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1.
Hannu Huhma Robert A. Cliff Vesa Perttunen Matti Sakko 《Contributions to Mineralogy and Petrology》1990,104(3):369-379
The Peräpohja schist belt in northern Finland rests unconformably on Archaean granitoids, and marks the early stages of Proterozoic crustal evolution in the Fennoscandian (Baltic) shield. 2440 Ma old layered mafic intrusions predate the supracrustal , and ca. 2200 Ma old sills of the gabbro-wehrlite association intrude the lowest quartzites and volcanics (Runkaus) of the sequence. The Sm-Nd mineral isochron of the Penikat layered intrusion gives an age of 2410±64 Ma. The initial Nd-values of the Penikat intrusion (Nd(2440) = –1.6) and the Runkausvaara sill (Nd(2200) 0) suggest that these mafic magmas were contaminated by older crustal material. The Sm-Nd and Pb isotopic results on the 2.44–2.2 Ga old Runkaus volcanics indicate mobility of Pb, fractionation of Sm/Nd during late greenschist facies metamorphism, and crustal contamination. The Pb-Pb data provide an age of 1972±80 Ma with a high initial 207Pb/204Pb ratio (1 = 8.49), while scattered Sm-Nd data result in an imprecise age of 2330±180 Ma, with an initial Nd-value of about zero. Secondary titanite gives an U-Pb age of ca. 2250 Ma. The Jouttiaapa basalts, in contrast, ascended from the mantle without interaction with older crust. These LREE depleted tholeiites mark a break in continental sedimentation, and yield a Sm-Nd age of 2090±70 Ma. Their initial Nd = + 4.2 ±0.5 implies that the subcontinental early Proterozoic mantle had been depleted in LREE for a long period of time. The first lava flows are strongly depleted in LREE, suggesting that their source was significantly more depleted than the source of mid-ocean ridge basalts today. 相似文献
2.
3.
The origin of reaction textures in mantle peridotite xenoliths from Sal Island, Cape Verde: the case for “metasomatism” by the host lava 总被引:1,自引:1,他引:1
Cliff S. J. Shaw Florian Heidelbach Donald B. Dingwell 《Contributions to Mineralogy and Petrology》2006,151(6):681-697
Reaction zones around minerals in mantle xenoliths have been reported from many localities worldwide. Interpretations of the origins of these textures fall into two groups: mantle metasomatic reaction or reaction during transport of the xenoliths to the surface. A suite of harzburgitic mantle xenoliths from Sal, Cape Verde show clear evidence of reaction during transport. The reactions resulted in the formation of olivine–clinopyroxene and Si- and alkali-rich glass reaction zones around orthopyroxene and sieve-textured clinopyroxene and sieve textured spinel, both of which are associated with a Si- and alkali-rich glass similar to that in the orthopyroxene reaction zones. Reaction occurred at pressures less than the mantle equilibration pressure and at temperatures close to the liquidus temperature of the host magma. In addition, there is a clear spatial relation of reaction with the host lava: reaction is most intense near the lava/xenolith contact. The residence time of the xenoliths in the host magma, determined from Fe–Mg interdiffusion profiles in olivine, was approximately 4 years. Our results cannot be reconciled with a recent model for the evolution of the mantle below the Cape Verde Archipelago involving mantle metasomatism by kimberlitic melt. We contend that alkali-rich glasses in the Sal xenoliths are not remnants of a kimberlitic melt, but rather they are the result of reaction between the host lava or a similar magma and xenolith minerals, in particular orthopyroxene. The formation of a Si- and alkali-rich glass by host magma–orthopyroxene reaction appears to be a necessary precursor to formation of sieve textured spinel and clinopyroxene. 相似文献
4.
Syn‐metamorphic folding in the Tauern Window,Austria dated by Th–Pb ages from individual allanite porphyroblasts 下载免费PDF全文
R. A. Cliff F. Oberli M. Meier G. T. R. Droop M. Kelly 《Journal of Metamorphic Geology》2015,33(4):427-435
High‐precision 232Th–208Pb dates have been obtained from allanite porphyroblasts that show unambiguous microstructural relationships to fabrics in a major syn‐metamorphic fold in the SE Tauern Window, Austria. Three porphyroblasts were analysed from a single garnet mica schist from the Peripheral Schieferhülle in the core of the Ankogel Synform, one of a series of folds which developed shortly before the thermal peak of Alpine epidote–amphibolite facies metamorphism: allanite grain 1 provided two analyses with a combined age of 27.7 ± 0.7 Ma; grain 2, which was slightly bent and fractured during crenulation, provided two analyses with a combined age of 27.7 ± 0.4 Ma; a single analysis from grain 3, which overgrew an already crenulated fabric, gave an age of 28.0 ± 1.4 Ma. The five 232Th–208Pb ages agree within error and define an isochron with an age of 27.71 ± 0.36 Ma (95% confidence level; MSWD = 0.46). The results imply that the crenulation event was in progress in a short interval (<1 Ma) c. 28 Ma, and that the Ankogel Synform was forming at this time. The thermal peak of regional metamorphism in the SE Tauern Window was probably attained shortly after 28 Ma, only c. 5 Ma after eclogite facies metamorphism in the central Tauern Window. Metasediment may contain allanite porphyroblasts with clear‐cut microstructural relationships to fabric development and metamorphic crystallization; for such rocks, 232Th–208Pb dating on microsamples offers a powerful geochronological tool. 相似文献
5.
The current study provides long-term catch-rate, biological and feeding data for smooth hammerhead sharks, Sphyrna zygaena, caught in South Africa’s KwaZulu-Natal bather protection programme. In total, 2 512 S. zygaena were caught in net installations between 1978 and 2014, and 72 S. zygaena were caught on drumlines between 2007 and 2014. There was no significant log-linear year trend in the net catch rate over time (slope = 0.0054, t = 1.808, p = 0.07). However, there was a significant temporal increase in mean size of the captured sharks (slope = 0.0012, t = 3.502, p < 0.001). A quasi-Poisson generalised additive mixed model showed that increasing latitude, winter months, colder sea temperatures and the deployment of drumlines all had a significant positive effect on the catch rate of sharks in nets. The size frequency of the catch was unimodal, with significantly more females caught in the nets and more males on the drumlines. The majority (93.1%) of all sharks caught were immature and measured between 80 and 120 cm precaudal length. Teleosts and cephalopods dominated the sharks’ diet in terms of all dietary indices. The prey species consumed indicate that immature S. zygaena are feeding primarily within the pelagic zone of shallow coastal habitats. 相似文献
6.
Abstract: Two adjacent volcanogenic massive sulfide (VMS) deposits, the Main Malusok and the Malusok Southeast, are delineated within Barangay Tabayo, Siocon, Zamboanga del Norte, Mindanao, Philippines. These deposits comprise massive to semi-massive sulfide lenses representing the down-dip equivalent of oxidized gossans. The massive sulfides have a primary mineral assemblage of pyrite-chalcopyrite-sphalerite with significant amounts of supergene copper in the form of chal-cocite. Owing to structural and metamorphic overprinting combined with intense alteration, primary textures are generally obliterated. Rock types are classified according to dominant mineral assemblages whereas the main lithologic units comprising the Malusok volcanic package are divided based on the position of each unit relative to the mineralized zone. The main lithologic units are designated as the hanging wall, the host, and the footwall sequences. In correlating the stratigraphy of the Main Malusok zone with that of the Malusok Southeast zone, a chlorite/epidote-rich interval located at the base of the hanging wall sequence serves as a distinct stratigraphic marker from which all lithologies are referred to. Comparisons between the stratigraphy of the two areas show that massive to semi-massive sulfide lenses are confined within a single stratigraphic interval representing the favorable horizon for the entire Malusok area. However, differences exist relative to style of mineralization and configuration of the altered interval between the Main Malusok and the Malusok Southeast VMS deposits. Based on characteristics exhibited by each individual deposit, it is inferred that the Main Malusok VMS deposit overlies a feeder zone whereas the Malusok Southeast sulfide lenses represent satellite deposits and transported blocks. 相似文献
7.
Shaw Cliff S. J. Thibault Yves Edgar Alan D. Lloyd Felicity E. 《Contributions to Mineralogy and Petrology》1998,132(4):354-370
Experiments dissolving orthopyroxene (En93) in a variety of Si-undersaturated alkaline melts at 1 atmosphere and variable f
O2 demonstrate that orthopyroxene dissolves to form olivine, Si-rich melt and clinopyroxene. These phases form a texturally
and chemically distinct boundary layer around the partly dissolved orthopyroxene crystals. The occurrence of clinopyroxene
in the boundary layer is due to inward diffusion of Ca from the solvent melt to the boundary layer causing clinopyroxene saturation.
Compositional profiles through the solvent and the boundary layer for a number of experiments demonstrate rapid diffusion
of cations across the boundary layer – solvent interface. SiO2 diffuses outward from the boundary layer whereas CaO and Al2O3 diffuse toward the Si-enriched boundary layer melt. The rate of Al diffusion is slower under reducing conditions compared
to the rates in experiments performed in air. Concentrations of FeO and MgO in the boundary layer and solvent are approximately
equal indicating rapid diffusion and attainment of equilibrium despite ongoing crystallisation of clinopyroxene within the
boundary layer. The behaviour of Na2O and K2O is strongly affected by f
O2. Under reducing conditions Na2O and K2O concentrations are approximately equal in the boundary layer and solvent indicating normal diffusion down the concentration
gradient and attainment of equilibrium. Under oxidising conditions, K2O and to a lesser extent Na2O, have compositional profiles indicative of uphill diffusion likely due to their preference for more polymerised Si- and
Al-rich melts. Under reduced conditions Al-enrichment in the boundary layer melt is not as extreme and uphill diffusion did
not occur. The composition of the solvent melt after the experiments indicates that it was contaminated by the boundary layer
by convective mixing due to the onset of hydrodynamic instabilities brought on by density and viscosity contrasts between
the two melts. Despite using a wide variety of solvent melt compositions we find that the boundary layer melts converge toward
a common composition at high SiO2 contents. The composition of glass generated by orthopyroxene dissolution at 1 atmosphere is similar in many respects to
Si-rich glass found in many orthopyroxene-rich mantle xenoliths that have been attributed to high pressure in situ processes
including mantle metasomatism. The results of this study suggest that at least some Si-rich melts are likely to have formed
by dissolution of xenolith orthopyroxene at low pressure possibly by their Si-undersaturated host magmas.
Received: 30 August 1996 / Accepted: 15 April 1998 相似文献
8.
Neodymium and strontium isotopic analyses from the Kalka layered basic intrusion, central Australia, are arrayed parallel to the Sr-axis of a Nd-Sr isotopic correlation diagram and are removed from the normal basaltic field. Initial143Nd/144Nd ratios are almost constant and typical of continental basalts, whereas initial87Sr/86Sr ratios vary greatly and range to high values (0.7049–0.7088). Acidic granulites from the country rock lie upon the continuation of the Kalka trend at higher87Sr/86Sr ratios outlining a mixing system between granulite and normal basaltic magma. If average granulite acted as a contaminant, isotope dilution calculations show that amounts assimilated reached as high as 25%. Bulk contamination is confirmed petrologically by the abundance of orthopyroxene, particularly as basal orthopyroxenites and the restriction of olivine to less-contaminated levels. Analogies between Kalka and several other major layered intrusions, such as the Bushveld Complex, suggest that large-scale contamination was a significant aspect of their genesis. 相似文献
9.
R. A. Cliff 《Contributions to Mineralogy and Petrology》1980,71(3):283-288
U/Pb isotopic data for two zircon suites are presented:
- a pre D 1 tonalite gneiss gives an age of 443 ± 16 13 m.y.
- a post D 1 leucogranite gneiss gives 427 ± 11 10 m.y.
10.
Cliff S. J. Shaw 《Contributions to Mineralogy and Petrology》2006,151(6):665-680
The dissolution rate of quartz in melts of the CMAS and CAS systems at 1,600°C and 1.5 GPa is a function of both the silica activity of the melt and its viscosity. In melts with low silica activity quartz dissolves more quickly than in higher aSiO2 melts regardless of viscosity. For melts with equal aSiO2, dissolution is faster in the low viscosity melt. Quartz dissolution is controlled by interface kinetics in three of the four melts used in this study for times much greater than predicted by the model of Zhang et al. (in Contrib Mineral Petrol 102:492–513 1989). One melt which was previously shown to adhere to the predicted behaviour at lower temperature shows a significant activation time at higher temperature. All the dissolution data indicate that there are likely to be three distinct domains of dissolution behaviour, although the details of why a particular melt falls in any one domain require further study. Although the current database is small, the relationship between quartz solubility and the dissolution constant indicate that solubility may be a useful parameter for predicting dissolution rates, particularly if silica activity and melt viscosity are also known. 相似文献