城镇化与区域工程地质学发展机遇

城镇化是我国现代化进程中的最伟大工程,2001年诺贝尔经济学奖获得者J.Stiglitse把中国的城镇化与美国的高科技并列为影响21世纪人类发展进程的两大关键因素。协调好城市化进程中强大的人类工程活动同复杂的地质环境变化间的关系是我国工程地质工作者的责任与义务,也是工程地质学发展的机遇。充分学习、借鉴地球科学相关学科领域的新观念、新成果、新资料,开展区域工程地质研究,探寻我国区域工程地质环境的形成演化和工程建设与地质环境间的相互作用规律,实现城镇化与地质环境的和谐。     

Experimental and theoretical methods on determination of stress-dependent natural frequency of marine sedimentary clay

Excited by the vibration sources in dynamic engineering, the natural frequency and damping factor of the saturated marine sedimentary clay are key dynamic parameters that influence the responses under cyclic loads. Experimental and theoretical methods are proposed in this paper to analyze the natural frequency and the stress-dependent nonlinearity. The experimental method shows that the natural frequency of soils with specific stress state subjected to large cyclic shear strain can be estimated from the data of dynamic triaxial tests based on the amplitude–frequency response curve. Trial and error by the criterion from the half-power bandwidth method is used to determine the optimal fitting. The results of a theoretical study on the free vibration of soil layers are then presented to derive the analytic solution of natural frequency. In addition to the two frequency-independent elements (a lumped mass matrix and a stiffness matrix), the system’s equivalent damping coefficient matrix is iteratively determined based upon the forced vibration experimentally. Finally, the impacts of the resonance phenomenon on the dynamic shear modulus and hysteretic loop are discussed.     

Structural features and petroleum geology of the fold-thrust belt in the southern Tarim basin, China

The west Kunlun fold-thrust belt (WKFTB) and the Altun fold-thrust belt (AFTB) are respectively located in the southern margin of the Tarim basin, NW China. The analyses of typical structures and regional dynamics of the fold-thrust belts reveal their different structural and petroleum features and mechanisms. WKFTB differs from AFTB by abundant fault-related folds and triangles zones, and was formed by northward extrusion of the west Kunlun orogen. AFTB was affected synchronously by northward extrusion of the Altun orogen and the sinistral strike-slipping of the Altun Fault, so it is characterized by the minor scale and the monotonous structural styles. The Aqike anticline and the Aqike fault, of which the strikes are orthogonal to the strike of the fold-thrust belts, are regarded as the adjustive structures between both of the fold-thrust belts. The oil-gas pools of WKFTB develop mainly in the faulted-related anticline traps, but the oil-gas pools of AFTB develop mainly in the low fault-block and anticlines traps related with the paleo-uplifts. There are different exploration countermeasures for both of the fold-thrust belts.     

川东北地区海相烃源岩中单质硫的定性与定量分析

利用定性与定量分析手段,研究了川东北地区各类海相烃源岩中的单质硫及其地球化学特征。定性分析表明,该区海相烃源岩中的单质硫具有八硫环状结构和六硫状环结构两种晶体构型,由S8和S6两种同素异形体组成,其中S8具有相对较高的丰度。定量分析表明,该区海相烃源岩中的单质硫含量为0.91×10-6～375.88×10-6,具有很宽的分布范围,并且随着烃源岩分布区域、地层时代以及岩性的不同而发生明显变化,表现出强烈的非均质性分布特征。该区海相烃源岩中单质硫含量与有机碳含量之间存在正相关关系,说明单质硫主要发育在富有机质沉积的层段中。通过单质硫含量与总硫含量对比分析,间接证明了川东北地区各类海相烃源岩中赋存有丰富的有机含硫化合物。     

Organochlorine Pesticide Residues in Soils and Sediments of the Herbert and Burdekin River Regions, North Queensland – Implications for Contamination of the Great Barrier Reef

Organochlorine pesticides were widely used in the Australian sugarcane industry from the early 1950s until the late 1980s. Erosion of sugarcane soils and subsequent transport of sediment bound contaminants in river run-off to the Great Barrier Reef lagoon is a growing concern as the cane industry continues to expand. Organochlorine pesticide residues can be used as tracers to examine the worst-case scenario of the spatial extent to which currently used, though less persistent, organic agricultural pesticides might extend. The coastal alluvial flood-plains of the Herbert and Burdekin Rivers in North Queensland have sugarcane growing as the major coastal land-use. Sediment cores and surface sediment samples were collected from near-shore coastal regions of the Herbert and Burdekin Rivers. In addition, soil samples from cane-fields in the two catchments were collected. Analyses of the marine surface sediment samples and three sediment cores revealed the absence of detectable concentrations of organochlorine pesticides (<5 pg/g). However, easily detectable concentrations were found in the sugarcane soil samples (0.01–45 ng/g).     

Wet deposition of excess sulfate at Macquarie Island, 54° S

Annual wet deposition of excess sulfate at Macquarie Island has been estimated from 5 months of rainwater composition data covering the Austral summer of 1985/86. The resulting figure of 2.1±0.6 mmol/m²/yr is at the low end of previous estimates of maritime excess sulfate deposition by precipitation. Within estimated uncertainty limits this figure is consistent with the DMS emission flux which would be predicted for latitude 50°–60° S, based solely on available Northern Hemispheric DMS measurements.Temporarily at the International Meteorological Institute, Stockholm University, S-106 91, Stockholm, Sweden.     

Salinisation de l’aquifère libre de la Chaouia côtière (Azemmour-Tnine Chtouka), Maroc

L’aquifère libre de la Chaouia côtière constitue un exemple des aquifères les plus exploités au Maroc. Ce travail est consacré à l’étude des processus de la salinisation des eaux souterraines par l’analyse physico-chimique de 39 puits répartis dans la zone. Deux types de faciès ont été révélés, l’un est chloruré-sodique dans la frange côtière ; l’autre faciès est de type chloruré bicarbonaté-calcique caractérisant les eaux exploitées dans les calcaires marneux du Crétacé. L’influence marine (aérosols et intrusion marine), la dissolution/précipitation de la roche aquifère et l’infiltration des eaux d’irrigation, sont parmi les causes de l’augmentation de la salinité des eaux souterraines, en plus de l’exploitation excessive de l’eau souterraine.     

Latitudinal variation of measured O3 photolysis frequencies J(O1D) and primary OH production rates over the Atlantic Ocean between 50° N and 30° S

The latitudinal variation of the photolysis frequency of ozone to O(¹D) atoms, J(O¹D), was measured using a filter radiometer during the cruise ANT VII/1 of the research vessel Polarstern in September/October 1988. The J(O¹D) noon values exhibited a maximum of 3.6×10^-5 s^-1 (2 sr) at the equator and decreased strongly towards higher latitudes. J(O¹D) reached highest values for clean marine background air with low aerosol load and almost cloudless sky. The J(O¹D) data, measured under these conditions and a temperature of 295 K, can be expressed by: % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaamOsaiaacI% cacaqGpbWaaWbaaSqabeaaiiaacqWF8baFaaGccaqGebGaaeykaiaa% bccacqWF9aqpcaqGGaGaaeyzaiaabIhacaqGWbGaaeiiaiaabUhacq% GHsislcaaI4aGaaiOlaiaaicdacaaIYaGaeyOeI0IaaGioaiaac6ca% caaI4aGaaiiEaiaaigdacaaIWaWaaWbaaSqabeaacqGHsislcaaIZa% aaaOGaaeiiaiaabIhacaqGGaGaam4uaiabgUcaRiaaiodacaGGUaGa% aGinaiaacIhacaaIXaGaaGimamaaCaaaleqabaGaeyOeI0IaaGOnaa% aakiaadofadaahaaWcbeqaaiaaikdaaaGccaGG9bGaaeikaiaaboha% daahaaWcbeqaaiabgkHiTiaaigdaaaGccaGGPaaaaa!5EE9!\[J({\text{O}}^| {\text{D) }} = {\text{ exp \{ }} - 8.02 - 8.8x10^{ - 3} {\text{ x }}S + 3.4x10^{ - 6} S^2 \} {\text{(s}}^{ - 1} )\] where S represents the product of the overhead ozone column (DU) and the secant of the solar zenith angle. The meridional profile of the primary OH radical production rate P(OH) was calculated from the J(O¹D) measurements and simultaneously recorded O₃ and H₂O mixing ratios. While the latitudinal distribution of J(O¹D) and water vapour was nearly symmetric to the equator, high tropospheric ozone levels up to 40 ppb were observed in the Southern Hemisphere, SH, resulting in higher P(OH) in the SH.     

Challenges associated with pre-border management of biofouling on oil rigs

The potential for oil rigs to transport diverse, reef-like communities around the globe makes them high risk vectors for the inadvertent spread of non-indigenous species (NIS). This paper describes two case studies where a suite of pre-border management approaches was applied to semi-submersible drilling rigs. In the first case study, a drilling rig was defouled in-water prior to departure from New Zealand to Australia. Risk mitigation measures were successful in reducing biosecurity risks to the recipient region, but they resulted in the unintentional introduction of the non-indigenous brown mussel (Perna perna) to New Zealand when the rig was defouled in-water by divers. In the second case study, lessons learned from this high-profile incursion resulted in a more structured approach to pre-border management, and this serves as a useful template for future rig transfers.     

Episodic fluid movements in superimposed basin:Combined evidence from outcrop and fluid inclusions of the Majiang ancient oil reservoir,Guizhou Province

Combined evidence from the outcrop and the fluid inclusion assemblage (FIA) analysis indicates that there exist two episodes of fluid flow controlled by the tectonic activity. The first episode was recorded mainly in the reservoir rock of the Honghuayuan Formation,representing the fluid flow of hydrocarbon charging. The second episode occurred mainly along the fault systems,representing the fluid move-ment when the ancient oil reservoir was destroyed. The host mineral morphology,homogeneous tem-perature,and salinity of the FIAs record an episodic fluid movement. Characters of high homogenous temperature,low salinity and a quick temperature variation of the first episode fluid flow may indicate an early-stage fluid eruption,and correspondingly,fine-grained calcite was formed. Temperature of the erupted fluid tended to decrease during its mixing with the upper formation fluid and finally had the same temperature as the upper formation. From then on,the temperature was rather steady and fa-vored the growth of the coarse calcite. Due to this character of the temperature variation of the episodic fluid flow,we can use the homogenous temperature of the FIA of the coarse calcite to date the forma-tion and the destruction time of the Majiang ancient oil reservoir. Episodic fluid flow was known for its inhomogeneous trapping,which resulted in the failure of dating according to the burial history. But taking a close look at its temperature variation,we think that the latest stage of fluid flow,characterized by steady state temperature and grow of the coarser crystals,can be used for dating. It will be of great value if this method is proved to be effective. The formation and the destruction time of the Majiang ancient oil reservoir were dated to be in the Indosinian Period and the late Yanshan-early Hymalayan Period respectively. This conclusion is in great discrepancy with the common accepted idea that the Majiang ancient oil reservoir was formed and destroyed during the Caledonian tectonic movement. Even so,this paper further discussed its reliability from the view of the source rock evolution and also the local tectonic evolution.