Model studies of the influence of O2 photodissociation parameterizations in the Schumann-Runge bands on ozone related photolysis in the upper atmosphere

A new parameterization for atmospheric transmission and O₂ photodissociation in the Schumann-Runge band region has been developed and tested with a 1D radiative-photochemical model. The parameterization is based on the O₂-column along the line of sight to the Sun and the local temperature. Line-by-line calculations have served as a benchmark for testing this method and several other, commonly used, parameterizations. The comparisons suggest that differences between the line-by-line calculations and currently accepted parameterizations can be reduced significantly by using the new method, particularly at large solar zenith angles. The production rate of O-atoms computed with this method shows less than 6% deviation compared to the line-by-line calculations at any altitude, all solar zenith angles and in all seasons. The largest errors are found toward the shorter wavelengths in the Schumann-Runge region at low altitudes. Transmittance is approximated to better than 4% at any altitude and/or solar zenith angle. The total O-production rate above 20 km is approximated to better than 2%. The new parameterization is easily implemented in existing photochemical models and in many cases it may simply replace the existing algorithm. The computational effort exceeds that of other parameterizations but in view of the total computation time needed for the actual calculation of the parameterized Schumann-Runge bands this should not lead to significant performance degeneration. The first 14 coefficients of the parameterization are included in this study. Both the complete sets of coefficients and a simple algorithm can be obtained by contacting the authors. A photochemical model study shows the largest effect of the parameterization method is on odd hydrogen concentrations. Subsequent interaction with an odd oxygen family causes differences in the ozone concentrations between the different parameterizations of more than 10% at selected altitudes. Although it is already established that deficiencies in the treatment of Schumann-Runge band absorption are unlikely to explain the current underestimation of ozone concentration at the stratopause in a variety of photochemical models, this study does show that the choice of parameterization has a large impact on the accuracy of the results at large solar zenith angles and in different seasons.     

Climate change and the long-term viability of the World’s busiest heavy haul ice road

Theoretical and Applied Climatology - Climate models project that the northern high latitudes will warm at a rate in excess of the global mean. This will pose severe problems for Arctic and...     

Age of the last major scabland flood of the Columbia Plateau in eastern Washington

Pumice layers of set S from Mount St. Helens can be correlated with certain ash beds associated with young flood deposits of the channeled scabland. The correlation points to an age of about 13,000 ¹⁴C yr B.P. for the last major flood to have crossed the scabland. Until recently, the last major episode of flooding was thought to be closer to 20,000 yr B.P., an age inferred chiefly from the relation of the flood to glacial events of the northern Rocky Mountains. Several investigations within the last few years have suggested that the last major flood occurred well after 20,000 yr B.P. Tentative correlations of ash beds of the scabland with set S pumice layers, the relations of flood and glacial events along the northwestern margin of the Columbia Plateau, and a radiocarbon date from the Snake River drainage southeast of the plateau all indicate an age much younger than 20,000 yr. The postulated age of about 13,000 yr B.P. is further supported by a radiocarbon date in the Columbia River valley downstream from the scabland tract. Basal peat from a bog on the Portland delta of Bretz, which is a downvalley deposit of the last major scabland flood, has been dated as 13,080 ± 300 yr B.P. (W-3404).     

Mount St. Helens a decade after the 1980 eruptions: magmatic models,chemical cycles,and a revised hazards assessment

Available geophysical and geologic data provide a simplified model of the current magmatic plumbing system of Mount St. Helens (MSH). This model and new geochemical data are the basis for the revised hazards assessment presented here. The assessment is weighted by the style of eruptions and the chemistry of magmas erupted during the past 500 years, the interval for which the most detailed stratigraphic and geochemical data are available. This interval includes the Kalama (A. D. 1480–1770s?), Goat Rocks (A.D. 1800–1857), and current eruptive periods. In each of these periods, silica content decreased, then increased. The Kalama is a large amplitude chemical cycle (SiO₂: 57%–67%), produced by mixing of arc dacite, which is depleted in high field-strength and incompatible elements, with enriched (OIB-like) basalt. The Goat Rocks and current cycles are of small amplitude (SiO₂: 61%–64% and 62%–65%) and are related to the fluid dynamics of magma withdrawal from a zoned reservoir. The cyclic behavior is used to forecast future activity. The 1980–1986 chemical cycle, and consequently the current eruptive period, appears to be virtually complete. This inference is supported by the progressively decreasing volumes and volatile contents of magma erupted since 1980, both changes that suggest a decreasing potential for a major explosive eruption in the near future. However, recent changes in seismicity and a series of small gas-release explosions (beginning in late 1989 and accompanied by eruption of a minor fraction of relatively low-silica tephra on 6 January and 5 November 1990) suggest that the current eruptive period may continue to produce small explosions and that a small amount of magma may still be present within the conduit. The gas-release explosions occur without warning and pose a continuing hazard, especially in the crater area. An eruption as large or larger than that of 18 May 1980 (0.5 km³ dense-rock equivalent) probably will occur only if magma rises from an inferred deep (7 km), relative large (5–7 km³) reservoir. A conservative approach to hazard assessment is to assume that this deep magma is rich in volatiles and capable of erupting explosively to produce voluminous fall deposits and pyroclastic flows. Warning of such an eruption is expectable, however, because magma ascent would probably be accompanied by shallow seismicity that could be detected by the existing seismic-monitoring system. A future large-volume eruption (0.1 km³) is virtually certain; the eruptive history of the past 500 years indicates the probability of a large explosive eruption is at least 1% annually. Intervals between large eruptions at Mount St. Helens have varied widely; consequently, we cannot confidently forecast whether the next large eruption will be years decades, or farther in the future. However, we can forecast the types of hazards, and the areas that will be most affected by future large-volume eruptions, as well as hazards associated with the approaching end of the current eruptive period.