This paper presents a constitutive model that predicts the water retention behaviour of compacted clays with evolving bimodal pore size distributions. In line with previous research, the model differentiates between the water present inside the saturated pores of the clay aggregates (the microstructure) and the water present inside the pores between clay aggregates (the macrostructure). A new formulation is then introduced to account for the effect of the macrostructural porosity changes on the retention behaviour of the soil, which results in a consistent evolution of the air-entry value of suction with volumetric deformations. Data from wetting tests on three different active clays (i.e. MX-80 bentonite, FEBEX bentonite, and Boom clay), subjected to distinct mechanical restraints, were used to formulate, calibrate, and validate the proposed model. Results from free swelling tests were also modelled by using both the proposed double porosity model and a published single porosity model, which confirmed the improvement in the predictions of degree of saturation by the present approach. The proposed retention model might be applied, for example, to the simulation of the hydromechanical behaviour of engineered bentonite barriers in underground nuclear waste repositories, where compacted active clays are subjected to changes of both suction and porosity structure under restrained volume conditions.
We have monitored the distribution, population status, breeding success, turnover rate and diet of a Peregrine Falcon population in Bizkaia (North of Spain) since 1997. On the 13th November 2002, the tanker Prestige sunk off La Coruña (NW Spain) causing an oil spill that affected the whole of the Cantabrian Coast and the Southwest of France. The total number of birds affected by the Prestige oil spill was expected to be between 115,000 and 230,000, some of them raptors. The loss of clutches during the incubation period increased significantly and was correlated with the loss of females. Moreover, the turnover rate of the population increased from 21% to 30%. The polycyclic aromatic hydrocarbon concentrations in the eggs, collected from five nests after they were deserted, ranged from 21.20 ng/g to 461.08 ng/g, values which are high enough to cause the death of the embryos and poisoning of adult birds. The effects of pollution reached inland since some inland-breeding falcons prey on shorebirds that use rivers during their migratory flights. As the Prestige oil spill has clearly resulted in increased rates of adult mortality and reduced fertility, we suggest that the environmental authorities urgently undertake measures aimed at protecting the Peregrine Falcon in Bizkaia. 相似文献
The Athabasca Basin hosts many world-class unconformity-related uranium deposits. Recently, uranium reserves for the Eagle
Point basement-hosted deposit have increased with the discovery of new mineralized zones within secondary structures. A paragenetic
study of Eagle Point reveals the presence of three temporally distinct alteration stages: a pre-Athabasca alteration, a main
alteration and mineralization comprised of three substages, and a post-main alteration and mineralization stage that culminated
in remobilization of uraninite from primary to secondary structures. The pre-Athabasca alteration stage consists of minor
amounts of clinochlore, followed by dolomite and calcite alteration in the hanging wall of major fault zones and kaolinitization
of plagioclase and K-feldspar caused by surface weathering. The main alteration and uranium mineralization stage is related
to three temporally distinct substages, all of which were produced by isotopically similar fluids. A major early alteration
substage characterized by muscovite alteration and by precipitation Ca–Sr–LREE-rich aluminum phosphate-sulfate minerals, both
from basinal fluids at temperatures around 240°C prior to 1,600 Ma. The mineralization substage involved uraninite and hematite
precipitated in primary structures. The late alteration substage consists of dravite, uranophane-beta veins, calcite veins,
and sudoite alteration from Mg–Ca-rich chemically modified basinal fluids with temperatures around 180°C. The post-main alteration
and mineralization stage is characterized by remobilization of main stage uraninite from primary to secondary structures at
a minimum age of ca. 535 Ma. U–Pb resetting events recorded on primary and remobilized uraninites are coincident with fluid
flow induced by distal orogenies, remobilizing radiogenic Pb to a distance of at least 225 m above the mineralized zones. 相似文献
Apoyeque volcano, located 9 km northwest of Managua city, erupted explosively at 12.4 ka. The Plinian eruption deposited a widespread pumice fall deposit known as the Upper Apoyeque Tephra (UAq). The UAq is massive, reversely graded, and consists of white juvenile pumice (~78 vol.%), a variety of cognate lithics and accidental altered lithics. The whole-rock pumice composition is rhyodacitic (SiO2?=?66.9–68.5 wt.%) with a mineral paragenesis of plagioclase, orthopyroxene, clinopyroxene, amphibole, titanomagnetite, and ilmenite in a rhyolitic glass groundmass (SiO2?=?74.4?±?0.6 wt.%). The deposit’s dispersal axis is to the south, with the deposit covering a minimum area of 877 km2 within the 50 cm isopach and has a total volume of 3 km3 (dense rock equivalent, 1.15 km3). The eruption column reached a maximum height of ca.28 km. The eruption ejected a total mass of 3?×?1012 kg at an average rate of 2?×?108 kg/s, and based on available models, we infer duration of almost 4 h. Petrographic and geochemical characteristics suggest that the eruption was triggered by magma mixing. 相似文献
The structure of the glacial ocean was significantly different to that of the present day with intermediate to mid-depth waters being notably more δ13C enriched than deep waters. This contrast was especially pronounced in the South Atlantic suggesting the development of a sharp chemical divide, or ‘chemocline’, at around 2500 m water depth between upper and lower layers, with implications for deep-ocean carbon storage [Hodell et al., 2003. Pleistocene vertical carbon isotope and carbonate gradients in the South Atlantic sector of the Southern Ocean. Geochemistry, Geophysics, Geosystems, 4(1): doi: 1004 10.1029/2002GC000367.]. We evaluate existing benthic foraminiferal δ13C, Cd/Ca and derived carbon isotope air–sea exchange signature (δ13Cas) data sets for the Atlantic during the Last Glacial Maximum (LGM), and Marine Isotope Stages (MIS) 6 and 8 in order to examine the regional extent of the chemocline in the South Atlantic. Benthic δ13C data north of the approximate latitude of the LGM Subantarctic Front (LGM-SAF, 43°S) linearly decrease with water depth, indicative of mixing between upper ‘well’ and lower ‘poorly’ ventilated water masses, with little evidence of the sharp chemical divide. Conversely, benthic δ13C data south of the LGM-SAF below 2500 m water depth are uniformly around ?0.8‰. The apparent δ13C gradient across the LGM-SAF suggests enhanced mid-depth ventilation north of the SAF and reduced ventilation to the south. From this pattern we conclude that the regional chemocline in the South Atlantic constituted a dominantly meridional, rather than a vertical gradient, and was developed during at least the past three glacial periods. Benthic Cd/Ca data indicate that the gradient was not nutrient related, although further data from the South Atlantic are needed for a better assessment of this suggestion. The combined benthic δ13C and Cd/Ca data indicate the source of well-ventilated upper waters in the South Atlantic changed from Northern Component Water (NCW) during early glacial phases to Upper Southern Component Water (USCW) during mid-to-late glacial phases when the Southern Ocean may have become isolated. USCW maintained a positive δ13C and δ13Cas signature simulating a North Atlantic origin that has been implicated in previous studies. The data demonstrate that secular imprints on δ13C must be taken into consideration when assessing the implications of the vertical δ13C gradient. This data also supports a variable water column architecture and modes of water mass formation as primary means to draw down atmospheric CO2 and storage in the abyssal ocean by involving processes occurring on either side of the SAF in the glacial Southern Ocean. 相似文献
Much work has been done in the context of the hedonic price theory to estimate the impact of air quality on housing prices. Research has employed objective measures of air quality, but only slightly confirms the hedonic theory in the best of cases: the implicit price function relating housing prices to air pollution will, ceteris paribus, be negatively sloped. This paper compares the performance of a spatial Durbin model when using both objective and subjective measures of pollution. On the one hand, we design an Air Pollution Indicator based on measured pollution as the objective measure of pollution. On the other hand, the subjective measure of pollution employed to characterize neighborhoods is the percentage of residents who declare that the neighborhood has serious pollution problems, the percentage being referred to as residents’ perception of pollution. For comparison purposes, the empirical part of this research focuses on Madrid (Spain). The study employs a proprietary database containing information about the price and 27 characteristics of 11,796 owner-occupied single family homes. As far as the authors are aware, it is the largest database ever used to analyze the Madrid housing market. The results of the study clearly favor the use of subjective air quality measures. 相似文献
ABSTRACT Optical satellite data is an efficient and complementary method to hydrographic surveys for deriving bathymetry in shallow coastal waters. Empirical approaches (in particular, the models of Stumpf and Lyzenga) provide a practical methodology to derive bathymetric information from remote sensing. Recent studies, however, have focused on enhancing the performance of such empirical approaches by extending them via spatial information. In this study, the relationship between multibeam depth and Sentinel-2 image bands was analyzed in an optically complex environment using the spatial predictor of kriging with an external drift (KED), where its external drift component was estimated: a) by a ratio of log-transformed bands based on Stumpf’s model (KED_S) and b) by a log-linear transform based on Lyzenga’s model (KED_L). Through the calibration of KED models, the study objectives were: 1) to better understand the empirical relationship between Sentinel-2 multispectral satellite reflectance and depth, 2) to test the robustness of KED to derive bathymetry in a multitemporal series of Sentinel-2 images and multibeam data, and 3) to compare the performance of KED against the existing non-spatial models described by Stumpf et al. and Lyzenga. Results showed that KED could improve prediction accuracy with a decrease in RMSE of 89% and 88%, and an increase in R2 of 27% and 14%, over the Stumpf and Lyzenga models, respectively. The decrease in RMSE provides a worthwhile improvement in accuracy, where results showed effective prediction of depth up to 6 m. However, the presence of higher concentrations of suspended materials, especially river plumes, can reduce this threshold to 4 m. As would be expected, prediction accuracy could be improved through the removal of outliers, which were mainly located in the channel of the river, areas influenced by the river plume, abrupt topography, but also very shallow areas close to the shoreline. These areas have been identified as conflictive zones where satellite-derived bathymetry can be compromised. 相似文献