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1.
Davide Lenaz Henrik Skogby Francesco Princivalle 《Geochimica et cosmochimica acta》2008,72(2):475-479
Four nearly pure MgAl2O4 spinels, of both natural and synthetic occurrence, have been studied by means of X-ray single crystal diffraction and FTIR spectroscopy in order to detect their potential OH content. Absorption bands that can be assigned to OH incorporated in the spinel structure were only observed in spectra of a non-stoichiometric synthetic sample. The absorption intensity of two bands occurring at 3350 and 3548 cm−1 indicate an OH content of 90 ppm H2O. Based on correlations of OH vibrational frequencies and O-H?O distances, the observed absorption bands correspond to O-H?O distances of 2.77 and 2.99 Å, respectively, which is close to the values obtained by the structure refinements for VIO-Ounsh (2.825 Å) and IVO-O (3.001 Å). This indicates that one probable local position for hydrogen incorporation is the oxygens coordinating a vacant tetrahedral site. The present spectra demonstrate that the detection limit for OH in Fe-free spinels is in the range 10-20 ppm H2O. However, at appreciable Fe2+ levels, the detection of OH bands becomes hampered due to overlap with strong absorption bands caused by electronic d-d transitions in Fe2+ in the tetrahedral position. 相似文献
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Regional variation in maturation of sandeels in the North Sea 总被引:1,自引:0,他引:1
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The petroleum generation potential and effective oil window of humic coals related to coal composition and age 总被引:1,自引:0,他引:1
A worldwide data set of more than 500 humic coals from the major coal-forming geological periods has been used to analyse the evolution in the remaining (Hydrogen Index, HI) and total (Quality Index, QI) generation potentials with increasing thermal maturity and the ‘effective oil window’ (‘oil expulsion window’). All samples describe HI and QI bands that are broad at low maturities and that gradually narrow with increasing maturity. The oil generation potential is completely exhausted at a vitrinite reflectance of 2.0–2.2%Ro or Tmax of 500–510 °C. The initial large variation in the generation potential is related to the original depositional conditions, particularly the degree of marine influence and the formation of hydrogen-enriched vitrinite, as suggested by increased sulphur and hydrogen contents. During initial thermal maturation the HI increases to a maximum value, HImax. Similarly, QI increases to a maximum value, QImax. This increase in HI and QI is related to the formation of an additional generation potential in the coal structure. The decline in QI with further maturation is indicating onset of initial oil expulsion, which precedes efficient expulsion. Liquid petroleum generation from humic coals is thus a complex, three-phase process: (i) onset of petroleum generation, (ii) petroleum build-up in the coal, and (iii) initial oil expulsion followed by efficient oil expulsion (corresponding to the effective oil window). Efficient oil expulsion is indicated by a decline in the Bitumen Index (BI) when plotted against vitrinite reflectance or Tmax. This means that in humic coals the vitrinite reflectance or Tmax values at which onset of petroleum generation occurs cannot be used to establish the start of the effective oil window. The start of the effective oil window occurs within the vitrinite reflectance range 0.85–1.05%Ro or Tmax range 440–455 °C and the oil window extends to 1.5–2.0%Ro or 470–510 °C. For general use, an effective oil window is proposed to occur from 0.85 to 1.7%Ro or from 440 to 490 °C. Specific ranges for HImax and the effective oil window can be defined for Cenozoic, Jurassic, Permian, and Carboniferous coals. Cenozoic coals reach the highest HImax values (220–370 mg HC/g TOC), and for the most oil-prone Cenozoic coals the effective oil window may possibly range from 0.65 to 2.0%Ro or 430 to 510 °C. In contrast, the most oil-prone Jurassic, Permian and Carboniferous coals reach the expulsion threshold at a vitrinite reflectance of 0.85–0.9%Ro or Tmax of 440–445 °C. 相似文献
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Lisbeth M. Ottosen Anne J. Pedersen Alexandra B. Ribeiro Henrik K. Hansen 《Engineering Geology》2005,77(3-4):317-329
Numerous studies have been conducted with electrochemical removal of heavy metals from spiked kaolinite. Meanwhile, when moving from kaolinite to real soils, new factors must be taken into account—factors influencing, e.g., the buffering capacity of the soil against acidification and the adsorption/desorption processes of the heavy metals. The present study gives some examples where it is necessary to use an enhancement solution to aid desorption of Cu, Zn and Pb during electrodialytic treatment. Dependent on the composition of the pollution, different choices can be made. In the case of a Cu-polluted calcareous soil, ammonia may be used as enhancement solution, due to the formation of charged complexes between ammonia and Cu. Thus, Cu is mobile at high pH when ammonia is added and Cu can be removed without dissolving the calcareous parts. Zn is also mobilized by ammonia, but to a lesser extent than Cu. In the case of Cu, Zn and Pb at the same time, alkaline ammonium citrate may be a solution. It was shown that this enhancement solution could mobilize these three pollutants, but optimization of concentration and pH of the ammonium citrate is still needed. When choosing a remediation scheme for electrochemical treatment of an actual industrially polluted soil, this scheme must be chosen on basis of characterization of soil and pollution combination. 相似文献
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Benthic Carbon Mineralization and Nutrient Turnover in a Scottish Sea Loch: An Integrative In Situ Study 总被引:1,自引:1,他引:0
Ronnie N. Glud Peter Berg Henrik Stahl Andrew Hume Morten Larsen Bradley D. Eyre Perran L. M. Cook 《Aquatic Geochemistry》2016,22(5-6):443-467
Based on in situ microprofiles, chamber incubations and eddy covariance measurements, we investigated the benthic carbon mineralization and nutrient regeneration in a ~65-m-deep sedimentation basin of Loch Etive, UK. The sediment hosted a considerable amount of infauna that was dominated by the brittle star A. filiformis. The numerous burrows were intensively irrigated enhancing the benthic in situ O2 uptake by ~50 %, and inducing highly variable redox conditions and O2 distribution in the surface sediment as also documented by complementary laboratory-based planar optode measurements. The average benthic O2 exchange as derived by chamber incubations and the eddy covariance approach were similar (14.9 ± 2.5 and 13.1 ± 9.0 mmol m?2 day?1) providing confidence in the two measuring approaches. Moreover, the non-invasive eddy approach revealed a flow-dependent benthic O2 flux that was partly ascribed to enhanced ventilation of infauna burrows during periods of elevated flow rates. The ratio in exchange rates of ΣCO2 and O2 was close to unity, confirming that the O2 uptake was a good proxy for the benthic carbon mineralization in this setting. The infauna activity resulted in highly dynamic redox conditions that presumably facilitated an efficient degradation of both terrestrial and marine-derived organic material. The complex O2 dynamics of the burrow environment also concurrently stimulated nitrification and coupled denitrification rates making the sediment an efficient sink for bioavailable nitrogen. Furthermore, bioturbation mediated a high efflux of dissolved phosphorus and silicate. The study documents a high spatial and temporal variation in benthic solute exchange with important implications for benthic turnover of organic carbon and nutrients. However, more long-term in situ investigations with like approaches are required to fully understand how environmental events and spatio-temporal variations interrelate to the overall biogeochemical functioning of coastal sediments. 相似文献
10.
John G. Pope Jannike Falk-Pedersen Simon Jennings Jake C. Rice Henrik Gislason Niels Daan 《Deep Sea Research Part II: Topical Studies in Oceanography》2009,56(21-22):2097
Historically colder regions of the North Atlantic had fisheries dominated by only a few fish species; principally cod and capelin. Possible population dynamic mechanisms that lead to such dominance are investigated by considering how a charmingly simple published multispecies model of the North Sea would react if the system operated at a lower temperature. The existing model equations were modified to describe temperature effects on growth, fecundity and recruitment and the model was rerun based on typical temperatures for the North Sea and a colder system. The results suggest that total fish biomass in the colder system increases but the community is more vulnerable to a given rate of fishing mortality. In the colder system, within species density dependence is reduced but relative predation rates are higher. Consequently, intermediate-sized species are vulnerable to relatively high levels of predation throughout their life history and tend to be excluded, leading to a system dominated by small and large species. The model helps to explain how temperature may govern coexistence and competitive exclusion in fish communities and accounts for the observed dominance of small and large species in Boreal/Arctic ecosystems. 相似文献