Some breakage characteristics of ultra-fine wet grinding with a centrifugal mill

A centrifugal mill is a high-power intensity media mill that can be used for ultra-fine grinding, employing centrifugal forces generated by gyration of the axis of the mill tube in a circle. The mill charge motion is quite different depending on the ratio of the gyration diameter to the mill diameter (G / D ratio), varying from a motion similar to that of a conventional tumbling media mill to that of a vibration mill. In this study, a centrifugal mill was constructed with an arrangement where the gyration diameter could be readily adjusted. The batch grinding characteristics of three different minerals (limestone, talc and illite) in water with dispersing agent were investigated at various G / D ratios. It was found that the optimum G / D ratio in terms of the specific energy consumption to give a desired fineness of product was different for the three minerals. This was due to their different reactions to the breakage mechanisms provided by the mill charge motion at varying G / D ratios. The size distributions became progressively narrower at increased grinding times, and particles finer than about 0.1 μm were not detected even for prolonged grinding times. Measurement of specific surface areas indicated that this was not due to an artifact of the size measurements by laser diffractometry. This implies that there is a limitation in which particles finer than 0.1 μm are not produced under the conditions tested in this type of mill, but further investigation is needed for experimental verification of this limit of comminution.     

Aerobic oxidation of mackinawite (FeS) and its environmental implication for arsenic mobilization

Oxidation of mackinawite (FeS) and concurrent mobilization of arsenic were investigated as a function of pH under oxidizing conditions. At acidic pH, FeS oxidation is mainly initiated by the proton-promoted dissolution, which results in the release of Fe(II) and sulfide in the solution. While most of dissolved sulfide is volatilized before being oxidized, dissolved Fe(II) is oxidized into green rust-like precipitates and goethite (α-FeOOH). At basic pH, the development of Fe(III) (oxyhydr)oxide coating on the FeS surface inhibits the solution-phase oxidation following FeS dissolution. Instead, FeS is mostly oxidized into lepidocrocite (γ-FeOOH) via the surface-mediated oxidation without dissolution. At neutral pH, FeS is oxidized via both the solution-phase oxidation following FeS dissolution and the surface-mediated oxidation mechanisms. The mobilization of arsenic during FeS oxidation is strongly affected by FeS oxidation mechanisms. At acidic pH (and to some extent at neutral pH), the rapid FeS dissolution and the slow precipitation of Fe (oxyhydr)oxides results in arsenic accumulation in water. In contrast, the surface-mediated oxidation of FeS at basic pH leads to the direct formation of Fe (oxyhydr)oxides, which provides effective adsorbents for As under oxic conditions. At acidic and neutral pH, the solution-phase oxidation of dissolved Fe(II) accelerates the oxidation of the less adsorbing As(III) to the more adsorbing As(V). This study reveals that the oxidative mobilization of As may be a significant pathway for arsenic enrichment of porewaters in sulfidic sediments.     

Characterization of spatial and temporal variation of suspended sediments in the Yellow and East China Seas using satellite ocean color data

Total suspended sediment (TSS) data concentrations are retrieved from two sets of satellite ocean color data (the Moderate Resolution Imaging Spectroradiometer (MODIS) onboard Aqua and the Korean Geostationary Ocean Color Imager (GOCI)) using an existing regional model to characterize spatial and temporal variation of TSS in the Yellow and East China Seas. MODIS-derived TSS maps show that TSS concentrations are, in general, high along the Korean and Chinese coasts including the Bohai Sea and the Yangtz River estuary, and lower in the middle of the Yellow Sea and the southeastern area of the East China Sea. The monthly average of 10-year MODIS data reveals that TSS values are highest during winter (January to February) and lowest in summer (July to August). Short-term TSS concentrations retrieved from GOCI data showed the dominant influence of semi-diurnal tidal changes on sediment dynamics through temporal (hourly) and spatial distribution in coastal zones of the Yellow sea. The results presented here demonstrate that the satellite-derived TSS products can be utilized as an application tool for future studies on long- and short-term sediment dynamics of turbid coastal waters. In particular, GOCI observations provide unique important capabilities to characterize and quantify the water properties at high temporal (hourly) and spatial (0.5 km) resolutions in the turbid coastal waters of the Yellow Sea and its vicinities.     

Statistical approach to determine the salinized ground water flow path and hydrogeochemical features around the underground LPG cavern,Korea

The ground water flow path of the coastal area in the Yellow Sea, Korea, was interpreted using both the cross‐correlation analysis of hydraulic properties and the principal component analysis (PCA) of ground water chemistry. Data was obtained from observation wells in the underground liquefied petroleum gas (LPG) cavern constructed in the coastal area of Pyeongtaek. Cross‐correlation results showed that the operating pressure became more influenced on artificial factors for the variation of the groundwater level of the study area (45–66% of correlation coefficient) even though its affecting area was limited to the region with fractures or faults, and also showed that the delay time from the variation of operating pressure to the fluctuation of ground water level were relatively long periods (28–31 days). Three hydrogeochemical events (encrusted cement dissolution, host rock dissolution, and seawater intrusion), which were dominantly influenced on ground water quality, could be induced from the result of PCA. Quantitative evaluation for these events using the mixed equation with principal component scores suggest that the dissolution of encrusted cement materials was the predominant factor (39·0% of the total mixed proportion) to change the chemical composition of the seepage water during the ground water flow from the observation wells to the cavern. Integration of the statistical results also imply that ground water flow and hydrogeochemistry were predominantly affected by artificial factors such as cavern operation pressure and dissolution of encrusted cement materials, which were interdependent factors on the observation wells with high cross‐correlation coefficients and pH. Copyright © 2007 John Wiley & Sons, Ltd.     

Bayesian probabilistic damage detection of a reinforced‐concrete bridge column

A Bayesian probabilistic approach for damage detection has been proposed for the continuous monitoring of civil structures (Sohn H, Law KH. Bayesian probabilistic approach for structure damage detection. Earthquake Engineering and Structural Dynamics 1997; 26 :1259–1281). This paper describes the application of the Bayesian approach to predict the location of plastic hinge deformation using the experimental data obtained from the vibration tests of a reinforced‐concrete bridge column. The column was statically pushed incrementally with lateral displacements until a plastic hinge is fully formed at the bottom portion of the column. Vibration tests were performed at different damage stages. The proposed damage detection method was able to locate the damaged region using a simplified analytical model and the modal parameters estimated from the vibration tests, although (1) only the first bending and first torsional modes were estimated from the experimental test data, (2) the locations where the accelerations were measured did not coincide with the degrees of freedom of the analytical model, and (3) there existed discrepancies between the undamaged test structure and the analytical model. The Bayesian framework was able to systematically update the damage probabilities when new test data became available. Better diagnosis was obtained by employing multiple data sets than just by using each test data set separately. Copyright © 2000 John Wiley & Sons, Ltd.     

Derivative‐Assisted Classification of Fractured Zones Crossing a Deep Borehole

In this study, the derivative analysis using the derivative of drawdown with respect to log‐time was utilized to determine candidates for hydraulic conductor domains (HCDs). At a 500‐m deep borehole in the study site, the fractured rocks crossing the borehole were first classified in fractured and nonfractured zones by core logging and geophysical loggings, such as acoustic televiewing, density, and flow loggings. After conducting the hydraulic tests such as constant head withdrawal and recovery tests at the fractured zones and the nonfractured zones, the derivative analyses were carried out, of which the results were evaluated to determine the candidates for HCDs. For the nonfractured zones, the diagnostic plot has only a big hump indicating poor connection of the background fractures to the permeable geologic media, while those of the candidates for HCDs show various flow regimes. On the basis of these results, the candidates for HCDs among the fractured zones were determined. From discussion on the results, the combination of the spacing analysis and derivative analysis following a hydraulic test is recommended for determining the candidates for HCDs rather than other geophysical loggings.     

Distribution and bioaccumulation of polychlorinated biphenyls and organochlorine pesticides residues in sediments and Manila clams (Ruditapes philippinarum) from along the Mid-Western coast of Korea

The distribution and bioaccumulation features of PCBs, DDTs, and HCHs were investigated in the sediments and Manila clams collected from along the Mid-Western coast of Korea. The measured concentrations of ΣPCBs, ΣDDTs and ΣHCHs were 1.08–3.5, 0.12–0.35 and 0.090–0.30 ng g⁻¹ dw in sediment, and 33–390, 7.4–46 and 6.3–27 ng g⁻¹ lipid in Manila clam, respectively. Their levels were found to be relatively lower than those of other contaminated areas and the consumption of Manila clam from these areas seems to be safe for human health according to calculated lifetime cancer risk and hazard indices. The ΣPCBs and ΣDDTs concentrations in sediments showed a significant relationship to those in clams. The significant correlation was observed between BSAF in clams and K_ow for each PCB congeners and DDT metabolites. These findings support that the PCBs and DDTs levels, which are highly hydrophobic chemicals, in clam reflect the sediment pollution through bioaccumulation.     

Modeling and control of a 75 kW class variable liquid-column oscillator for highly efficient wave energy converter

The modeling and control of a variable liquid-column oscillator having a liquid filled U-tube with air chambers at its vertical columns are presented. As an ocean wave energy extracting device, the structure of the variable liquid-column oscillator (VLCO) is analogous to that of the tuned liquid-column damper used to suppress oscillatory motion in large structures like tall buildings and cargo ships. However, owing to an air spring effect caused by the dynamic pressure of air chambers, the amplitude of response of the VLCO becomes significantly amplified for a desired wave period. The governing equations for the motion of VLCO structure under wave excitation and the motion of liquid with an air spring effect caused by an air–liquid interaction are described by a series of nonlinear differential equations. A set of control parameters for extracting maximum power from various wave conditions is determined for the efficient operation of the VLCO. It is found that the effect of the air spring has an important role to play in making the oscillation of the VLCO match with the ocean wave. In this way, the VLCO provides the most effective mode for extracting energy from the ocean wave.