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The long-path differential optical absorption spectroscopy(LP-DOAS)technique was developed to mea- sure nighttime atmospheric nitrate radical(NO_3)concentrations.An optimized retrieval method,resulting in a small residual structure and low detection limits,was developed to retrieve NO_3.The time series of the NO_3 concentration were collected from 17 to 24 March,2006,where a nighttime average value of 15.8 ppt was observed.The interfering factors and errors are also discussed.These results indicate that the DOAS technique provides an essential tool for the quantification of NO_3 concentration and in the study of its effects upon nighttime chemistry. 相似文献
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