Revisiting the existence of an effective stress for wet granular soils with micromechanics

A possible effective stress variable for wet granular materials is numerically investigated based on an adapted discrete element method (DEM) model for an ideal three‐phase system. The DEM simulations consider granular materials made of nearly monodisperse spherical particles, in the pendular regime with the pore fluid mixture consisting of distinct water menisci bridging particle pairs. The contact force‐related stress contribution to the total stresses is isolated and tested as the effective stress candidate for dense or loose systems. It is first recalled that this contact stress tensor is indeed an adequate effective stress that describes stress limit states of wet samples with the same Mohr‐Coulomb criterion associated with their dry counterparts. As for constitutive relationships, it is demonstrated that the contact stress tensor used in conjunction with dry constitutive relations does describe the strains of wet samples during an initial strain regime but not beyond. Outside this so‐called quasi‐static strain regime, whose extent is much greater for dense than loose materials, dramatic changes in the contact network prevent macroscale contact stress‐strain relationships to apply in the same manner to dry and unsaturated conditions. The presented numerical results also reveal unexpected constitutive bifurcations for the loose material, related to stick‐slip macrobehavior.     

Non‐equilibrium concepts lead to a unified explanation of the formation of chondrules and chondrites

Abstract— Calculations of the formation of seven types of chondrules in Semarkona from a gas of solar composition were performed with the FACT computer program to predict the chemistries of oxides (including silicates), developed by the authors and their colleagues. The constrained equilibrium theory was used in the calculations with two nucleation constraints suggested by nucleation theory. The first constraint was the blocking of Fe and other metal gaseous atoms from condensing to form solids or liquids because of very high surface free energies and high surface tensions of the solid and liquid metals, respectively. The second constraint was the blocking of the condensation of solids and the formation of metastable liquid oxides (including silicates) well below their liquidus temperatures. Our laboratory experiments suggested subcooling of type IIA chondrule compositions of 400 degrees or more below the liquidus temperature. The blocking of iron leads to a supersaturation of Fe atoms, so that the partial pressure of Fe (p_Fe) is larger than the partial pressure at equilibrium (p_Fe(eq)). The supersaturation ratio S = p_Fe/p_Fe(eq) becomes larger than 1 and increases rapidly with a decrease in temperature. This drives the reaction Fe + H₂O ? H₂ + FeO to the right. With S = 100, the activity of FeO in the liquid droplet is 100 times as large as the value at equilibrium. The FeO activities are a function of temperature and provide relative average temperatures of the crystallization of chondrules. Our calculations for the LL3.0 chondrite Semarkona and our study of some non‐equilibrium effects lead to accurate representations of the compositions of chondrules of types IA, IAB, IB, IIA, IIAB, IIB, and CC. Our concepts readily explain both the variety of FeO concentrations in the different chondrule types and the entire process of chondrule formation. Our theory is unified and could possibly explain the formation of chondrules in all chondritic meteorites as well as provide a simple explanation for the complex chemistries of chondrites, and especially for type 3 chondrites.     

Amino acid analyses of Antarctic CM2 meteorites using liquid chromatography‐time of flight‐mass spectrometry

Abstract— Amino acid analyses of the Antarctic CM2 chondrites Allan Hills (ALH) 83100 and Lewis Cliff (LEW) 90500 using liquid chromatography‐time of flight‐mass spectrometry (LC‐ToF‐MS) coupled with UV fluorescence detection revealed that these carbonaceous meteorites contain a suite of indigenous amino acids not present in Antarctic ice. Several amino acids were detected in ALH 83100, including glycine, alanine, β‐alanine, γ‐amino‐n‐butyric acid (γ‐ABA), and α‐aminoisobutyric acid (AIB) with concentrations ranging from 250 to 340 parts per billion (ppb). In contrast to ALH 83100, the CM2 meteorites LEW 90500 and Murchison had a much higher total abundance of these amino acids (440–3200 ppb). In addition, ALH 83100 was found to have lower abundances of the α‐dialkyl amino acids AIB and isovaline than LEW 90500 and Murchison. There are three possible explanations for the depleted amino acid content in ALH 83100: 1) amino acid leaching from ALH 83100 during exposure to Antarctic ice meltwater, 2) a higher degree of aqueous alteration on the ALH 83100 parent body, or 3) ALH 83100 originated on a chemically distinct parent body from the other two CM2 meteorites. The high relative abundance of ?‐amino‐n‐caproic acid (EACA) in the ALH 83100 meteorite as well as the Antarctic ice indicates that Nylon‐6 contamination from the Antarctic sample storage bags may have occurred during collection.     

Steady-state size distributions for collisional populations:: analytical solution with size-dependent strength

The steady-state population of bodies resulting from a collisional cascade depends on how material strength varies with size. We find a simple expression for the power-law index of the population, given a power law that describes how material strength varies with size. This result is extended to the case relevant for the asteroid belt and Kuiper belt, in which the material strength is described by 2 separate power laws—one for small bodies and one for larger bodies. We find that the power-law index of the small body population is unaffected by the strength law for the large bodies, and vice versa. Simple analytical expressions describe a wave that is superimposed on the large body population because of the transition between the two power laws describing the strength. These analytical results yield excellent agreement with a numerical simulation of collisional evolution. These results will help to interpret observations of the asteroids and KBOs, and constrain the strength properties of those objects.     

REGIONAL DEMOGRAPHIC STRUCTURE OF THE UNITED STATES

This paper analyzes the surprisingly great variation in demographic character across the states, utilizing data on fertility, mortality, age, sex, mobility, household character, abortion, race and ethnicity. A fairly simple regional pattern is revealed that is less related to levels of economic development than to long-standing historical cultural differences.     

Structure in the solar corona from radio scintillation measurements

Since the 1950s, a wide variety of radio observations based on scattering by electron density fluctuations in the solar wind has provided much of our information on density fluctuations and solar wind speed near the source region of the solar wind. This paper reviews recent progress in the understanding of the nature of these density fluctuations and their relationship to features on the Sun. The results include the first measurements of fine-scale structure within coronal streamers and evidence for structure in solar wind speed in the inner corona.     

What Drives Star Formation?

Current theoretical models for what drives star formation (especially low-mass star formation) are: (1) magnetic support of self-gravitating clouds with ambipolar diffusion removing support in cores and triggering collapse and (2) compressible turbulence forming self-gravitating clumps that collapse as soon as the turbulent cascade produces insufficient turbulent support. Observations of magnetic fields can distinguish between these two models because of different predictions in three areas: (1) magnetic field morphology, (2) the scaling of field strength with density and non-thermal velocities, and (3) the mass to magnetic flux ratio, M/Φ. We first discuss the techniques and limitations of methods for observing magnetic fields in star formation regions, then describe results for the L1544 prestellar core as an exemplar of the observational results. Application of the three tests leads to the following conclusions. The observational data show that both magnetic fields and turbulence are important in molecular cloud physics. Field lines are generally regular rather than chaotic, implying strong field strengths. But fields are not aligned with the minor axes of oblate spheroidal clouds, suggesting that turbulence is important. Field strengths appear to scale with non-thermal velocity widths, suggesting a significant turbulent support of clouds. Giant Molecular Clouds (GMCs) require mass accumulation over sufficiently large volumes that they would likely have an approximately critical M/Φ. Yet H I clouds are observed to be highly subcritical. If self-gravitating (molecular) clouds form with the subcritical M/Φ of H I clouds, the molecular clouds will be subcritical. However, the observations of molecular cloud cores suggest that they are approximately critical, with no direct evidence for subcritical molecular clouds or cloud envelopes. Hence, the observations remain inconclusive in deciding between the two extreme-case models of what drives star formation. What is needed to further advance our understanding of the role of magnetic fields in the star formation process are additional high sensitivity surveys of magnetic field strengths and other cloud properties in order to further refine the assessment of the importance of magnetic fields in molecular cores and envelopes.     

A high resolution,multiproxy Late‐glacial record of climate change and intrasystem responses in northwest England

A lacustrine carbonate sequence from Hawes Water, Lancashire, UK, has been studied using stable isotopic, lithological, pollen and mineral magnetic analysis. The data reveal four abrupt climatic oscillations in the Late‐glacial Interstadial leading up to the onset of the Loch Lomond Stadial. The data also point to climatic warming relatively early within the stadial, ca. 12 500 GRIP yr, prior to the onset of the Holocene. The oxygen isotope record is taken as a signature of climate forcing against which the response of the lake‐system can be monitored. By adopting this approach it is revealed that the response of the biological system to the rapid climatic oscillations is non‐linear and primarily a function of the antecedent conditions. A significant end‐Devensian isotopic excursion (A) is matched by only minor changes in the cold‐adapted floras and faunas. During the warmer interstadial, the response of the biological ecosystem (events B–D) is clearly influenced by thresholds: major changes in the catchment vegetation associated with relatively minor oscillations in the isotopic signature. The stratigraphical patterns reveal significant lag effects between the onset of climate deterioration and resulting changes in vegetation. Copyright © 2002 John Wiley & Sons, Ltd.