A comparison of airborne eddy correlation and bulk aerodynamic methods for ocean-air turbulent fluxes during cold-air outbreaks

Four bulk schemes (LKB, FG, D and DB), with the flux-profile relationships of Liuet al. (1979), Francey and Garratt (1981), Dyer (1974), and Dyer and Bradley (1982), are derived from the viscous interfacial-sublayer model of Liuet al. These schemes, with stability-dependent transfer coefficients, are then tested against the eddy-correlation fluxes measured at the 50 m flight level above the western Atlantic Ocean during cold-air outbreaks. The bulk fluxes of momentum (), sensible heat (H), and latent heat (E) are found to increase with various von Kármán constants (k _M for k _H forH, andk _E forE). Except that the LKB scheme overestimates by 28% (46Wm^–2), on the average, the fluxes estimated by the four bulk schemes appear to be in fairly good agreement with those of the eddy correlation method (magnitudes of biases within 10% for , 17% forH, and 13% forE). The results suggest that the overall fluxes and surface-layer scaling parameters are best estimated by FG and thatk _H <k _E . On the average, the FG scheme underestimates by 10% (0.032N m^–2) andE by 4% (12Wm^–2), and overestimatesH by 0.3% (0.5W m^–2). The equivalent neutral transfer coefficients at 10 m height of the FG scheme compare well with some schemes of those tested by Blanc (1985).The relative importance of various von Kármán constants, dimensionless gradients and roughness lengths to the oceanic transfer coefficients is assessed. The dependence of transfer coefficients on wind speeds and roughness lengths is discussed. The transfer coefficients for andE agree excellently between LKB and FG. However, the ratio of the coefficient forH of LKB to that of FG, increasing with decreasing stability, is very sensitive to stability at low winds, but approaches the neutral value of 1.25 at high winds.     

THE EFFECTS OF EXTERNAL FORCING,DISSIPATION AND NONLINEARITY ON THE SOLUTIONS OF ATMOSPHERIC EQUATIONS*

Based on the primitive equations of the atmosphere,we study the effects of external forcing.dissipation and nonlinearity on the solutions of stationary motion and non-stationary motion.The results show that the asymptotic behavior of solutions of the forced dissipative nonlinear system is essentially different from that of the adiabatic non-dissipative system,the adiabatic dissipative system,the diabatic non-dissipative system and the diabatic dissipative linear system,and that the joint action of external forcing,dissipation and nonlinearity is the source of multiple equilibria.From this we can conclude that the important actions of diabatic heating and dissipation must be considered in the models of the long-term weather and the climate.     

Mineralogy and geochemistry of a Late Permian coal in the Dafang Coalfield, Guizhou, China: influence from siliceous and iron-rich calcic hydrothermal fluids

This paper describes the influence of siliceous and iron-rich calcic low-temperature hydrothermal fluids (LTHF) on the mineralogy and geochemistry of the Late Permian No. 11 Coal (anthracitic, R_r=2.85%) in the Dafang Coalfield in northwestern Guizhou Province, China. The No. 11 Coal has high contents of vein ankerite (10.2 vol.%) and vein quartz (11.4 vol.%), with formation temperatures of 85 and 180 °C, respectively, indicating that vein ankerite and vein quartz were derived from low-temperature calcic and siliceous hydrothermal fluids in two epigenetic episodes. The vein quartz appears to have formed earlier than vein ankerite did, and at least three distinct stages of ankerite formation with different Ca/Sr and Fe/Mn ratios were observed.The two types of mineral veins are sources of different suites of major and trace metals. Scanning electron microscope and sequential extraction studies show that, in addition to Fe, Mg, and Ca, vein ankerite is the dominant source of Mn, Cu, Ni, Pb, and Zn in the coal, and the contents of these five elements are as high as 0.09% and 74.0, 33.6, 185, and 289 μg/g, respectively. In contrast, vein quartz is the main carrier mineral for platinum-group elements (PGEs) Pd, Pt, and Ir in the coal, and the contents of Pd, Pt, and Ir are 1.57, 0.15, and 0.007 μg/g, respectively. Sequential extraction showed a high PGE content in the silicate fraction, up to 10.4 μg/g Pd, 1.23 μg/g Pt, and 0.05 μg/g Ir, respectively. It is concluded that the formation of ankerite and quartz and the anomalous enrichment of trace elements in the No. 11 Coal in the Dafang Coalfield, Guizhou, result from the influx of calcic and siliceous low-temperature hydrothermal fluids.     

环氧树脂/沸石纳米复合材料的制备及表征

提出了一种用原位插入法制取环氧树脂/沸石纳米复合材料的新方法, 详细探讨了钠化、有机化、环氧树脂插入、固化及制备环氧树脂/沸石纳米复合材料的条件, 在实验的基础上确定了最佳条件, 制成了纳米复合材料, 并用XRD和TEM对其结构进行了表征, 发现纳米复合材料的平均粒径在5 0~ 6 0nm之间, 同时力学性能有明显提高, 可用于高性能的工程塑料和高品质的粘合剂.      

New aromatic biomarkers and possible maturity indicators found in New Albany Shale extracts

Aromatic hydrocarbons from benzene extracts of New Albany Shale were characterized. A biomarker that has a molecular weight of 546 and a structural configuration consistent with that of an alkyl-aromatic hydrocarbon (C₄₀H₆₆) was tentatively identified. It was found that the relative concentrations of the biomarker are indicative of differing levels of thermal maturity of the shale organic matter. A 40-carbon bicyclic carotenoid (C₄₀H₄₈) is proposed as the geochemical precursor of this biomarker. Thermal maturity of the shale organic matter can also be differentiated by observing differences in “fingerprints” as obtained by field-ionization mass spectrometry on the aromatic hydrocarbon fraction. Using this technique, we found that the more mature shale samples from southeastern Illinois contain more low molecular weight extractable aromatic hydrocarbons and the less mature shale samples from northwestern Illinois contain more high molecular weight extractable aromatic hydrocarbons. It was demonstrated that field-ionization and tandem mass spectrometric techniques through fingerprint and individual compound identification, are useful for shale aromatic hydrocarbon fraction characterization and for thermal maturation interpretation.     

气候系统可预报性的全局研究

胞映射方法是对非线性系统进行全局分析的强有力工具。文中基于一个最大简化的地－气耦合模式,引入胞映射全局分析方法,对气候系统的可预报性进行了全局的研究。气候系统存在最大可预报期限,对于超过逐日预报可预报期限后的预报,用胞映射思想证明了平均值的可预报性,并得到了定量的结果。研究表明,耦合机制具有延长可预报期限的作用,观测精度的提高亦可延长可预报期限     

Gallium and germanium in the metal and silicates of L- and LL-chondrites

Concentrations of Ga and Ge in the metal of 31 L-, 8 LL- and 2 H-chondrites, and in the silicates of 12 L- and LL-chondrites have been determined by spectrophotometric methods. The ranges of Ga contents in the metal of L- and LL-chondrites are 1.1–36.9 ppm and 1.0–34.1 ppm, respectively. The Ge content in the metal is positively correlated with Ga and ranges from 89.1–160 ppm, and 126–308 ppm for L- and LL-chondrites, respectively. The Ga content in the silicates of L-chondrites varies from 4.0 to 8.9 ppm.The Ga and Ge contents in the metal are clearly lower in unequilibrated than in equilibrated L- and LL-group chondrites. Unequilibrated (type 3 and 4) and equilibrated (type 5 and 6) chondrites are well separated in the plots of Ga vs Ge in the metal and the L- and LL-groups are also well resolved. The Ga and Ge in the metal are well correlated with petrologic grade. This suggests that Ga and Ge variations in the metal are related to thermal metamorphism. There is evidence of an enrichment of Ga in the metal due to shock-reheating.     

数值天气预报中的两类反问题及一种数值解法──理想试验

针对数值预报中产生误差的两个来源提出了数值预报中存在着两类反问题。并在一维的非线性平流扩散方程上，用共轭方程的解法对提出的两类反问题作出了理想场的数值试验。试验结果表明，这种解反问题的方法非常有效。它利用＂观测资料＂所包含的时间演变的信息确定出了方程的初值或方程中误差订正项的空间分布状况。而且无论对＂观测资料＂的超定还是欠定都能得出较有意义的结果。因而有很大的利用前景。     

The activity of convectively coupled equatorial waves in CMIP3 global climate models

This study evaluates the convectively coupled equatorial waves in ten coupled general circulation models (GCMs) in the twentieth century experiment from the Coupled Model Intercomparison Project phase 3 of the World Climate Research Programme. The antisymmetric bands in all GCMs are weaker than in observations, and the mixed Rossby-gravity (MRG) wave seems to be a mixture of the equatorial Rossby (ER) and tropical depression-type (TD-type) waves rather than a mixture of the ER and inertiogravity waves found in observations. The simulated TD-type wave is more organized than in observations with a quasilinear wavenumber–frequency relationship. In most GCMs, the two observed activity centers of the MRG and TD-type waves over the southern Indian Ocean and the southwestern Pacific cannot be separated; only one wave activity center is found over the Maritime Continent. The observed northwestward propagation of the TD-type wave over the western North Pacific is also not well simulated in the GCMs. The simulated active season of the MRG and TD-type waves over the northern hemisphere during the boreal summer and fall is much shorter than in observations. The models from CCSR utilizing the Pan and Randall scheme with the convection suppression simulate the realistic Kelvin wave activity with the maximum activity near the equator, while the wave activities filtered for the Kelvin wave in the other GCMs are similar to the extratropical Rossby wave with the maximum activity at higher latitudes. Likewise, only these two models produce a realistic seasonal cycle of the Kelvin wave activity.     

Projections of climate change impacts on central America tropical rainforest

Tropical rainforest plays an important role in the global carbon cycle, accounting for a large part of global net primary productivity and contributing to CO₂ sequestration. The objective of this work is to simulate potential changes in the rainforest biome in Central America subject to anthropogenic climate change under two emissions scenarios, RCP4.5 and RCP8.5. The use of a dynamic vegetation model and climate change scenarios is an approach to investigate, assess or anticipate how biomes respond to climate change. In this work, the Inland dynamic vegetation model was driven by the Eta regional climate model simulations. These simulations accept boundary conditions from HadGEM2-ES runs in the two emissions scenarios. The possible consequences of regional climate change on vegetation properties, such as biomass, net primary production and changes in forest extent and distribution, were investigated. The Inland model projections show reductions in tropical forest cover in both scenarios. The reduction of tropical forest cover is greater in RCP8.5. The Inland model projects biomass increases where tropical forest remains due to the CO₂ fertilization effect. The future distribution of predominant vegetation shows that some areas of tropical rainforest in Central America are replaced by savannah and grassland in RCP4.5. Inland projections under both RCP4.5 and RCP8.5 show a net primary productivity reduction trend due to significant tropical forest reduction, temperature increase, precipitation reduction and dry spell increments, despite the biomass increases in some areas of Costa Rica and Panama. This study may provide guidance to adaptation studies of climate change impacts on the tropical rainforests in Central America.