江西德兴铜矿区水系的Cu同位素地球化学特征及其地质意义

江西德兴铜矿水系样的δ65Cu值具有极大的变化范围(-5.8‰~+24.4‰),是迄今为止已报道发现的最大的Cu同位素分馏值。水体中铜的来源可分为黄铜矿源和黄铁矿源,二者具有明显不同的Cu同位素特征。根据水体的Cu同位素值分布特征,圈出了流经矿体(矿体上方)水、矿体外围水和尾矿库水3个源区。水体中的Cu主要以离子态和微粒态存在,二者具有明显不同的65Cu特征,尾矿库中黄铁矿65Cu对水体的Cu同位素组成具有较大的影响作用。Cu同位素在示踪找矿及地质环境监测方面具有良好的应用潜力。     

Derivation of a curve number and kinematic-wave based flood frequency distribution

Abstract

The physically-based flood frequency models use readily available rainfall data and catchment characteristics to derive the flood frequency distribution. In the present study, a new physically-based flood frequency distribution has been developed. This model uses bivariate exponential distribution for rainfall intensity and duration, and the Soil Conservation Service-Curve Number (SCS-CN) method for deriving the probability density function (pdf) of effective rainfall. The effective rainfall-runoff model is based on kinematic-wave theory. The results of application of this derived model to three Indian basins indicate that the model is a useful alternative for estimating flood flow quantiles at ungauged sites.     

Atmospheric ultrafine aerosol number concentration and its correlation with vehicular flow at two sites in the western Himalayan region: Kullu-Manali,India

The concentration of ultrafine aerosol particles of aitken and nucleation mode having size in the range of 1–20 nm was monitored with water-based Condensation Particle Counter. The monitoring was carried out from midnight-to-midnight in every alternate day on a fortnightly basis to represent summer, monsoon and winter (autumn) seasons of 2008 at Mohal (1154 m amsl) and Kothi (2530 m amsl) in Kullu-Manali area of the northwestern Himalayan region of India. The results indicate that diurnal pattern has faint bimodal structure with two peaks, one in morning and the other in evening at both the sites but it is not as distinct as found in plains. There is rather a constant particle density pattern of large magnitude consistent with vehicular movement from morning till evening. The monthly 24 h average particle density gradually picks up from January, increases rapidly in summer months and then decreases in monsoon season at Mohal but at Kothi it keeps on rising from April to October with a slight more increase in September. The particle density is more in summer than in monsoon season at Mohal, a trend opposite to plains. It may be due to the development of warm thermal layer on valley floor while a cold layer develops along snowy hilltops in winter leading to convection of fine particle up the slopes of valley during daytime. At Kothi, the trend is same as it is in continental plains but opposite to Mohal. The relatively more value of particle density in September and October at both the sites may be due to month long International Kullu Dussehra fair in the valley. The vehicular survey conducted agrees well with entire study period averaged diurnal variations and monthly 24 h averaged value of fine particle density. The average value of ultrafine particle density at each hour of a day for entire study period is 20369 ± 1230 Ncm^− 3 and 14389 ± 1464 Ncm^− 3 at Mohal and Kothi sites, respectively. The comparison with earlier results shows a significant increase indicating impact of vehicular onslaught on pure air of this hilly region.     

Past as prologue: an innovation-diffusion approach to additionality

The ‘additionality’ criterion for the Clean Development Mechanism (CDM) (which is key to ensuring that CDM projects lead to real and additional emission reductions) has been a topic of much analysis and discussion. A number of different approaches, including those based on financial, barrier and market-penetration criteria, have been suggested as a test for additionality. A simple test for additionality is proposed that draws on the framework of the diffusion of innovations, especially the risk profile of adopters of new technologies or innovations. This approach has the potential to streamline the assessment for additionality, although it will require data on the rate of implementation of specific technologies or innovations.     

Projections of SO2, NOx and carbonaceous aerosols emissions in Asia

Estimates of Asian emissions of air pollutants and carbonaceous aerosols and their mid-term projections have been changing significantly in the last years. The remote sensing community has shown that increase in NO _x in Central East Asia is much stronger than any of the emission inventories or projections indicated so far. A number of studies reviewing older estimates appeared. Here, we review the key contributions and compare them to the most recent results of the GAINS model application for Asia and to the SRES projections used in the IPPC work. The recent projections indicate that the growth of emissions of SO₂ in Asia should slow down significantly towards 2010 or even stabilize at the current level. For NO _x , however, further growth is projected although it will be most likely slower that in the last decade, owing to introduction of measures in transport. Emissions of carbonaceous aerosols (black carbon and organic carbon) are expected to decline after 2010, largely due to reduced use of biofuels in residential sector and efficiency improvements. The estimates of these emissions are burdened with significantly larger uncertainties than SO₂ and NO _x ; even for the year 2000 the differences in estimates between studies are up to a factor of 2.     

First-principles Study on Equilibrium Sn Isotope Fractionations in Hydrothermal Fluids

Tin (Sn) isotope geochemistry has great potential in tracing geological processes. However, lack of equilibrium Sn isotope fractionation factors of various Sn species limits the development of Sn isotope geochemistry. Equilibrium Sn isotope fractionation factors (124Sn/116Sn and 122Sn/116Sn) among various Sn(II, IV) complexes in aqueous solution were calculated using first-principles calculations. The results show that the oxidation states and the change of Sn(II, IV) species in hydrothermal fluids are the main factors leading to tin isotope fractionation in hydrothermal systems. For the Sn(IV) complexes, Sn isotope fractionation factors depend on the number of H2O molecules. For the Sn(II) complexes, the Sn isotope fractionation between Sn(II)?F, Sn(II)?Cl and Sn(II)?OH complexes is mainly affected by the bond length and the coordination number of anion, whereas the difference in 1000lnβ values of Sn(II)?SO4 and Sn(II)?CO3 complexes is insignificant with the change of anion coordination number. By comparing the 1000lnβ values of all Sn(II, IV) complexes, the enrichment trend in heavy Sn isotopes is Sn(IV) complexes > Sn(II) complexes. The equilibrium Sn isotopic fractionation factors enhance our understanding of the tin transportation and enrichment processes in hydrothermal systems.     

Fe-Cu-Zn同位素在矿床学和找矿勘查中的应用

金属稳定同位素已经广泛应用于矿床学研究以及找矿勘查。金属来源及其成矿过程是金属矿床研究以及找矿勘查中重点关注的基本核心问题。金属稳定同位素这项新技术进一步提高了我们对地壳中金属来源、迁移和富集的认识。这项新技术的优点是我们可以直接从矿石矿物本身获取信息。在本文中,我们重点关注矿石、水、岩石、土壤、植物等测量出的Fe-Cu-Zn同位素分馏,聚焦于Fe-Cu-Zn同位素从最深部岩浆系统开始一直向上延伸到浅部表生系统的过程中Fe-Cu-Zn同位素如何应用于矿床学研究以及找矿勘查,试图展示这些相对较新的技术可以提供的潜在应用范围。经过系统研究和总结,我们认为金属稳定同位素数据可以从三方面加以利用。首先,地表的植物、水、风化的岩石以及土壤中产生的较大的同位素分馏可以作为地下矿产勘查的指示标志;第二,矿区范围内金属稳定同位素往往具有系统的空间变化规律,可以指示成矿热液空间演化模式和矿体延伸方向;第三,金属元素作为成矿元素,其同位素可以直接有效地约束矿石的形成过程、成因以及源区特征。     

Atmospheric correction for sea surface temperature retrieval from single thermal channel radiometer data onboard Kalpana satellite

An atmospheric correction method has been applied on sea surface temperature (SST) retrieval algorithm using Very High Resolution Radiometer (VHRR) single window channel radiance data onboard Kalpana satellite (K-SAT). The technique makes use of concurrent water vapour fields available from Microwave Imager onboard Tropical Rainfall Measuring Mission (TRMM/TMI) satellite. Total water vapour content and satellite zenith angle dependent SST retrieval algorithm has been developed using Radiative Transfer Model [MODTRAN ver3.0] simulations for Kalpana 10.5–12.5 μm thermal window channel. Retrieval of Kalpana SST (K-SST) has been carried out for every half-hourly acquisition of Kalpana data for the year 2008 to cover whole annual cycle of SST over Indian Ocean (IO). Validation of the retrieved corrected SST has been carried out using near-simultaneous observations of ship and buoys datasets covering Arabian Sea, Bay of Bengal and IO regions. A significant improvement in Root Mean Square Deviation (RMSD) of K-SST with respect to buoy (1.50–1.02 K) and to ship datasets (1.41–1.19 K) is seen with the use of near real-time water vapour fields of TMI. Furthermore, comparison of the retrieved SST has also been carried out using near simultaneous observations of TRMM/TMI SST over IO regions. The analysis shows that K-SST has overall cold bias of 1.17 K and an RMSD of 1.09 K after bias correction.     

First results from imaging riometer installed at Indian Antarctic station Maitri

Cosmic noise absorption (CNA) measurred by imaging riometer, is an excellent tool to passively study the high latitude D-region ionospheric conditions and dynamics. An imaging riometer has been installed at Indian Antarctic station Maitri (geographic 70.75°S, 11.75°E; corrected geomagnetic 63.11°S, 53.59°E) in February 2010. This is the first paper using the imaging riometer data from Maitri. The present paper introduces the details of this facility, including its instrumentation, related CNA theory and its applications. Sidereal shift of around 2 hours in the diurnal pattern validates the data obtained from the newly installed instrument. Moreover, the strength of cosmic noise signal on quiet days also varies with months. This is apparently due to solar ionization of D-region ionosphere causing enhanced electron density where collision frequency is already high. The main objective of installing the imaging riometer at Maitri is to study magneotspheric–ionospheric coupling during substorm processes. In the current study, we present two typical examples of disturbed time CNA associated with storm-time and non-storm time substorm. Results reveal that CNA is more pronounced during storm-time substorm as compared to non-storm time substorm. The level of CNA strongly depends upon the strengthening of convectional electric field and the duration of southward turning of interplanetary magnetic field before the substorm onset.