Oil-weathering behavior in Arctic environments

Oil-weathering processes in ice-free subarctic and Arctic waters include spreading, evaporation, dissolution, dispersion of whole-oil droplets into the water column, photochemical oxidation, water-in-oil emulsification, microbial degradation, adsorption onto suspended particulate material, ingestion by organisms, sinking, and sedimentation. While many of these processes also are important factors in ice-covered waters, the various forms of sea ice (depending on the active state of ice growth, extent of coverage and/or decay) impart drastic, if not controlling, changes to the rates and relative importance of different oil-weathering mechanisms. Flow-through seawater wave-tank experiments in a cold room at −35°C and studies in the Chukchi Sea in late winter provide data on oil fate and effects for a variety of potential oil spill scenarios in the Arctic. Time-series chemical weathering data are presented for Prudhoe Bay crude oil released under and encapsulated in growing first-year columnar ice through spring breakup.     

States of maximum entropy production in a one-dimensional vertical model with convective adjustment

We investigate the hypothesis that the atmosphere is constrained to maximize its entropy production by using a one-dimensional (1-D) vertical model. We prescribe the lapse rate in the convective layer as that of the standard troposphere. The assumption that convection sustains a critical lapse rate was absent in previous studies, which focused on the vertical distribution of climatic variables, since such a convective adjustment reduces the degrees of freedom of the system and may prevent the application of the maximum entropy production (MEP) principle. This is not the case in the radiative-convective model (RCM) developed here, since we accept a discontinuity of temperatures at the surface similar to that adopted in many RCMs.
For current conditions, the MEP state gives a difference between the ground temperature and the air temperature at the surface ≈10 K. In comparison, conventional RCMs obtain a discontinuity ≈2K only. However, the surface boundary layer velocity in the MEP state appears reasonable (≈m s⁻¹). Moreover, although the convective flux at the surface in MEP states is almost uniform in optically thick atmospheres, it reaches a maximum value for an optical thickness similar to current conditions. This additional result may support the maximum convection hypothesis suggested by Paltridge (1978 ).     

Anatomy and origin of toplap in a mixed carbonate-clastic system, Seven Rivers Formation (Permian, Guadalupian), Guadalupe Mountains, New Mexico, USA

The Seven Rivers Formation exposed in Slaughter Canyon, Guadalupe Mountains, New Mexico, reveals complex relations between long- and short-term relative changes in sea-level, shelf configuration and sedimentation, which interacted to create a distinct toplap geometry. At least five sandstones diverge basinward from a prominent boundary unit marking the surface of toplap at the top of the Seven Rivers Formation and create a series of prograding, shingled clinoforms. The boundary unit is a horizontal, well-sorted, quartz arenite underlain across the shelf by peritidal carbonate or by other merging sandstones. Preserved palaeotopography is indicated by facies changes downdip and the presence of horizontal geopetal indicators in inclined beds. Near the boundary unit (updip), merging sandstones contain rare sedimentary structures including evaporite moulds and irregular fenestrae and are bounded above and below by peritidal carbonate with microbial laminae, fenestral fabrics and mudcracks. Laterally (downdip), the sandstone-bounding peritidal carbonate facies pass into subtidal carbonate facies (ooid-peloid-fusulinid-dasyclad-mollusc pack- and grainstone) and interbedded sandstones contain sedimentary structures such as ripple marks and trough to planar cross-stratification, as well as ooids, fusulinids and other carbonate grains. Toplap is interpreted to have developed by sediment bypass across a subaerially exposed shelf while sedimentation continued in still-submerged areas downdip from the shelf crest, and hence represents depositional toplap. Physical tracing of subaerial exposure surfaces suggests that the shoreline migrated up and down palaeoslope several times. The vertical component of five short-term shoreline migrations decreased during formation of the toplap geometry. Sea-level rose to approximately the same position following each fall to create the toplap geometry. This depositional toplap is the stratigraphic result of high-‘frequency’ relative changes of sea-level that combined to produce the larger-scale geometry. We suggest that changing amplitudes of relative sea-level may play a significant role in the stratigraphic evolution of platforms and that separating ‘short-term’and ‘long-term’relative sea-level may be ambiguous in such instances.     

A STATISTICAL FRAMEWORK FOR TREE‐RING RECONSTRUCTION OF HIGH‐MAGNITUDE MASS MOVEMENTS: CASE STUDY OF SNOW AVALANCHES IN EASTERN CANADA

This paper investigates the application of the peaks‐over‐threshold method in combination with fitting of the generalized Pareto distribution for estimating the frequency of high‐magnitude geomorphic events, on the basis of tree‐ring data. In particular, attention is focused on extreme value distribution of tree‐ring responses and in the minimum threshold or index number required to assure the past occurrence of high‐magnitude events. The objective is to set a threshold, adapted to the sample distribution, which will make the distinction between high‐magnitude years and remaining years, where the response of sampled trees is too weak to be attributed to a high‐magnitude geomorphic event. The statistical framework proposed is based on the statistics of extremes. Through the use of simple, strong and effective mathematics, this model should strengthen the position of dendrogeomorphology in the evaluation and management of natural hazards.     

An analysis of regional climate model performance over the tropical Americas. Part I: simulating seasonal variability of precipitation associated with ENSO forcing

Sea surface temperature (SST) anomalies associated with El Niño/Southern Oscillation (ENSO) constitute a major source of predictability in the tropics. We evaluate the ability of a regional climate model (the Rossby Centre Atmospheric Model; RCA) to downscale SST and large-scale atmospheric anomalies associated with ENSO. RCA is configured over the tropical east Pacific and tropical Americas and runs for the period 1979–2005, using European Centre for Medium-Range Weather Forecasts (ECMWF) lateral and surface boundary conditions. We study the ability of RCA to represent regional patterns of precipitation, with respect to both the climatology and interannual variability associated with ENSO. The latter is achieved by grouping the simulations into El Niño and La Niña composites and studying the delayed response of precipitation to SST forcing in four regions of Central and South America.
In this paper, we concentrate on seasonal mean timescales. We find that RCA accurately simulates the main features of the precipitation climatology over the four regions and also reproduces the majority of the documented regional responses to ENSO forcing. Furthermore, the model captures the variability in precipitation anomalies between different ENSO events. The model exhibits a wet bias over the northern Amazon and slightly overestimates the magnitude of ENSO anomalies over Central America.     

Holocene changes on a peatland in northwestern Ontario interpreted from testate amoebae (Protozoa) analysis

Radiocarbon-dating and analyses of fossil testate amoebae (Protozoa) have established changes in soil moisture conditions on the developing surface of a Sphagnum -dominated peatland near Emo in northwestern Ontario.
The distribution and composition of modern testate amoebae communities were studied from peatlands in the region of Ontario and Minnesota as a guide to interpreting fossil assemblages. Although the core spans all of the Holocene, fossil testate amoebae were recovered only from the part post-dating 6500 BP. Earliest testate amoebae assemblages associated with bryophytic and cyperaceous-rich fen peat are dominated by species in the genera Cyclopyxis and Centropyxis . By 5000 BP, Amphitrema Jraaum, Assulina muscorum, Heleopera sphugni and Hyalosphenia subjaoa become important species as Sphagnum-rich peat accumulated at the site. Present-day microtopographic differentiation probably developed during historic time when the site became progressively drier, as indicated by a change of Nebela griseola, N. militaris and Trigonopyxis arcula . Although it is possible to derive quantitative estimates of changing soil moisture conditions from testate amoebae, care should be taken in interpreting results, particularly from non-Sphagnum-rich peats, until more is learned about the distribution and ecology of modern faunas.     

Suspension and calibration of a sediment trap

The aim of this technical note is to introduce a new, simple construction of a buoy-carried, suspended sediment trap that meets given demands concerning design (geometry of vessels) and stability during the registration period. The device is based on a ball-and-socket joint in the center and two Plexiglas cylinders (D=5cm, H=30cm) on PVC plastic arms. The suspension consists of only three parts. To determine the optimal construction, the apparatus has been calibrated in a circulating flume at various water velocities.