Reprint of: Diagenetic controls on evolution of porosity and permeability in lower Tertiary Wilcox sandstones from shallow to ultradeep (200–6700 m) burial,Gulf of Mexico Basin,U.S.A.

Reservoir quality is a critical risk factor in deep to ultradeep reservoirs at depths >4.5 km. Analysis of Paleogene Wilcox sandstones on the upper Texas Gulf Coast provides insight into the evolution of reservoir quality during shallow to ultradeep burial diagenesis. Reduction of porosity and permeability with burial in Wilcox sandstones was evaluated using subsurface samples from 200 to 6700 m, at temperatures of 25–230 °C. Diagenesis and petrophysical properties were interpreted from petrographic data and core analyses. Wilcox sandstones are mostly lithic arkoses and feldspathic litharenites having an average composition of Q₅₉F₂₂R₁₉. Provenance did not change significantly during Wilcox deposition in this area, nor does average sandstone composition vary among lower, middle, and upper Wilcox sandstones. However, composition does vary with sequence-stratigraphic position; lowstand slope-fan deposits contain more rock fragments than do deposits from highstand or transgressive systems tracts. Given observations from this onshore dataset, Wilcox sandstones deposited in deepwater environments in the Gulf of Mexico are likely to contain more rock fragments than their linked highstand equivalents.     

Open-system chemical behavior in deep Wilcox Group mudstones,Texas Gulf Coast,USA

Wilcox Group mudstones have been mechanically and geochemically transformed over a temperature range of 20–200 °C. Our research controlled for provenance and age by sampling from five wells, parallel to the paleodepositional axis, all within the Houston delta system. Across the sampled depths, mudstone porosity has been reduced from ∼25 to <10% and bulk mineralogical change as documented by quantitative X-ray diffraction includes decreases in quartz, K-feldspar and kaolinite content whereas illite + illite − smectite, chlorite, and plagioclase increase. These mineral transformations transfer elements at a scale of less than 1 mm from one mineralogical form to another, however, X-ray fluorescence data suggest that among major elements only Al₂O₃ and TiO₂ are fully conserved within the system (trace-element ZrO₂ is also conserved). K₂O has been added to and SiO₂ released from the Wilcox Group mudstones. Cathodoluminescence and secondary electron imaging did not find this SiO₂ locally precipitated. We, therefore, document an open-system geochemical behavior.     

The role of antecedent groundwater heads in controlling transient aquifer storage and flood peak attenuation in karst watersheds

Transient storage of floodwaters in aquifers is known to attenuate peak flows in rivers and drive subsurface dissolution. Transient aquifer storage could be enhanced in watersheds overlying karst aquifers where caves facilitate surface and groundwater exchange. Few studies, however, have examined controls on, or magnitudes of, transient aquifer storage or flood peak attenuation in karstic watersheds. Here we evaluate flood peak attenuation with multiple linear regression analyses of 10 years of river and groundwater data from the Suwannee River, which flows over the karstic upper Floridan aquifer in north-central Florida and experiences frequent flooding. Regressions show antecedent river stage exerts the dominant control on magnitudes of transient aquifer storage, with recharge and time to peak having secondary controls. Specifically, low antecedent stages result in larger magnitudes of transient aquifer storage and thus greater flood attenuation than conditions of elevated antecedent stage. These findings suggest subsurface weathering, including cave formation and enlargement, caused by transient aquifer storage could occur on a more frequent basis in aquifers where groundwater table elevation is lowered due to anthropogenic or climatic influences. Our work also shows that measures of groundwater table elevation prior to an event could be used to improve predictive flood models. © 2018 John Wiley & Sons, Ltd.     

Limit state analysis of earthen slopes using dual continuum/FEM approaches

A framework alternative to that of classical slope stability analysis is developed, wherein the soil mass is treated as a continuum and in-situ soil stresses and strengths are computed accurately using inelastic finite element methods with general constitutive models. Within this framework, two alternative methods of stability analysis are presented. In the first, the strength characteristics of the soil mass are held constant, and the gravitational loading on the slope system is increased until failure is initiated by well-defined mechanisms. In the second approach, the gravity loading on the slope system is held constant, while the strength parameters of the soil mass are gradually decreased until well-defined failure mechanisms develop. Details on applying both of the proposed methods, and comparisons of their characteristics on a number of solved example problems are presented. Copyright © 1999 John Wiley & Sons, Ltd.     

Copper in the sediment and sea surface microlayer near a fallowed, open-net fish farm

Sediment and sea surface microlayer samples near an open-net salmon farm in Nova Scotia, were analysed for copper. Copper is a constituent of the feed and is an active ingredient of anti-foulants. The salmon farm was placed in fallow after 15years of production. Sampling was pursued over 27months. Elevated copper concentrations in the sediments indicated the farm site as a source. Bubble flotation due to gas-emitting sediments from eutrophication is a likely process for accumulating copper in the sea surface microlayer at enriched concentrations. Elevated and enriched concentrations in the sea surface microlayer over distance from the farm site led, as a result of wind-drift, to an enlarged farm footprint. The levels of copper in both sediments and sea surface microlayer exceeded guidelines for protection of marine life. Over the 27months period, copper levels persisted in the sediments and decreased gradually in the sea surface microlayer.     

Reply to the Discussion by Rose of Phelps et al. (2014) ‘Oceanographic and eustatic control of carbonate platform evolution and sequence stratigraphy on the Cretaceous (Valanginian–Campanian) passive margin,northern Gulf of Mexico’, Sedimentology, 61, 461–496

Discussion points raised by Rose ( 2016 ) concentrate on late Albian stratigraphic relationships between formations of the East Texas Basin and the San Marcos Arch of the Comanche Platform in the northern Gulf of Mexico. Criticisms of Phelps et al. (2014) regarding stratigraphic nomenclature, palaeogeography and regional lithostratigraphic correlations generally focus on interpretive aspects of the study or do not account for the full scope of published information. Revisions to the top Aptian–Albian Supersequence boundary by Rose are incompatible with the relative location of a subaerial unconformity, as well as deepening lithofacies trends and retrogradational stratigraphic patterns below the interpreted boundary. Rose's placement of the top Aptian–Albian Supersequence boundary precisely at the Albian–Cenomanian stage boundary also implies ca 1·4 Ma of diachroneity in second order sea‐level patterns between the northern Gulf of Mexico and other documented global sedimentary basins.     

Geochemical and metallogenic provinces: a discussion initiated by results from geochemical mapping across northern Fennoscandia

The concept of metallogenic province has won general acceptance in economic geology. It is agreed that metallogenic provinces offer good opportunities for exploration of new ore deposits. The concept of geochemical province is also established, but its exact meaning is disputable. In this paper, geochemical province is used as an abnormal spatial distribution of an element or element combination in a particular sample type as measured by a particular analytical technique. The practical consequences of this concept of geochemical provinces in mineral exploration seem not to have been fully utilized, although geochemical and metallogenic provinces could only be different manifestations of the same regional features. The location of geochemical provinces should be of greater importance in exploration than the location of metallogenic provinces, simply because a geochemical province can be identified early in an exploration program, while a metallogenic province cannot be defined until a number of ore discoveries has already been made. We have compared metallogenic provinces with geochemical provinces obtained by regional geochemical mapping in Fennoscandia (mainly data from the Nordkalott Project) and other places such as England, Wales, Germany and Alaska in order to study to what degree large-scale geochemical dispersion patterns can be associated with clusters of economically interesting mineral deposits.It is concluded that metallogenic provinces lie within or coincide with a number of geochemical provinces, some of which may have causal relationships with the ore deposits. It can be assumed that an enormous hierarchy of large and small geochemical provinces exist at the earth's surface. The main features of this system would be detectable by worldwide low-density geochemical mapping. Such mapping should be performed in order to shorten the time lapse between possible rises in the demand of certain raw materials and their supply. Worldwide geochemical mapping would also contribute to a better understanding of major geochemical processes of the Earth and provide baselines for environmental research.     

Rhizocarpon calibration curve for the Aoraki/Mount Cook area of New Zealand

Development of Rhizocarpon growth curve from the Aoraki/Mount Cook area of New Zealand provides a means to assess Little Ice Age glacier behaviour and suggests approaches that have wider application. Employing a sampling strategy based on large populations affords the opportunity to assess which of various metrics (e.g. single largest, average of five largest, mean of an entire population) best characterise Rhizocarpon growth patterns. The 98% quantile from each population fitted with a quadric curve forms a reliable representation of the growth pattern. Since this metric does not depend on the original sample size, comparisons are valid where sample strategy must be adapted to local situations or where the original sample size differs. For the Aoraki/Mount Cook area a surface 100 years old will have a 98% quantile lichen diameter of 34.3 mm, whereas a 200‐year‐old surface will have a lichen diameter of 73.7 mm. In the Southern Alps, constraints from the age range of calibration points, the flattening of the quadric calibration curve and ecological factors limit the useful age range to approximately 250 years. Copyright © 2005 John Wiley & Sons, Ltd.     

Sea level rise and tigers: predicted impacts to Bangladesh’s Sundarbans mangroves

The Sundarbans mangrove ecosystem, shared by India and Bangladesh, is recognized as a global priority for biodiversity conservation. Sea level rise, due to climate change, threatens the long term persistence of the Sundarbans forests and its biodiversity. Among the forests’ biota is the only tiger (Panthera tigris) population in the world adapted for life in mangrove forests. Prior predictions on the impacts of sea level rise on the Sundarbans have been hampered by coarse elevation data in this low-lying region, where every centimeter counts. Using high resolution elevation data, we estimate that with a 28 cm rise above 2000 sea levels, remaining tiger habitat in Bangladesh’s Sundarbans would decline by 96% and the number of breeding individuals would be reduced to less than 20. Assuming current sea level rise predictions and local conditions do not change, a 28 cm sea level rise is likely to occur in the next 50–90 years. If actions to both limit green house gas emissions and increase resilience of the Sundarbans are not initiated soon, the tigers of the Sundarbans may join the Arctic’s polar bears (Ursus maritimus) as early victims of climate change-induced habitat loss.     

Lateglacial and Holocene cosmogenic surface exposure age glacial chronology and geomorphological evidence for the presence of cold‐based glaciers at Nevado Sajama,Bolivia

Comparisons of palaeo‐equilibrium line altitudes between the Western and Eastern Cordilleras in the Central Andes are commonly based on the assumption that the tall outermost moraines visible in remotely sensed images of the Western Cordillera date to the Last Glacial Maximum (LGM). However, field investigation and geomorphic mapping at Nevado Sajama, Bolivia, indicates the tall moraines are relic features with shorter moraines overlying and in some cases extending beyond them. ³⁶Cl exposure ages from the shorter moraines suggest that they date to Lateglacial times ca. 16.9–10.2 ka. Although Lateglacial deposits have been found throughout the Central Andes, the extent of these deposits relative to LGM deposits varies both between the Western and Eastern Cordilleras and north‐to‐south along the Western Cordillera. In the Western Cordillera in the zone of easterly winds, the Lateglacial appears to be the most extensive glacial advance of the last glacial cycle. Geomorphic evidence also suggests that some Lateglacial moraines were deposited by cold‐based ice, a previously unreported finding in the tropical Andes. Retreat from other glacial features occurred at about 7.0–4.4 ka and 4.7–3.3 ka. These are the first directly dated Holocene glacial deposits in the Western Cordillera of Bolivia, and their presence suggests that the mid Holocene may not have been as warm and dry as previously thought. Copyright © 2008 John Wiley & Sons, Ltd.