Theoretical infrared spectra of some model polycyclic aromatic hydrocarbons: effect of ionization

In order to test the hypothesis of ionized polycyclic aromatic hydrocarbons (PAHs) as possible carriers of the UIR bands, we realized a computational exploration on selected PAHs of small dimension in order to identify which changes ionization would induce on their IR spectra. In this study we performed ab initio calculations of the spectra of neutral and positively ionized naphthalene, anthracene, and pyrene. The results are significantly important. The frequencies in the cations are slightly shifted with respect to the neutral species, but no general conclusion can be reached from the three molecules considered. By contrast, the relative intensities of most vibrations are strongly affected by ionization, leading to a much better agreement between the calculated CH/CC vibration intensity ratios and those deduced from observations.     

États de contraintes et mécanismes d'ouverture et de fermeture des bassins permiens du Maroc hercynien. L'exemple des bassins des Jebilet et des RéhamnaStates of stresses and opening/closing mechanisms of the Permian basins in Hercynian Morocco. The example of the Jebilet and Réhamna Basins

The fracturing analysis in the Permian basins of Jebilet and Rehamna (Hercynian Morocco) and the underlying terranes allowed us to suggest a model for their opening. Three tectonic episodes are distinguished: a transtensional episode NNE–SSW-trending (Permian I), occurring during the opening along sinistral wrench faults N70–110-trending, associated with synsedimentary normal faults; a transpressive episode ESE–WNW-trending (Permian II), initiating the closure, the normal faults playing back reverse faults and the N70 trending faults dextral wrench faults; a compressional episode NNW–SSE (post-Permian, ante-Triassic), accentuating the closure and the deformation and putting an end to the Tardi-Hercynian compressive movements. To cite this article: A. Saidi et al., C. R. Geoscience 334 (2002) 221–226.     

Soil salinity and vegetation cover change detection from multi-temporal remotely sensed imagery in Al Hassa Oasis in Saudi Arabia

Detecting soil salinity changes and its impact on vegetation cover are necessary to understand the relationships between these changes in vegetation cover. This study aims to determine the changes in soil salinity and vegetation cover in Al Hassa Oasis over the past 28 years and investigates whether the salinity change causing the change in vegetation cover. Landsat time series data of years 1985, 2000 and 2013 were used to generate Normalized Difference Vegetation Index (NDVI) and Soil Salinity Index (SI) images, which were then used in image differencing to identify vegetation and salinity change/no-change for two periods. Soil salinity during 2000–2013 exhibits much higher increase compared to 1985–2000, while the vegetation cover declined to 6.31% for the same period. Additionally, highly significant (p < 0.0001) negative relationships found between the NDVI and SI differencing images, confirmed the potential long-term linkage between the changes in soil salinity and vegetation cover.     

Late Quaternary-Holocene lake-level changes in the eastern margin of the Thar Desert,India

A study on two closed salt lake basins, Tal Chapar and Parihara in the eastern margin of the Thar Desert, Rajasthan, was carried out to unravel late Quaternary geomorphic evolution of these saline lakes. Both lakes are elliptical in shape bordered by stabilised dunes, and are oriented in a NE-SW direction, i.e., in the direction of the prevailing summer monsoon wind. Both lakes have been formed in the wind-shadow zones of isolated hills of Precambrian quartzite. Our study indicates that the late Quaternary sediments in the lakes began with the cyclic deposition of laminated fine silt layers (0.5 m thick), rich in organic matter, alternating with ripple cross-bedded sand layers (each ∼1.5–2 m thick). Sand layers that are moderately sorted are separated by laminated silt-clay layers with gypsum/calcite and this unit occurs in the upper most 4 m sequence in deeper sections. The presence of gypsum crystals within the laminated sediments suggests a high concentration of Ca in the inflowing water. At Parihara Lake the organic carbon-rich sediments at 95 cm depth was dated to 7,375 + 155/−150 year BP. At Tal Chapar radiocarbon dates of 7,190 + 155/−150 and 9,903 + 360/−350 was obtained from the sediments rich in organic carbon occurring at a depth of 1.35 m and 1.80 m, respectively. The study reveals strong hydrologic oscillations during the past ∼14,000 year BP (13,090 + 310/−300 year BP). Quaternary geomorphic processes, especially the strong aeolian processes during dry climatic phases, played a major role in the formation of the lake basins, as well as the fringing linear dunes. Geochemical and mineralogical analyses of the lacustrine sediments, supported by radiocarbon dates indicate the existence of an ephemeral lake earlier than ∼13,000 year BP as sediments began to be deposited in a lacustrine environment implying sustained runoff in the catchments. A freshwater lake formed between 9,000 year and 7,000 year BP. The lake dried periodically and this strong fluctuating regime continued until about ∼7,000 year BP. Mid-Holocene was wet and this was possibly due to higher winter rains A saline lake existed between 6,000 year and 1,300 year BP and finally present day semi arid conditions set in since 1,200 year BP. Remnants of a habitation site (hearth and charred bones) on stabilised dune at Devani near Tal Chapar were dated to 240 ± 120 year, while that at Gopalpura was dated to 335 ± 90 year. These historical sites on stabilised dunes were, according to the local accounts, settlements of people who used the lake brine for manufacturing salt.     

The aeolian sedimentation record of the Thar desert

A review of the aeolian sedimentary record of the Thar desert is presented. This includes a regional survey of the major dune forms, their genesis and their relationship to climate and other regional landforms. A key aspect of this work is the chronometry of the dunes using luminescence methods. Luminescence dating of sand has enabled quantification of the duration of the phases of sand aggradation and quiescence, time scales of dune migration and the dating of pedogenic carbonates. We demonstrate that the conventional wisdom of synchronicity of dune aggradation with glacial epoch is not true in the context of Thar sands and here only a short durationwindow of opportunity existed for dune aggradation. Luminescence ages further suggest that this window occurred during a transitional climatic regime from glacial to interglacial about 4–10 ka after the glacial epoch. Other inferences included are that:

Petrology, isotope geochemistry and chemical budgets of oceanic gabbros-seawater interactions in the Equatorial Atlantic

 Petrological and chemical variations, as well as oxygen and strontium isotopic data are presented for metagabbros from the Romanche and Vema fracture zones. These rocks were affected by several types and degrees of alterations ranging from slight hydrothermal alteration to complete amphibolitization. Five major kinds of alteration processes ranging from late-magmatic deuteric alteration (stage I) to low temperature (<150 °C) alteration (stage V) were identified. Water-rock interactions between 300 and 650 °C are the most dominant interactions resulting in the most prevailing secondary mineralogical assemblages which characterize the amphibolite and/or greenschist facies (amphibole ± plagioclase ± epidote ± titanite ± chlorite ± prehnite). Hydrothermal alteration of these gabbroic rocks results in isotopic exchanges between rocks and seawater-derived fluids. These exchanges lead to decrease of gabbroic δ¹⁸O toward values as low as +3.9‰, and larger Sr isotopic variations than other oceanic gabbroic rocks (⁸⁷Sr/⁸⁶Sr ratios shift to 0.7029–0.7051). Calculation of a chemical budget indicates that metagabbros are hydrated and enriched in Fe and probably in Mg and Cl, while Si, Ca and Ti are released to the hydrothermal fluids. In addition to metamorphic recrystallization and geochemical transformation, hydrothermal alteration of oceanic gabbros contributes to the control of the global ocean geochemistry. Received: 8 March 1999 / Accepted: 12 July 1999     

Bottom-up climate risk assessment of infrastructure investment in the Niger River Basin

The Niger River is the third largest river in the African continent. Nine riparian countries share its basin, which rank all among the world’s thirty poorest. Existing challenges in West Africa, including endemic poverty, inadequate infrastructure and weak adaptive capacity to climate variability, make the region vulnerable to climate change. In this study, a risk-based methodology is introduced and demonstrated for the analysis of climate change impacts on planned infrastructure investments in water resources systems in the Upper and Middle Niger River Basin. The methodology focuses on identifying the vulnerability of the Basin’s socio-economic system to climate change, and subsequently assessing the likelihood of climate risks by using climate information from a multi-run, multi-GCM ensemble of climate projections. System vulnerabilities are analyzed in terms of performance metrics of hydroelectricity production, navigation, dry and rainy season irrigated agriculture, flooding in the Inner Delta of the Niger and the sustenance of environmental flows. The study reveals low to moderate risks in terms of stakeholder-defined threshold levels for most metrics in the 21st Century. The highest risk levels were observed for environmental flow targets. The findings indicate that the range of projected changes in an ensemble of CMIP3 GCM projections imply only relatively low risks of unacceptable climate change impacts on the present large-scale infrastructure investment plan for the Basin.