The presence of anomalous trace element levels in present day Jamaican soils and the geochemistry of Late-Miocene or Pliocene phosphorites

High levels of Cd and Zn in Jamaican soils observed in geochemical surveys are related to the presence of phosphorites of possible Late-Miocene or Pliocene age. The trace element and REE geochemistry of the phosphorites, together with SEM studies, indicate a guano origin for the phosphorites. No specific host minerals for Cd could be identified in the fossiliferous phosphorite which is characterized by uniquely high levels of Cd, Zn, Ag, Be, U and Y. However, in the soil Cd is present in lithiophorite and a complex history of pedological development is preserved in the aluminous–goethite present in the soil. The unique guano signature is preserved in the soil despite the fact that guanos themselves have either not been observed or have been destroyed by continuing karst and soil development. The phosphorite geochemical signature can be traced in the data of a 1988 island-wide soil geochemical survey, identifying areas where the Palaeo-environment that supported bird ‘rookeries’ existed in the Late-Miocene or Pliocene.     

The capacity of marine plankton, macrophytes and particulate matter to adsorb Cu in the presence of Mg

A complexometric titration technique was employed to measure the total capacity of a variety of marine organisms to adsorb Cu²⁺. Measured adsorption capacities were 0.22 meq g⁻¹ for phytoplankton, 0.3–1.0 meq g⁻¹ for macrophytes, 1.0–2.5 meq g⁻¹ for zooplankton and 0.3 meq g⁻¹ for suspended particulate matter. The capacity of these materials to adsorb Cu²⁺ was reduced significantly in the presence of Mg²⁺ at seawater concentrations. Competition between Mg^t2+ and Cu²⁺ for adsorption sites at pH 6 is described by an average conditional equilibrium constant of 10^3.7. This constant is such that very little Cu²⁺ may be adsorbed onto particulates and marine phytoplankton in the presence of Mg²⁺. Further, primary productivity data and estimates of the detrital carbon sedimentation in Long Island Sound suggest that the flux of particulate carbon is insufficient to remove significant amounts of Cu from the water column to sediments by adsorption mechanisms.     

A finite element model of interaction between viscous free surface waves and submerged cylinders

This paper describes the simulation of the flow of a viscous incompressible Newtonian liquid with a free surface. The Navier–Stokes equations are formulated using a streamline upwind Petrov–Galerkin scheme, and solved on a Q-tree-based finite element mesh that adapts to the moving free surface of the liquid. Special attention is given to fitting the mesh correctly to the free surface and solid wall boundaries. Fully non-linear free surface boundary conditions are implemented. Test cases include sloshing free surface motions in a rectangular tank and progressive waves over submerged cylinders.     

Interpretation of spatial and temporal variations of hydrogen quadropole absorptions in the Jovian atmosphere observed during the 1972 apparition

During the 1972 apparition of Jupiter, we carried out a patrol of the (3,0) S(1) and (4,0) S(1) quadrupole lines of molecular hydrogen in the equatorial region and in bands bounded by ±15 and ±49° zenographic latitude from the McDonald and Table Mountain Observatories. At the center of the Jovian disk, we found evidence of temporal variability of both lines over the duration of our observing period. We employ a technique which takes into account all radiative transfer processes in an inhomogeneous model of Jupiter's atmosphere, and use it to derive the effective level of formation of the spectral lines and the relative abundance of hydrogen. In this way, we are able to correlate measured changes in the equivalent widths of the hydrogen lines with variations in cloud structure. The effective pressure level at which the (4,0) S(1) line is formed varies in the range 2 ± 0.5 to 1.3 ± 0.2 atm, while for the (3,0) S(1) line, the pressure varies between 1.6 ± 0.5 and 1 ± 0.4 atm. If these variations are interpreted in terms of changes in elevation of the top of a dense lower cloud deck, the elevation apparently varied with an amplitude of 25 km during the observational period.Spatial variations in the strengths of both lines were also found. Both lines are weaker at the east limb than at the center of the disk (15–19%) while the variations toward the west limb are less pronounced (5%). Similar center-to-limb variations were found in the latitude bands bounded by ±15 and ±49°, although the lines were stronger in the northern component at the time of the observations.     

The thermodynamic influence of subgrid orography in a global climate model

Assessments of the impacts of climate change typically require information at scales of 10 km or less. Such a resolution in global climate simulations is unlikely for at least two decades. We have developed an alternative to explicit resolution that provides a framework for meeting the needs of climate change impact assessment much sooner. We have applied to a global climate model a physically based subgrid-scale treatment of the influence of orography on temperature, clouds, precipitation, and land surface hydrology. The treatment represents subgrid variations in surface elevation in terms of fractional area distributions of discrete elevation classes. For each class it calculates the height rise/descent of air parcels traveling through the grid cell, and applies the influence of the rise/descent to the temperature and humidity profiles of the elevation class. Cloud, radiative, and surface processes are calculated separately for each elevation class using the same physical parametrizations used by the model without the subgrid orography parametrization. The simulated climate fields for each elevation class can then be distributed in post-processing according to the spatial distribution of surface elevation within each grid cell. Parallel 10-year simulations with and without the subgrid treatment have been performed. The simulated temperature, precipitation and snow water are mapped to 2.5-minute (~5 km) resolution and compared with gridded analyses of station measurements. The simulation with the subgrid scheme produces a much more realistic distribution of snow water and significantly more realistic distributions of temperature and precipitation than the simulation without the subgrid scheme. Moreover, the 250-km grid cell means of most other fields are virtually unchanged by the subgrid scheme. This suggests that the tuning of the climate model without the subgrid scheme is also applicable to the model with the scheme.     

Aptian to Coniacian (Early–Late Cretaceous) palynostratigraphy of the Gustav Group, James Ross Basin, Antarctica

The Gustav Group of the James Ross Basin, Antarctic Peninsula, forms part of a major Southern Hemisphere Cretaceous reference section. Palynological data, chiefly from dinoflagellate cysts, integrated with macrofaunal evidence and strontium isotope stratigraphy, indicate that the Gustav Group, which is approximately 2.6 km thick, is Aptian–Coniacian in age. Aptian–Coniacian palynofloras in the James Ross Basin closely resemble coeval associations from Australia and New Zealand, and Australian palynological zonation schemes are applicable to the Gustav Group. The lowermost units, the coeval Pedersen and Lagrelius Point formations, have both yielded early Aptian dinoflagellate cysts. Because the overlying Kotick Point Formation is of early to mid Albian age, the Aptian/Albian boundary is placed, questionably, at the Lagrelius Point Formation–Kotick Point Formation boundary on James Ross Island, and this transition may be unconformable. Although the Kotick Point Formation is largely early Albian on dinoflagellate cyst evidence, the uppermost part of the formation appears to be of mid Albian age. This differentiation of the early and mid Albian has refined the age of the formation, previously considered to be Aptian–Albian, based on macrofaunal evidence. The Whisky Bay Formation is of late Albian to latest Turonian age on dinoflagellate cyst evidence and this supports the macrofaunal ages. Late Albian palynofloras have been recorded from the Gin Cove, lower Tumbledown Cliffs, Bibby Point and the lower–middle Lewis Hill members. However, the Cenomanian age of the upper Tumbledown Cliffs and Rum Cove members, based on molluscan evidence, is not supported by the dinoflagellate cyst floras and further work is required on this succession. The uppermost part of the Whisky Bay Formation in north-west James Ross Island is of mid to late Turonian age and this is confirmed by strontium isotope stratigraphy. The uppermost unit, the Hidden Lake Formation, is Coniacian in age on both palaeontological and strontium isotope evidence. The uppermost part of the formation appears to be early Santonian based on dinoflagellate cysts, but strontium isotope stratigraphy constrains this as being no younger than late Coniacian. This refined palynostratigraphy greatly improves the potential of the James Ross Basin as a major Cretaceous Southern Hemisphere reference section.     

Site effects at a vertical accelerometer array near Paducah, Kentucky

The downhole vertical accelerometer array VSAP near Paducah, KY, consists of three-component accelerometers at the surface, the top of the McNairy Formation (−41 m), and the top of the Paleozoic bedrock (—99 m). The array is at the northern end of the Mississippi Embayment, and it was installed to verify the ground-motion modeling for the site, assuming a significant earthquake in the New Madrid Seismic Zone. Accelerograms from 4.2 and 2.0 m_b earthquakes were used to check aspects of the modeling pertaining to linear behavior of the soil column, and to review the soil column models derived by drilling and geotechnical methods and through the use of high-resolution P- and SH-wave seismic refraction in reflection techniques. Results of the study indicate that for the linear case the soil column models derived by the two techniques are equivalent, and that the most important boundary in the soil column, with respect to amplification of the ground motions, is the interface between the limestone bedrock and soil.     

Precise/ Small Sample Size Determinations of Lithium Isotopic Compositions of Geological Reference Materials and Modern Seawater by MC-ICP-MS

The Li isotope ratios of four international rock reference materials, USGS BHVO-2, GSJ JB-2, JG-2, JA-1 and modern seawater (Mediterranean, Pacific and North Atlantic) were determined using multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS). These reference materials of natural samples were chosen to span a considerable range in Li isotope ratios and cover several different matrices in order to provide a useful benchmark for future studies. Our new analytical technique achieves significantly higher precision and reproducibility (< ± O.3%o 2s) than previous methods, with the additional advantage of requiring very low sample masses of ca . 2 ng of Li.