Phosphine absorption in the 5-μm window of Jupiter

Since the original suggestion by Gillett et al. (1969) it has generally been assumed that the region of partial transparency near 5 μm in Jupiter's atmosphere (the 5-μm window) is bounded by the v₄ NH₃ at 6.1 μm and the v₃ CH₄ band at 3.3 μm. New measurements of Jupiter and of laboratory phosphine (PH₃) samples show that PH₃ is a significant contributor to the continuum opacity in the window and in fact defines its short-wavelength limit. This has important implications for the use of 5-mu;m observations as a means to probe the deep atmospheric structure of Jupiter. The abundance of PH₃ which results from a comparison of Jovian and laboratory spectra is about 3 to 5 cm-am. This is five to eight times less than that found by Larson et al. [Astrophys. J. (1977) 211, 972–979] in the same spectral region, but is in good agreement with the result of Tokunaga et al. [Astrophys. J. (1979) 232, 603–615] from 10-μm observations.     

Ground deformation of Nisyros Volcano (Greece) for the period 1995–2002: Results from DInSAR and DGPS observations

Differential GPS (DGPS) and Differential Interferometric Synthetic Aperture Radar (DInSAR) analyses were applied to the Kos-Yali-Nisyros Volcanic Field (SE Hellenic Volcanic Arc) to quantify the ground deformation of Nisyros Volcano. After intense seismic activity in 1996, a GPS network was installed in June 1997 and re-occupied annually up to 2002. A general uplift ranging from 14 to 140 mm was determined at all stations of the network. The corresponding horizontal displacements ranged from 13 to 53 mm. The displacement vectors indicate that the island is undergoing extension towards the East, West and South. A two-source “Mogi” model combined with assumed motion along the Mandraki Fault was constructed to fit the observed deformation. The best-fit model assumes sources at a depth of 5500 m NW of the centre of the island and at 6500 m offshore ESE of Yali Island. DInSAR analysis using four pairs of images taken between May 1995 and September 2000 suggests that deformation was occurring during 1995 before the start of the seismic crisis. An amplitude of at least 56 mm along the slant range appeared for the period 1996 through 1999. This deformation is consistent with the two-source model invoked in DGPS modelling. Surface evidence of ground deformation is expressed in the contemporaneous reactivation of the Mandraki Fault. In addition, a 600 m long N-S trending irregular rupture in the caldera floor was formed between 2001 and 2002. This rupture is interpreted as the release of surface stress in the consolidated epiclastic and hydrothermal sediments of the caldera floor.     

Assessment of small-diameter shallow wells for managed aquifer recharge at a site in southern Styria,Austria

An approach to establish the recharge component of managed aquifer recharge (MAR) has recently been proposed that uses small-diameter shallow wells installed using relatively inexpensive drilling methods such as direct push. As part of further development of that approach, a generalized procedure is presented for a technical and economic assessment of the approach’s potential in comparison to other systems. Following this procedure, the use of small-diameter wells was evaluated both experimentally and numerically for a site located in southern Styria, Austria. MAR is currently done at the site using a horizontal pipe infiltration system, and system expansion has been proposed with a target rate of 12 l/s using small-diameter wells as one possible option. A short-duration single-well field recharge experiment (recharge rate 1.3–3.5 l/s) was performed (recharge by gravity only). Numerical modeling of the injection test was used to estimate hydraulic conductivity (K). Quasi-steady-state, single-well recharge simulations for different locations, as well as a long-term transient simulation, were performed using the K value calibrated from the field injection test. Results indicate that a recharge capacity of 4.1 l/s was achievable with a maximum head rise of 0.2 m at the injection well. Finally, simulations were performed for three different well fields (4, 6 and 8 wells, respectively) designed to infiltrate a target rate of 12 l/s. The experimental and numerical assessments, supported by a cost analysis of the small-diameter wells, indicate that the small-diameter wells are a viable, cost-effective recharge approach at this and other similar sites.     

Die Porositäten toniger Keuper- und Jura-Sedimente Südwestdeutschlands

After a short review of the basic principles governing compaction of clayey sediments, investigations of the porosities of Mesozoic shales from southwestern Germany are reported. The results reveal the influence of grain size, mineral content, temperature, and organic matter on the porosity of shales. All these and other factors have to be considered when evaluating primary porosities of shales at the time of deposition.     

Efficient generation of conditional simulations by chebyshev matrix polynomial approximations to the symmetric square root of the covariance matrix

Consider the problem of generating a realization y₁ of a Gaussian random field on a dense grid of points ₁ conditioned on field observations y₂ collected on a sparse grid of points ₂. An approach to this is to generate first an unconditional realization y over the grid =_{1 2}, and then to produce y₁ by conditioning y on the data y₂. As standard methods for generating y, such as the turning bands, spectral or Cholesky approaches can have various limitations, it has been proposed by M. W. Davis to generate realizations from a matrix polynomial approximations to the square root of the covariance matrix. In this paper we describe how to generate a direct approximation to the conditional realization y₁, on ₁ using a variant of Davis' approach based on approximation by Chebyshev polynomials. The resulting algorithm is simple to implement, numerically stable, and bounds on the approximation error are readily available. Furthermore we show that the conditional realization y₁ can be generated directly with a lower order polynomial than the unconditional realization y, and that further reductions can be achieved by exploiting a nugget effect if one is present. A pseudocode version of the algorithm is provided that can be implemented using the fast Fourier transform if the field is stationary and the grid ₁ is rectangular. Finally, numerical illustrations are given of the algorithm's performance in generating various 2-D realizations of conditional processes on large sampling grids.     

Composition and origin of organic matter in surface sediments of Lake Sarbsko: A highly eutrophic and shallow coastal lake (northern Poland)

We present an organic geochemical study of surface sediments of Lake Sarbsko, a shallow coastal lake on the middle Polish Baltic coast. The aim was to provide evidence concerning the origin of the organic matter (OM) and its compositional diversity in surface deposits of this very productive, highly dynamic water body. The content and composition of the OM in the bottom sediments were investigated at 11 sampling stations throughout the lake basin. OM sources were assigned on the basis of bulk indicators [total organic carbon (TOC), total nitrogen (TN), δ¹³C_TOC and δ¹⁵N and extractable OM yield], biomarker composition of extractable OM and compound-specific C isotope signatures. The source characterization of autochthonous compounds was verified via phytoplankton analysis. The distribution of gaseous hydrocarbons in the sediments, as well as temporal changes in lake water pH, the concentration of DIC (dissolved inorganic carbon) and δ¹³C_DIC were used to trace OM decomposition.The sedimentary OM is composed mainly of well preserved phytoplankton compounds and shows minor spatial variability in composition. However, the presence of CH₄ and CO₂ in the bottom deposits provides evidence for microbial degradation of sedimentary OM. The transformation of organic compounds in surface, bottom and pore waters via oxidative processes influences carbonate equilibrium in the lake and seasonally favours precipitation or dissolution of CaCO₃.The data enhance our understanding of the relationships between the composition of sedimentary OM and environmental conditions within coastal ecosystems and shed light on the reliability of OM proxies for environmental reconstruction of coastal lakes.