Geochemical evolution of the Capim River kaolin, Northern Brazil

The Capim River kaolin, located in the eastern Brazilian Amazon, constitutes one of the most important kaolin deposits in the world. Known for its high whiteness, its noble application is in the paper industry. Studies were carried out on samples from the six facies of the deposit (sand kaolin, soft kaolin, lower transition facies, ferruginous crust, upper transition facies and flint kaolin) in order to trace its geochemical evolution. The kaolin developed at the expense of Cretaceous sandy–clayey sediments of the Ipixuna Formation. Intense lateritic processes characterized by ferruginization and deferruginization mechanisms led to the distinction of the different facies.     

DNAPL Characterization Methods and Approaches, Part 2: Cost Comparisons

Contamination from the use of chlorinated solvents, often classified as dense nonaqueous phase liquids (DNAPLs) when in an undissolved state, pose environmental threats to ground water resources worldwide. DNAPL site characterization method performance comparisons are presented in a companion paper (Kram et al. 2001). This study compares the costs for implementing various characterization approaches using synthetic unit model scenarios (UMSs), each with particular physical characteristics. Unit costs and assumptions related to labor, equipment, and consumables are applied to determine costs associated with each approach for various UMSs. In general, the direct-push sensor systems provide cost-effective characterization information in soils that are penetrable with relatively shallow (less than 10 to 15 m) water tables. For sites with impenetrable lithology using direct-push techniques, the Ribbon NAPL Sampler Flexible Liner Underground Technologies Everting (FLUTe) membrane appears to be the most cost-effective approach. For all scenarios studied, partitioning interwell tracer tests (PITTs) are the most expensive approach due to the extensive pre-and post-PITT requirements. However, the PITT is capable of providing useful additional information, such as approximate DNAPL saturation, which is not generally available from any of the other approaches included in this comparison.     

Hazard mapping based on macroseismic data considering the influence of geological conditions

The object of this study is to consider directly the influence of regional geological conditions on the assessment of seismic hazard. It is assumed that macroseismic data at individual locations contain, in an average way, the influence of geological conditions.A Data Base referring to 199 historical (5) and instrumental (194, in the 1947–1993 period) events with macroseismic information in 1195 locations of Portugal was built. For any given seismic event, whenever macroseismic information was available at a location (town, village, etc.), an EMS-92 intensity value was estimated. To each one of those locations a geological unit, representing the most common type of soil, was assigned, based on the Geological Portuguese Map at a scale 1:500 000; the geological units were grouped into three categories: soft, intermediate and hard soils.The Data Base was used to determine the attenuation laws in terms of macroseismic intensity for the three different geological site conditions, using multiple linear regression analysis. The reasonability of the laws was tested by (i) checking residual distributions and (ii) comparing the map of isoseismals of important earthquakes with the isoseismals generated by the attenuation curves derived for each one of the three different soil classes, taking into consideration the soil class of each site. The main results of attenuation modeling are: high dispersion on macroseismic intensity data; all the models predict intensity values, for short hypocentral distances, lower than the ones observed; and for some important analyzed earthquakes and for the observed range of distances, the models confirm the expectancy that macroseismic intensity increases from hard to soft soil.The approach to obtain the hazard assessment at each location consisted in the use of the attenuation law specifically derived for the class of soil of that particular location. This method, which considers the influence of the regional geology, was illustrated with the mapping of hazard for the country for several return periods. Comparison with previous maps not taking into consideration the regional geological conditions emphasizes the importance of this new parameter. It can be concluded that (i) soil segmentation is clearly the cause for hazard increase in the region to the north of Lisbon, especially at sites with soft and intermediate soils as the ones in lower Tagus valley; the maximum increase on hazard is, in any case, less than one degree; (ii) when geological conditions are disregarded in the attenuation regression analysis, hazard pattern is similar to the one obtained for the case of hard soil everywhere.     

From brightening to dimming in sunshine duration over the eastern and central Tibetan Plateau (1961–2005)

The Tibetan Plateau (TP) with an average elevation of over 4,000 m asl is the highest and most extensive highland in the world. We used monthly mean sunshine duration from the Chinese Meteorological Administration to examine the spatial and temporal variability of sunshine duration at 71 stations with elevations above 2,000 m asl in the eastern and central TP during the 1961–2005 period. The temporal evolution of the mean annual sunshine duration series shows a significant increase from 1961 to 1982 at a rate of 49.8 h/decade, followed by a decrease from 1983 to 2005 at a rate of ?65.1 h/decade, with an overall significant decrease at a rate of ?20.6 h/decade during the whole 1961–2005 period, which is mainly due to the summer and spring seasons. This confirms the evidence that sunshine duration in the TP ranges from brightening to dimming in accordance with sunshine duration trends in the rest of China. The surface solar radiation downwards from ERA-40 reanalysis data in the same region confirms the brightening/dimming phenomenon shown by the sunshine duration before/after the 1980s. Otherwise, additional climatic variables such as low cloud amount, total cloud amount, precipitation, relative humidity and water vapor pressure, in most cases, exhibit significant negative correlation with sunshine duration in the TP on an annual and seasonal basis before and after 1982, respectively. The trends of these variables suggest that changes in some of them might be related to the brightening and dimming detected with the use of sunshine duration measurements over the TP. We also hypothesize that the impact of anthropogenic aerosols upon the climatic variables analyzed cannot be rejected, especially in the significant increase in low cloud cover since approximately 1980.     

Bismuth‐melt trails trapped in cassiterite–quartz veins

Native bismuth in the form of metallic melt has been considered instrumental to the formation of some metallic ore deposits via a mechanism dubbed the “Liquid Bismuth Collector Model.” Here, we provide petrographical documentation of trail‐forming, μm‐sized blebs of native bismuth in cassiterite–quartz veins from the Santa Bárbara greisen Sn deposit in the Rondônia tin province of northern Brazil. These inclusions suggest the trapping of a Bi melt that took place during vein formation, in a mechanism similar to the entrapment of fluid inclusions.     

Lake sedimentary processes and vegetation changes over the last 45k cal a bp in the uplands of south-eastern Amazonia

This study addresses paleoclimate influences in a southern Amazonia ecotone based on multiproxy records from lakes of the Carajás region during the last 45k cal a bp. Wet and cool environmental conditions marked the initial deposition in shallow depressions with detrital sediments and high weathering rates until 40k cal a bp. Concomitantly, forest and C3 canga plants, along with cool-adapted taxa, developed; however, short drier episodes enabled expansion of C4 plants and diagenetic formation of siderite. A massive event of siderite formation occurred approximately 30k cal a bp under strong drier conditions. Afterwards, wet and cool environmental conditions returned and persisted until the Last Glacial Maximum (LGM). The LGM was marked by lake-level lowstands and subaerial exposure. The transition from the LGM to the Holocene is marked by the onset of oscillations in temperature and humidity, with an expansion of forest and canga plants. Cool taxa were present for the last time in the Carajás region ~ 9.5–9k cal a bp. After 10k cal a bp , shallow lakes became upland swamps due to natural infilling processes, but the current vegetation types and structures of the plateaus were acquired only after 3k cal a bp under wetter climatic conditions.     

Effect of climatic oscillations on flood occurrence on Papaloapan River,México,during the 1550–2000 period

This study presents a chronology of historical and measured flood events in the Papaloapan River basin of Mexico during 450 years. Twenty-eight historical floods were recorded during the period 1550–1948 on this river and one flood event (1969) in the instrumental era (1949–2000), of which 14 were extraordinary floods and only 15 were catastrophic ones. There were several flood-rich decades during 1860–1870, 1880–1890, 1920–1930 and 1940–1950. Wavelet analysis found a significant flooding periodicity of 58 years. The wavelet coherence analysis found that flooding had an in-phase relationship with the Atlantic Multidecadal Oscillation and also with the Pacific Decadal Oscillation. Logistic regression corroborated that there exists a positive relationship between floods events and these two natural climatic oscillations. The logistic regression model predicted correctly 92% of flood events.