Kinetics of peptide hydrolysis and amino acid decomposition at high temperature

Dipeptide hydrolysis and amino acid decomposition appear to follow a first-order rate law. The hydrolysis rate increases exponentially with increasing temperature in aqueous solution at both 265 atm and water steam pressures over the temperature range of 100 to 220 degrees C. Dipeptide hydrolysis has a lower apparent activation energy at 265 atm (44.1 KJ/mol) than at water steam pressure (98.9 KJ/mol). At lower temperatures (<200-220 degrees C), the rate of peptide bond hydrolysis is faster at 265 atm than at water steam pressure. At higher temperatures (>200-220 degrees C), however, peptide bond hydrolysis is slower at 265 atm than at water steam pressure. In aqueous solution, amino acid decomposition rates also increase exponentially with increasing temperature. Amino acid decomposition rates are much higher at 265 atm than at water steam pressure over the entire temperature range investigated.     

H2 in interstellar and extragalactic ices: infrared characteristics, ultraviolet production, and implications

H2 is the most abundant molecule in the universe. We demonstrate that this molecule may be an important component of interstellar and possibly intergalactic ices, both because it can be formed in situ, within the ices, and because gas phase H2 can freeze out onto dust grains in some astrophysical environments. The condensation-sublimation and infrared spectral properties of ices containing H2 are presented. We show that solid H2 in H20-rich ices can be detected by an infrared absorption band at 4137 cm-1 (2.417 micrometers). The surface binding energy of H2 to H2O ice was measured to the delta Hs/k = 555 +/- 35 K. Surface binding energies can be used to calculate the residence times of H2 on grain surfaces as a function of temperature. Some of the implications of these results are considered.     

The condensation and vaporization behavior of ices containing SO2, H2S, and CO2: implications for Io

In an extension of previously reported work on ices containing CO, CO2, H2O, CH3OH, NH3, and H2, measurements of the physical and infrared spectral properties of ices containing molecules relevant to Jupiter's moon Io are presented. These include studies on ice systems containing SO2, H2S, and CO2. The condensation and sublimation behaviors of each ice system and surface binding energies of their components are discussed. The surface binding energies can be used to calculate the residence times of the molecules on a surface as a function of temperature and thus represent important parameters for any calculation that attempts to model the transport of these molecules on Io's surface. The derived values indicate that SO2 frosts on Io are likely to anneal rapidly, resulting in less fluffy, "glassy" ices and that H2S can be trapped in the SO2 ices of Io during night-time hours provided that SO2 deposition rates are on the order of 5 micrometers/hr or larger.     

激光照排机输出控制系统设计

简析了激光照排机工作原理，提出了激光照排机输出控制接口的设计方法，重点论述了计算机与激光照排机之间数据缓冲、数据传送、数据分离、信号转换的基本设计思想和实现方法     

地理信息系统基础软件吉奥之星NT版的总体设计思想与关键技术

介绍了新一代面向对象的ＧＩＳ基础软件系统吉奥之星ＮＴ版的总体设计思想、系统结构、功能特点和有关关键技术。     

激光照排机输出控制系统设计

简析了激光照排机工作原理，提出了激光照排机输出控制接口的设计方法，重点论述了计算机与激光照排机之间数据缓冲、数据传送、数据分离、信号转换的基本设计思想和实现方法。     

基于J2EE的移动定位服务研究

阐述了基于J2EE的移动定位服务 (MLS)的体系结构 ,介绍了适于MLS的GIS应用服务器和信息设备地图可视化表达的关键技术 ,给出了GeoSurf的WAP和J2ME的两种解决方案 ,并阐述了其应用前景     

海量地形数据的Web发布与交互浏览

阐述了基于CORBA的分布式平台实现异构网络环境下海量地形数据的Web发布与服务的关键技术 ,通过一个实验系统对上述方法进行了测试