The significance and validity of integrating data obtained from a variety of analytical techniques to understand, elucidate and model kerogen's complex chemical structure is reported here using degradative (open and closed system pyrolysis, chemical oxidation), non-degradative (13C CP/MAS NMR) and optical (incident white light and blue light) methods. Seven Cambrian Alum Shale samples, ranging in maturity from immature to post-mature with respect to petroleum generation, were studied and were chosen for their simple geological history, uniform organic matter type and high organic carbon content. The Alum Shale kerogens, which primarily consist of algal organic matter, liberate low molecular weight gaseous and aromatic compounds on pyrolysis and give mostly branched dicarboxylic acids on chemical oxidation. 13C NMR spectroscopy shows that the Alum Shale kerogens are anomalously rich in oxygen-bearing functional groups (such as C = O, ArCO, CHO, CHxO), most of which apparently remain intact within the kerogen macro-molecule (KMM) through the diagenetic and catagenetic stages. Fragments released by different degradative techniques are quantified and the aromaticity (fa), O/C and relative proportions of various carbon types estimated by 13C NMR. A synthesis of these data has allowed us to better understand the chemistry of the Alum Shale kerogen. 相似文献
On May 13, 1996, a disastrous tornado hit the Tangail district of Bangladesh, killing more than 700 people and causing extensive damage to homes, crops, and livestock. This paper explores and analyzes how tornado victims adjusted to this destruction. Data collected from two study sites show that victims received emergency assistance from people both in neighboring areas and from more distant areas, as well as from government agencies and non-governmental organizations (NGOs). At both sites, NGOs played the leading role in minimizing the hardships of victims through extraordinary disaster relief and rehabilitation efforts. Because of the extensive support received, the tornado victims were able to return to their “normal” lives very quickly. This study concludes with several recommendations to help cope with future tornado disasters. 相似文献
This paper presents the study of normalized north–south asymmetry, cumulative normalized north–south asymmetry and cumulative difference indices of sunspot areas, solar active prominences (at total, low (?40°) and high (?50°) latitudes) and Hα solar flares from 1964 to 2008 spanning the solar cycles 20–23. Three different statistical methods are used to obtain the asymmetric behavior of different solar activity features. Hemispherical distribution of activity features shows the dominance of activities in northern hemisphere for solar cycle 20 and in southern hemisphere for solar cycles 21–23 excluding solar active prominences at high latitudes. Cumulative difference index of solar activity features in each solar cycle is observed at the maximum of the respective solar cycle suggesting a cyclic behavior of approximately one solar cycle length. Asymmetric behavior of all activity features except solar active prominences at high latitudes hints at the long term periodic trend of eight solar cycles. North–south asymmetries of SAP (H) express the specific behavior of solar activity at high solar latitudes and its behavior in long-time scale is distinctly opposite to those of other activity features. Our results show that in most cases the asymmetry is statistically highly significant meaning thereby that the asymmetries are real features in the N–S distribution of solar activity features. 相似文献
The objectives of this paper are to examine the extent of human injuries caused by Cyclone Sidr, which made landfall in Bangladesh
coast on November 15, 2007, and report on the circumstances, type and causes of injuries, along with selected risk factors
associated with such injuries. Relevant data was collected through a questionnaire survey administered among the cyclone victims.
Semi-structured interviews with key personnel were also conducted to obtain information regarding the circumstances causing
injuries and public response to care for the injured. The questionnaire survey data reveals that among the respondent families,
132 persons sustained various types of injuries. Since the respondent families comprised of 1,443 members, the injury rate
was 9.15%. All injured victims were treated either onsite or in local hospitals. The most common types of injuries were soft-tissue
injuries (cuts, bruises, and scrapes) and fracture/dislocations. The most common causes of injuries for survivors were associated
with falling trees. Analysis of risk factors reveals that age is significantly correlated with injuries. Both formal and informal
interviews suggest that injured persons and their family members were in general pleased with medical response they received
from various sources. Several recommendations have been suggested to reduce future cyclone-related injuries in Bangladesh. 相似文献
The regional impacts of future climate changes are principally driven by changes in energy fluxes. In this study, measurements on micrometeorological and biophysical variables along with surface energy exchange were made over a coniferous subtropical chir pine (Pinus roxburghii) plantation ecosystem at Forest Research Institute, Doon valley, India. The energy balance components were analyzed for two years to understand the variability of surface energy fluxes, their drivers, and closure pattern. The period covered two growth cycles of pine in the years 2010 and 2011 without and with understory growth. Net short wave and long wave radiative fluxes substantially varied with cloud dynamics, season, rainfall induced surface wetness, and green growth. The study clearly brought out the intimate link of albedo dynamics in chir pine system with dynamics of leaf area index (LAI), soil moisture, and changes in understory background. Rainfall was found to have tight linear coupling with latent heat fluxes. Latent heat flux during monsoon period was found to be higher in higher rainfall year (2010) than in lower rainfall year (2011). Higher or lower pre-monsoon sensible heat fluxes were succeeded by noticeably higher or lower monsoon rainfall respectively. Proportion of latent heat flux to net radiation typically followed the growth curve of green vegetation fraction, but with time lag. The analysis of energy balance closure (EBC) showed that the residual energy varied largely within ±30% of net available energy and the non-closure periods were marked by higher rainspells or forced clearance of understory growths. 相似文献
With a 2.4 million people living with Human Immunodeficiency Virus (HIV), India is among the countries in the world most vulnerable to the spread of HIV. This study focuses on understanding what makes female college students (ages 18–24) in Kolkata, India willing to comply with HIV/AIDS preventive measures; these students are widely believed to be at low risk of infection with HIV. Through a questionnaire survey, the data used in this study was collected from 232 female students attending five higher education institutes. Multiple regression analysis reveals that religion, household income, perception of whether preventive measures would hamper freedom, and respondents’ perception of the effectiveness of preventive measures all influence the students’ willingness to comply with preventive measures. Based on its findings, the study makes several recommendations to improve HIV/AIDS prevention in Kolkata and West Bengal, India. 相似文献
Buildings and other human-made constructions have been accepted as an indicator of human habitation and are identified as built-up area. Identification of built-up area in a region and its subsequent measurement is a key step in many fields of studies like urban planning, environmental studies, and population demography. Remote sensing techniques utilising medium resolution images (e.g. LISS III, Landsat) are extensively used for the extraction of the built-up area as high-resolution images are expensive, and its processing is difficult. Extraction of built land use from medium resolution images poses a challenge in regions like Western-Ghats, North-East regions of India, and countries in tropical region, due to the thick evergreen tree cover. The spectral signature of individual houses with a small footprint are easily overpowered by the overlapping tree canopy in a medium resolution image when the buildings are not clustered. Kerala is a typical case for this scenario. The research presented here proposes a stochastic-dasymetric process to aid in the built-up area recognition process by taking Kerala as a case study. The method utilises a set of ancillary information to derive a probability surface. The ancillary information used here includes distance from road junctions, distance from road network, population density, built-up space visible in the LISS III image, the population of the region, and the household size. The methodology employs logistic regression and Monte Carlo simulation in two sub processes. The algorithm estimates the built-up area expected in the region and distributes the estimated built-up area among pixels according to the probability estimated from the ancillary information. The output of the algorithm has two components. The first component is an example scenario of the built-up area distribution. The second component is a probability surface, where the value of each pixel denotes the probability of that pixel to have a significant built-up area within it. The algorithm is validated for regions in Kerala and found to be significant. The model correctly predicted the built-up pixel count count over a validation grid of 900 m in 95.2% of the cases. The algorithm is implemented using Python and ArcGIS. 相似文献
Debris flow has caused severe human casualties and economic losses in landslide-prone areas around the globe. A comprehensive understanding of the morphology and deposition mechanisms of debris flows is crucial to delineate the extent of a debris flow hazard. However, due to inherent complex field topography and varying compositions of the flowing debris, coupled with a lack of fundamental understanding about the factors controlling the geomaterial flow, interparticle interactions and its final settlement resulted in a limited understanding of the flow behaviour of the landslide debris. In this study, a physical model was set up in the laboratory to simulate and calibrate the debris flow using PFC, a distinct element modelling-based software. After calibration, a case study of the Varunavat landslide was taken to validate the developed numerical model. Following validation with an acceptable level of confidence, several models were generated to evaluate the effect of slope height, slope angle, slope profile, and grain size distribution of the dislodged geomaterial in the rheological properties of debris flow. Both qualitative and quantitative analysis of the landslide debris flow was performed. Finally, the utility of retaining wall and their effect on debris flow is also studied with different retaining wall positions along the slope surface.
Immediately following the May 2011 tornado, the city of Joplin, Missouri, initiated recovery efforts to rebuild the part of the community devastated by this event. In doing so, city officials introduced two new safety measures and recommended several others. The main objective of this paper is to explore the tornado survivors' compliance with the safety features recommended by the Joplin city authorities. Face‐to‐face interviews, as well as other methods, were used to survey respondents who were living within the tornado path (damage zones) at the time of the tornado. Results showed that 43 percent of all respondents implemented at least one recommended tornado measure in rebuild or repair their destroyed/damaged homes. Further, it was found that three variables considered here— rebuild or repair, damage zone category, and perceived tornado risk—were all significant contributors to a homeowner's decision to implement recommended tornado safety measures. The paper concludes with a recommendation for expanding tornado safety education among the respondents. 相似文献