Mineralogical and geochemical spatial analyses of a waste-rock dump at the Libiola Fe–Cu sulphide mine (Eastern Liguria,Italy)

In this work, we investigated a 3 ha sulphide-bearing waste-rock dump (Libiola Mine, Italy) using mineralogical, geochemical, and geostatistical analyses. The dumped materials were highly heterogeneous in grain size and lithology and varied both laterally and vertically. Other than the host rock of the ore, basalts and serpentinites, the dumped materials contained high amounts of low-grade chalcopyrite- and pyrite-rich mineralisations. Due to these characteristics and to the absence of minerals able to neutralise acidity, this waste-rock dump can be classified as an acid mine drainage (AMD) producer. The study confirms that AMD is still active and, in the best scenario, can persist for up to 6.17 × 10³ years. The consequences of this process are of serious environmental concern as it involves strong acidification of the circulating waters, the release of potentially toxic metals into the soil, streams and rivers and the precipitation of huge quantities of secondary Fe-oxides and Fe-oxyhydroxides.     

The humin structure of mucilage aggregates in the Adriatic and Tyrrhenian seas: hypothesis about the reasonable causes of mucilage formation

Sixteen mucilages sampled in the Adriatic and Tyrrhenian seas during 1999–2001 were characterised using spectroscopic [Fourier transform infrared spectroscopy (FTIR); colorimetric], chromatographic [thin-layer chromatography (TLC)], and elemental analysis techniques. Most samples contained comparable fractions of organic and inorganic compounds, with the exception of a few samples where the inorganic fraction was greater than the organic fraction. Carbohydrates were important in the samples rich in organic matter, while carbonate and silica (quartz and biogenic silica) were the most important constituents of the inorganic fraction. Carbonate and silica were the only important constituents of the samples with a very low organic content.According to chemical analyses, mucilage aggregates show the typical structure of humin—the insoluble fraction of the humic substance. Classification of mucilage samples as humin-like compounds, together with a reexamination of the factors involved in the formation of organic aggregates in marine environment, has led to the formulation of a reasonable hypothesis for mucilage formation.     

I Zwicky 1: Decomposition and dynamics of the nearby QSO host

We address current theories of research on morphology, environment and evolution of active galaxies in the form of a detailed case study of the nearby QSO host I Zw 1. This study is based on sub-kpc resolution ¹²CO(1-0) observations with the BIMA mm-interferometer and on near-infrared imaging with ISAAC at the VLT. The ¹²CO(1-0) maps reveal a circumnuclear molecular gas ring with a radius of 0.9 kpc. The imaging data in the J-band are analyzed with respect to a disk-bulge decomposition. Together with a model of the gas rotation curve, the radial profile of the dynamical J-band mass-to-light ratio (M/L) is discussed. The J-band images give new evidence for an interaction between I Zw 1 and its nearby companion. First results from a sequence of N-body simulations for an extensive test of the parameter space of the interaction are presented. This revised version was published online in August 2006 with corrections to the Cover Date.     

High‐pressure phase transitions of α‐quartz under nonhydrostatic dynamic conditions: A reconnaissance study at PETRA III

Hypervelocity collisions of solid bodies occur frequently in the solar system and affect rocks by shock waves and dynamic loading. A range of shock metamorphic effects and high‐pressure polymorphs in rock‐forming minerals are known from meteorites and terrestrial impact craters. Here, we investigate the formation of high‐pressure polymorphs of α‐quartz under dynamic and nonhydrostatic conditions and compare these disequilibrium states with those predicted by phase diagrams derived from static experiments under equilibrium conditions. We create highly dynamic conditions utilizing a mDAC and study the phase transformations in α‐quartz in situ by synchrotron powder X‐ray diffraction. Phase transitions of α‐quartz are studied at pressures up to 66.1 and different loading rates. At compression rates between 0.14 and 1.96 GPa s^?1, experiments reveal that α‐quartz is amorphized and partially converted to stishovite between 20.7 GPa and 28.0 GPa. Therefore, coesite is not formed as would be expected from equilibrium conditions. With the increasing compression rate, a slight increase in the transition pressure occurs. The experiments show that dynamic compression causes an instantaneous formation of structures consisting only of SiO₆ octahedra rather than the rearrangement of the SiO₄ tetrahedra to form a coesite. Although shock compression rates are orders of magnitude faster, a similar mechanism could operate in impact events.     

Neutral hydrogen gas in interacting galaxies: the NGC 1511 galaxy group

We present H  i line and 20-cm radio continuum observations of the NGC 1511 galaxy group obtained with the Australia Telescope Compact Array. The data reveal an extended, rather disturbed H  i distribution for the peculiar starburst galaxy NGC 1511 and a narrow bridge to its small companion galaxy, NGC 1511B, which has been severely distorted by the interaction/collision between the two galaxies. No stellar counterpart to the gaseous bridge has been detected. In addition, we find that the peculiar optical ridge to the east of NGC 1511 is probably the stellar remnant of a galaxy completely disrupted by interactions with NGC 1511. The slightly more distant neighbour, NGC 1511A, shows a regular H  i velocity field and no obvious signs of interactions.
Radio continuum emission from NGC 1511 reveals three prominent sources on top of a more diffuse, extended distribution. We derive an overall star formation rate of  7 M_⊙ yr⁻¹  . The most enhanced star formation is found in the south-eastern part of the disc, coincident with several bright H  ii regions, and closest to the peculiar optical ridge. No continuum emission was detected in the companions, but NGC 1511B appears to show an H  ii region at its faint western edge, closest to NGC 1511. The group displays a prime example of interaction-induced star formation activity.     

GDP and employment effects of policies to close the 2020 emissions gap

Four policies might close the gap between the global GHG emissions expected for 2020 on the basis of current (2013) policies and the reduced emissions that will be needed if the long-term global temperature increase can be kept below the 2 °C internationally agreed limit. The four policies are (1) specific energy efficiency measures, (2) closure of the least-efficient coal-fired power plants, (3) minimizing methane emissions from upstream oil and gas production, and (4) accelerating the (partial) phase-out of subsidies to fossil-fuel consumption. In this article we test the hypothesis of the International Energy Agency (IEA) that these policies will not result in a loss of gross domestic product (GDP) and we estimate their employment effects using the E3MG global macro-econometric model. Using a set of scenarios we assess each policy individually and then consider the outcomes if all four policies were implemented simultaneously. We find that the policies are insufficient to close the emissions gap, with an overall emission reduction that is 30% less than that found by the IEA. World GDP is 0.5% higher in 2020, with about 6 million net jobs created by 2020 and unemployment reduced.

Policy relevance

The gap between GHG emissions expected under the Copenhagen and Cancun Agreements and that needed for emissions trajectories to have a reasonable chance of reaching the 2 °C target requires additional policies if it is to be closed. This article uses a global simulation model E3MG to analyse a set of policies proposed by the IEA to close the gap and assesses their macroeconomic effects as well as their feasibility in closing the gap. It complements the IEA assessment by estimating the GDP and employment implications separately by the different policies year by year to 2020, by major industries, and by 21 world regions.     

Time distributions in satellite constellation design

The aim of the time distribution methodology presented in this paper is to generate constellations whose satellites share a set of relative trajectories in a given time, and maintain that property over time without orbit corrections. The model takes into account a series of orbital perturbations such as the gravitational potential of the Earth, the atmospheric drag, the Sun and the Moon as disturbing third bodies and the solar radiation pressure. These perturbations are included in the design process of the constellation. Moreover, the whole methodology allows to design constellations with multiple relative trajectories that can be distributed in a minimum number of inertial orbits.     

Functioning of intertidal flats inferred from temporal and spatial dynamics of O<Subscript>2</Subscript>, H<Subscript>2</Subscript>S and pH in their surface sediment

In this article, we describe the dynamics of pH, O₂ and H₂S in the top 5–10 cm of an intertidal flat consisting of permeable sand. These dynamics were measured at the low water line and higher up the flat and during several seasons. Together with pore water nutrient data, the dynamics confirm that two types of transport act as driving forces for the cycling of elements (Billerbeck et al. 2006b): Fast surface dynamics of pore water chemistry occur only during inundation. Thus, they must be driven by hydraulics (tidal and wave action) and are highly dependent on weather conditions. This was demonstrated clearly by quick variation in oxygen penetration depth: Seeps are active at low tide only, indicating that the pore water flow in them is driven by a pressure head developing at low tide. The seeps are fed by slow transport of pore water over long distances in the deeper sediment. In the seeps, high concentrations of degradation products such as nutrients and sulphide were found, showing them to be the outlets of deep-seated degradation processes. The degradation products appear toxic for bioturbating/bioirrigating organisms, as a consequence of which, these were absent in the wider seep areas. These two mechanisms driving advection determine oxygen dynamics in these flats, whereas bioirrigation plays a minor role. The deep circulation causes a characteristic distribution of strongly reduced pore water near the low water line and rather more oxidised sediments in the centre of the flats. The two combined transport phenomena determine the fluxes of solutes and gases from the sediment to the surface water and in this way create specific niches for various types of microorganisms.