. Modules could be developed for specific crops, regions, and practices. We identify a policy process that could facilitate this development in concert with emerging scientific research and conclude by acknowledging potential benefits and limitations of the approach.

Key policy insights

• Agricultural greenhouse gas market options are growing, but are still underutilized

• Streamlining protocol development through an umbrella process could enable quicker development of protocols across new crops, regions, and practices

• Effective protocol development must not compromise best available science and should follow a rigorous pathway to ensure appropriate implementation

     

Activity-composition relations in FeTiO3-MnTiO3 ilmenite solid solutions from EMF measurements at 1050–1300 K

The activity of FeTiO₃ in the binary ilmenitepyrophanite (FeTiO₃-MnTiO₃) solid solution has been determined for the temperature range 1050–1300 K by displacement of the reaction: 2 FeTiO₃=2 Fe+2 TiO₂+O₂ in T-O₂ space, using an electrochemical technique with calcia- and yttria-stabilized zirconia solid electrolytes. The activities show small positive deviations from ideality, which, although the data are unusually precise, may be perfectly described by the simple regular solution model, with an interaction parameter, W _Fe-Mn ^ilm , of 2.2±0.3 kJ g-atom^–1, which is independent of temperature. This value, together with the experimental data on the partitioning of Fe and Mn between ilmenite and garnet (Pownceby et al. 1987), gives W _Fe-Mn ^gt =1.2±0.5 kJ g-atom^–1 for the almandine-spessartine (Fe₃Al₂Si₃O₁₂-Mn₃Al₂Si₃O₁₂) solid solution.     

Hydraulics of sediment-laden sheetflow and the influence of simulated rainfall

Laminar sheetflows, transporting sediment at their capacity rates, both with and without rainfall disturbance, were investigated. Values of flow depth and relative submergence were very small. In the flows without rainfall, measured velocities exceeded the predictions of the smooth-surface, clear-water laminar model by an average of 12 per cent. Reduced flow resistance due to high sediment concentrations may explain this result. Velocities in the rainfall-disturbed flows were not significantly different from the predictions of the smooth-surface, clear-water model, and the velocity reduction due to rainfall was about 12 per cent. Although the uniformity of rainfall intensity under the single-nozzle rainfall simulator is high, variation of momentum and kinetic energy fluxes along the 1-5 m long flume was significant. The rainfall angle of incidence was highly correlated with deviations from expected flow velocities in the upper and lower sections of the flume.