Radar observations of Itokawa in 2004 and improved shape estimation

Abstract— We present June 2004 radar images of asteroid 25143 Itokawa (1998 SF36) that improve upon the longitude‐latitude coverage of images obtained in 2001 by Ostro et al. (2004) and use the 2001–2004 data to refine that paper's constraints on Itokawa's shape. The 2004 images, the first of the asteroid's southern side, look distinctly different from the 2001 images, revealing leading edges that are much more curved and rugged than the nearly convex leading edges seen at northern latitudes in 2001. Itokawa is shaped like a slightly asymmetrical, bent, lumpy ellipsoid with dimensions along the principal axes within 10% of 594 times 320 times 288 m. To illustrate the uncertainty space associated with shape reconstruction from images with suboptimal orientational coverage, we present two alternative three‐dimensional models of the object.     

Argillite debris converted to bauxite during karst weathering: evidence from immobile element geochemistry at the Olmedo Deposit, Sardinia

The Olmedo bauxite deposit occurs in the Nurra district of northwest Sardinia. It forms a stratiform horizon in Cretaceous limestone and marl. Uplift in mid-Cretaceous had exposed recently deposited limestone to karst weathering, and a layer of argillaceous debris accumulated on its surface and was partly converted to bauxite. Intermediate products were desiccated marl, bauxitic argillite and argillaceous bauxite. Subsidence followed, and the bauxite was preserved by the deposition of late Cretaceous limestone and other sediments. Uplift in Oligocene-Miocene time, with ensuing erosion, exposed the bauxite horizon to its present configuration. Concentrations of normative minerals illustrate chemical processes and the build-up of Al in the bauxite horizon. Plots of chemical data and correlation coefficients show that Al, Ti, Zr, Nb, Th, Cr and V were immobile during the bauxitization process. Mass changes point to large net removal of Si, Mg and K from the system, although some of this material and slightly mobile Al were reprecipitated in the underlying argillite and altered marl. Immobile element ratios trace the source of the bauxite to the underlying argillaceous limestone. Al in the bauxite was accumulated from the degradation of 25 to 50 m of the argillaceous limestone. Received: 10 June 1996 / Accepted: 15 April 1997     

Long-term changes in summer phytoplankton communities of the open northern Baltic Sea

Changes in the biomass and species composition of phytoplankton may reflect major shifts in environmental conditions. We investigated relationships between the late summer biomass of different phytoplankton taxa and environmental factors, and their long-term (1979–2003) trends in two areas of the Baltic Sea, the northern Baltic proper (NBP) and the Gulf of Finland (GF), with statistical analyses. An increasing trend was found in late summer temperature and chlorophyll a of the surface water layer (0–10 m) in both areas. There was also a significant decrease in summer salinity and an increase in winter dissolved inorganic nitrogen to phosphorus (DIN:DIP) ratio in the NBP, as well as increases in winter DIN concentrations and DIN:SiO₄ ratio in the GF. Simultaneously, the biomass of chrysophytes and chlorophytes increased in both areas. In the NBP, also the biomass of dinophytes increased and that of euglenophytes decreased, whereas in the GF, cyanobacteria increased and cryptophytes decreased. Redundancy analysis (RDA) indicated that summer temperature and winter DIN concentration were the most important factors with respect to changes in the phytoplankton community structure. Thus, the phytoplankton communities seem to reflect both hydrographic changes and the ongoing eutrophication process in the northern Baltic Sea.     

Combining shock barometry with numerical modeling: Insights into complex crater formation—The example of the Siljan impact structure (Sweden)

Siljan, central Sweden, is the largest known impact structure in Europe. It was formed at about 380 Ma, in the late Devonian period. The structure has been heavily eroded to a level originally located underneath the crater floor, and to date, important questions about the original size and morphology of Siljan remain unanswered. Here we present the results of a shock barometry study of quartz‐bearing surface and drill core samples combined with numerical modeling using iSALE. The investigated 13 bedrock granitoid samples show that the recorded shock pressure decreases with increasing depth from 15 to 20 GPa near the (present) surface, to 10–15 GPa at 600 m depth. A best‐fit model that is consistent with observational constraints relating to the present size of the structure, the location of the downfaulted sediments, and the observed surface and vertical shock barometry profiles is presented. The best‐fit model results in a final crater (rim‐to‐rim) diameter of ~65 km. According to our simulations, the original Siljan impact structure would have been a peak‐ring crater. Siljan was formed in a mixed target of Paleozoic sedimentary rocks overlaying crystalline basement. Our modeling suggests that, at the time of impact, the sedimentary sequence was approximately 3 km thick. Since then, there has been around 4 km of erosion of the structure.     

Shock barometry of the Siljan impact structure,Sweden

Abstract– The Siljan impact structure in Sweden is the largest confirmed impact structure in Western Europe. Despite this, the structure has been poorly studied in the past, and detailed studies of shock metamorphic features in the target lithologies are missing. Here, we present the results of a detailed systematic search for shock metamorphic features in quartz grains from 73 sampled localities at Siljan. At 21 localities from an area approximately 20 km in diameter located centrally in the structure, the orientations of 2851 planar deformation feature sets in 1179 quartz grains were measured. Observations of shatter cones outside of the zone with shocked quartz extend the total shocked area to approximately 30 km in diameter. The most strongly shocked samples, recording pressures of up to 20 GPa, occur at the very central part of the structure, and locally in these samples, higher pressures causing melting conditions in the affected rocks were reached. Pressures recorded in the studied samples decrease outwards from the center of the structure, forming roughly circular envelopes around the proposed shock center. Based on the distribution pattern of shocked quartz at Siljan, the original transient cavity can be estimated at approximately 32–38 km in diameter. After correcting for erosion, we conclude that the original rim to rim diameter of the Siljan crater was somewhere in the size range 50–90 km.     

A 3‐D study of mineral inclusions in chromite from ordinary chondrites using synchrotron radiation X‐ray tomographic microscopy—Method and applications

Abstract– A method is described for imaging in 3‐D the interiors of meteoritic chromite grains and their inclusions using synchrotron radiation X‐ray tomographic microscopy. In ordinary chondrites, chromite is the only common mineral that survives long‐term weathering on Earth. Information about the silicate matrix of the original meteorite, however, can be derived from mineral inclusions preserved in the protecting chromite. The inclusions are crucial in the classification of fossil meteorites as well as sediment‐dispersed chromite grains from decomposed meteorites and larger impacts, as these are used for characterizing the past influx of material to Earth, but have previously been difficult to locate. The method is non‐destructive and time efficient for locating inclusions. The method allowed quantitative and morphological studies of both host chromite grains and inclusions in three dimensions. The study of 385 chromite grains from eight chondrites (H4–6, L4–6, LL4, LL6) reveals that inclusions are abundant and equally common in all samples. Almost two‐thirds of all chromite grains contain inclusions, regardless of group and type. The study also shows that the size of the inclusions and the host chromite grains, as well as the number of inclusions, within the host chromite grains vary with petrographic type. Thus, the petrographic type of the host of a suite of chromite grains can be determined based solely on inclusion content. The study also revealed that the amount of fractures in the host chromite can be correlated to previously assigned shock stages for the various chondrites. The study has thus shown that the features and inclusions of fossil chromite grains can give similar information about a former host meteorite as do studies of an unweathered whole meteorite, meaning that this technique is essential in the studies of ancient meteorite flux to Earth.     

Tumbling asteroids

We present both a review of earlier data and new results on non-principal axis rotators (tumblers) among asteroids. Among new tumblers found, the best data we have are for 2002 TD₆₀, 2000 WL₁₀₇, and (54789) 2001 MZ₇—each of them shows a lightcurve with two frequencies (full terms with linear combinations of the two frequencies are present in the lightcurve). For 2002 TD₆₀, we have constructed a physical model of the NPA rotation. Other recent objects which have been found to be likely tumblers based on their lightcurves that do not fit with a single periodicity are 2002 NY₄₀, (16067) 1999 RH₂₇, and (5645) 1990 SP. We have done a statistical analysis of the present sample of the population of NPA rotators. It appears that most asteroids larger than ∼0.4 km with estimated damping timescales (Harris, 1994, Icarus 107, 209) of 4.5 byr and longer are NPA rotators. The statistic of two short-period tumblers (D=0.04 and 0.4 km) with non-zero tensile strength suggests that for them the quantity μQ/T, where μ is the mechanical rigidity, Q is the elastic dissipation factor, and T is a spin excitation age (i.e., a time elapsed since the last significant spin excitation event), is greater by two to four orders of magnitude than the larger, likely rubble-pile tumblers. Among observational conditions and selection effects affecting detections of NPA rotations, there is a bias against detection of low-amplitude (small elongation) tumblers.     

Identifying recent sources of organic matter enrichment and eutrophication trends at coastal sites using stable nitrogen and carbon isotope ratios in sediment cores

We studied the potential for using stable carbon and nitrogen isotope ratios in sediment profiles to trace external nutrient sources and eutrophication at four coastal sites in the Baltic Sea. The sites are characterized by various present and past activities in their catchments, including residential development, sugar processing, agriculture and fish farming. Radiometrically dated sediment cores were analysed for nutrient isotope ratios, organic carbon and total nitrogen. Background information was collected from historical sources, literature and water monitoring data. Despite the multiple organic enrichment sources, it was possible to identify individual sources and processes in the sediment profiles using stable isotope analysis of bulk sediment. The largest changes in δ¹⁵N values were seen at sites receiving urban wastewaters. The site that received effluents from a sugar cane (C₄-plant) refinery in the past showed a clear effect on δ¹³C values compared to the site that received wastewater from a sugar beet (C₃-plant) factory. Fish farming produced detectable, albeit minor changes in the sediment profile. Slightly lower δ¹³C values reflected the influence of fish feed and fish metabolism, and higher δ¹⁵N values likely indicated the influence of increased sediment denitrification. The land-sea connection via river discharge was observable in the overall δ¹³C levels of the sediment cores. Our results suggest that temporal changes in sources of organic matter enrichment can be detected in well-dated coastal sediment cores using nutrient stable isotope analyses, even at sites subjected to multiple impacts. There is not, however, a simple relationship between sediment stable isotope profiles and the eutrophication history of our study sites.     

Sulfur speciation in natural hydrothermal waters, Iceland

The speciation of aqueous dissolved sulfur was determined in hydrothermal waters in Iceland. The waters sampled included hot springs, acid-sulfate pools and mud pots, sub-boiling well discharges and two-phase wells. The water temperatures ranged from 4 to 210 °C, the pH_T was between 2.20 and 9.30 at the discharge temperature and the SO₄ and Cl concentrations were 0.020-52.7 and <0.01-10.0 mmol kg⁻¹, respectively. The analyses were carried out on-site within ∼10 min of sampling using ion chromatography (IC) for sulfate (SO₄²⁻), thiosulfate (S₂O₃²⁻) and polythionates (S_xO₆²⁻) and titration and/or colorimetry for total dissolved sulfide (S²⁻). Sulfite (SO₃²⁻) could also be determined in a few cases using IC. Alternatively, for few samples in remote locations the sulfur oxyanions were stabilized on a resin on site following elution and analysis by IC in the laboratory. Dissolved sulfate and with few exceptions also S²⁻ were detected in all samples with concentrations of 0.02-52.7 mmol kg⁻¹ and <1-4100 μmol kg⁻¹, respectively. Thiosulfate was detected in 49 samples of the 73 analyzed with concentrations in the range of <1-394 μmol kg⁻¹ (S-equivalents). Sulfite was detected in few samples with concentrations in the range of <1-3 μmol kg⁻¹. Thiosulfate and SO₃²⁻ were not detected in <100 °C well waters and S₂O₃²⁻ was observed only at low concentrations (<1-8 μmol kg⁻¹) in ∼200 °C well waters. In alkaline and neutral pH hot springs, S₂O₃²⁻ was present in significant concentrations sometimes corresponding to up to 23% of total dissolved sulfur (S_TOT). In steam-heated acid-sulfate waters, S₂O₃²⁻ was not a significant sulfur species. The results demonstrate that S₂O₃²⁻ and SO₃²⁻ do not occur in the deeper parts of <150 °C hydrothermal systems and only in trace concentrations in ∼200-300 °C systems. Upon ascent to the surface and mixing with oxygenated ground and surface waters and/or dissolution of atmospheric O₂, S²⁻ is degassed and oxidized to SO₃²⁻ and S₂O₃²⁻ and eventually to SO₄²⁻ at pH >8. In near-neutral hydrothermal waters the oxidation of S²⁻ and the interaction of S²⁻ and S⁰ resulting in the formation of S_x²⁻ are considered important. At lower pH values the reactions seemed to proceed relatively rapidly to SO₄²⁻ and the sulfur chemistry of acid-sulfate pools was dominated by SO₄²⁻, which corresponded to >99% of S_TOT. The results suggest that the aqueous speciation of sulfur in natural hydrothermal waters is dynamic and both kinetically and source-controlled and cannot be estimated from thermodynamic speciation calculations.