Excitation mechanism of atmospheric pressure waves from the 1980 Mount St Helens eruption

Summary. Atmospheric pressure waves from the Mount St Helens eruption 1980 May 18 have been clearly recorded by a sensitive microbarograph at Berkeley, California. The record shows three types of waves with different group velocities. The pressure waves can be interpreted in terms of direct waves A1, antipodean travelling waves A2 and circumnavigating waves A3, all of which are composed of several acoustic-gravity modes propagated in the lower atmosphere. Synthetic barograms appropriate to the Berkeley station have been calculated on the basis of the dynamic response of the lower atmospheric structure, together with various assumptions of source properties. Comparisons between synthetic and observed barograms provide estimates for ranges of the time history of upward particle velocity at the source, source dimensions and the velocity of the source spreading over the blast zone, as well as for the average dissipation effects over the circumferential path. The results suggest that two major compression pulses on the A1 record correlate with the arrival of pressure waves from the first (lateral) blast and second (vertical) blast, although the inferred interblast time interval is not consistent with that estimated from seismic observations.     

The “Shiva Hypothesis”: Impacts, mass extinctions, and the galaxy

The “Shiva Hypothesis”, in which recurrent, cyclical mass extinctions of life on Earth result from impacts of comets or asteroids, provides a possible unification of important processes in astrophysics, planetary geology, and the history of life. Collisions with Earth-crossing asteroids and comets ≥ a few km in diameter are calculated to produce widespread environmental disasters (dust clouds, wildfires), and occur with the proper frequency to account for the record of five major mass extinctions (from ≥ 10⁸ Mt TNT impacts) and ~ 20 minor mass extinctions (from 10⁷–10⁸ Mt impacts) recorded in the past 540 million years. Recent studies of a number of extinctions show evidence of severe environmental disturbances and mass mortality consistent with the expected after-effects (dust clouds, wildfires) of catastrophic impacts. At least six cases of features generally considered diagnostic of large impacts (e.g., large impact craters, layers with high platinum-group elements, shock-related minerals, and/or microtektites) are known at or close to extinction-event boundaries. Six additional cases of elevated iridium levels at or near extinction boundaries are of the amplitude that might be expected from collision of relatively low-Ir objects such as comets. The records of cratering and mass extinction show a correlation, and might be explained by a combination of periodic and stochastic impactors. The mass extinction record shows evidence for a periodic component of about 26 to 30 Myr, and an ~ 30 Myr periodic component has been detected in impact craters by some workers, with recent pulses of impacts in the last 2–3 million years, and at ~ 35, 65, and 95 million years ago. A cyclical astronomical pacemaker for such pulses of impacts may involve the motions of the Earth through the Milky Way Galaxy. As the Solar System revolves around the galactic center, it also oscillates up and down through the plane of the disk-shaped galaxy with a half-cycle ~ 30±3 Myr. This cycle should lead to quasi-periodic encounters with interstellar clouds, and periodic variations in the galactic tidal force with maxima at times of plane crossing. This “galactic carrousel” effect may provide a viable perturber of the Oort Cloud comets, producing periodic showers of comets in the inner Solar System. These impact pulses, along with stochastic impactors, may represent the major punctuations in earth history.     

Illite K–Ar dating and crystal growth processes in diagenetic environments: a critical review

K–Ar dating of illitic minerals is commonly used in studies of diagenetic series applied to oil prospecting. In spite of a great number of specialized papers, some problems remain unresolved. These are mostly due to a misunderstanding of the argon accumulation process during illitization. Criteria for identifying detrital–authigenic mineral mixtures, crystal ripening, fast precipitation or continuous nucleation‐growth processes are discussed using K–Ar data available in the literature. Using different parameters, such as Δ_age (age_K–Ar ? age_strati), Δ_cryst (diagenetic age_K–Ar ? age_strati) or Δ_frac (age_{K–Arfraction} ?age_K–Arfinest), it is shown that the K–Ar age significance depends on the illite nucleation–growth processes. A ‘diagenetic age’ is obtained when these processes are rapid (the K₂O accumulation period is shorter than 2σ). If lower than this value, the K–Ar ratio depends on the proportions of new and old particles, respectively, which are controlled by the relative rates of nucleation, crystal growth and ripening.     

Longevity of fluorine-bearing tremolite on Venus

There is a general belief that hydrous minerals cannot exist on Venus under current surface conditions. This view was challenged when Johnson and Fegley (2000, Icarus 146, 301-306) showed that tremolite (Ca₂Mg₅Si₈O₂₂(OH)₂), a hydrous mineral, is stable against thermal decomposition at current Venus surface temperatures, e.g., 50% decomposition in 4 Ga at 740 K. To further explore hydrous mineral thermal stability on Venus, we experimentally determined the thermal decomposition kinetics of fluorine-bearing tremolite. Fluor-tremolite is thermodynamically more stable than OH-tremolite and should decompose more slowly. However how much slower was unknown. We measured the decomposition rate of fluorine-bearing tremolite and show that its decomposition is several times to greater than ten times slower than that of OH-tremolite. We also show that F-bearing tremolite is depleted in fluorine after decomposition and that fluorine is lost as a volatile species such as HF gas. If tremolite ever formed on Venus, it would probably also contain fluorine. The exceptional stability of F-bearing tremolite strengthens our conclusions that if hydrous minerals ever formed on Venus, they could still be there today.     

The solubility of iron sulphides in synthetic and natural waters at ambient temperature

A critical evaluation of literature values for the solubility products, K _sp ^NBS = [Fe²⁺][HS^–] Fe²⁺ HS^– (H _NBS ⁺ )^–1, of various iron sulphide phases results in consensus values for the pKs of 2.95 ± 0.1 for amorphous ferrous sulphide, 3.6 ± 0.2 for mackinawite, 4.4 ± 0.1 for greigite, 5.1 ± 0.1 for pyrrhotite, 5.25 ± 0.2 for troilite and 16.4 ± 1.2 for pyrite.Where the analogous ion activity products have been measured in anoxic freshwaters in which there is evidence for the presence of solid phase FeS, the values lie within the range of 2.6–3.22, indicating that amorphous iron sulphide is the controlling phase. The single value for a groundwater of 2.65 (2.98 considering carbonate complexation) agrees. In seawater four values range between 3.85 to 4.2, indicating that mackinawite or greigite may be the controlling phase. The single low value of 2.94 is in a situation where particularly high fluxes of Fe (II) and S (–II) may result in the preferential precipitation of amorphous iron sulphide. Formation of framboidal pyrite in these sulphidic environments may occur in micro-niches and does not appear to influence bulk concentrations. Calculations show that the formation of Fe₂S₂ species probably accounts for very little of the iron or sulphide in most natural waters. Previously reported stability constants for the formation of Fe (HS)₂ and (Fe (HS)₃)^– are shown to be suspect, and these species are also thought to be negligible in natural waters. In completely anoxic pore waters polysulphides also have a negligible effect on speciation, but in tidal sediments they may reach appreciable concentrations and lead to the direct formation of pyrite. Concentrations of iron and sulphide in pore waters can be controlled by the more soluble iron sulphide phase. The change in the IAP with depth within the sediment may reflect ageing of the solid phase or a greater flux of Fe (II) and S (–II) nearer the sediment surface. This possible kinetic influence on the value of IAPs has implications for their use in geochemical studies involving phase formation.     

The trouble with nature: Ambivalence in the lives of urban Australian environmentalists

The number and range of contests over the social production of nature is growing. Much environmentalist discourse, however, continues to appeal for unequivocal scientific support on clearly demarcated issues of pure, a-social nature. This paper explores the question of how participants in environmental movements view this demarcation in the context of their own lives. After introducing scholarly critique of dualistic ideas of nature and the ambivalence characteristic of environmentalist conceptions of nature, the paper draws upon a qualitative study with environmentalists in the Australian cities of Melbourne, Perth and Hobart. Inquiring into the interplay of discourse of nature and everyday worlds, interviews revealed a complex interdependence of dualistic and non-dualistic understandings of nature. This ecology of ideas was especially evident in spatial imaginaries of nature. Scientific terminology, social disaffection and pessimism were associated with abstract and mutually exclusive conceptions of society and nature. Reflections on personal experience, however, indicated more flexible and hopeful negotiations in everyday liminal spaces offering ‘the best of both worlds’. It is concluded that environmentalist resistance to dismantling of conceptual boundaries between society and nature may often stem not from failure to appreciate socionatural complexity, but from a strongly felt sense that the self can only truly be found in nature.     

Functional responses for zooplankton feeding on multiple resources: a review of assumptions and biological dynamics

Modelers often need to quantify the rates at which zooplankton consume a variety of species, size classes and trophic types. Implicit in the equations used to describe the multiple resource functional response (i.e. how nutritional intake varies with resource densities) are assumptions that are not often stated, let alone tested. This is problematic because models are sensitive to the details of these formulations. Here, we enable modelers to make more informed decisions by providing them with a new framework for considering zooplankton feeding on multiple resources. We define a new classification of multiple resource responses that is based on preference, selection and switching, and we develop a set of mathematical diagnostics that elucidate model assumptions. We use these tools to evaluate the assumptions and biological dynamics inherent in published multiple resource responses. These models are shown to simulate different resource preferences, implied single resource responses, changes in intake with changing resource densities, nutritional benefits of generalism, and nutritional costs of selection. Certain formulations are further shown to exhibit anomalous dynamics such as negative switching and sub-optimal feeding. Such varied responses can have vastly different ecological consequences for both zooplankton and their resources; inappropriate choices may incorrectly quantify biologically-mediated fluxes and predict spurious dynamics. We discuss how our classes and diagnostics can help constrain parameters, interpret behaviors, and identify limitations to a formulation's applicability for both regional (e.g. High-Nitrate-Low-Chlorophyll regions comprising large areas of the Pacific) and large-scale applications (e.g. global biogeochemical or climate change models). Strategies for assessing uncertainty and for using the mathematics to guide future experimental investigations are also discussed.