新疆东准库布苏金矿床石英矿物标型特征及找矿评价意义

新疆东准库布苏金矿床石英矿物标型特征及找矿评价意义张旺生高怀忠吕瑞英（中国地质大学,武汉４３００７４）关键词石英标型特征找矿评价东准噶尔新疆１金矿成矿阶段石英的一般特征库布苏金矿位于新疆东准噶尔野马泉南约１６ｋｍ,矿区所属构造单元为西伯利亚板块准噶...     

安家营子金矿含金和无金石英的标型特征

系统研究了安家营子金矿区含金石英和无金石英的微量元素、流体包裹体、颜色、比重、发光、晶胞参数和红外光谱等标型特征，并依据所得数据对这两类石英进行了判别分析，提出了一系列的找矿标志。     

Geology and fluid inclusion of Wadi Sharis Neoproterozoic orogenic gold deposits in northwestern Yemen

The Wadi Sharis orogenic gold deposit in northwestern Yemen is related to the fault and shear zones vein at medium depth in the crust in the Neoproterozoic meta-sedimentary and meta-volcanosedimentary succession of greenschist to amphibolite facies metamorphism.Three distinct fluid inclusion types have been identified in the gold-bearing quartz sulphide veins of the deposit:(1) type I:vapour-liquid two-phase(VH2O-LH2O),(2) type II:three-phase CO2(VCO2-LH2O-LCO2) and(3) type III:vapour-rich(LCO2-VCO2) inclus...     

Fluid generation and evolution during exhumation of deeply subducted UHP continental crust: Petrogenesis of composite granite–quartz veins in the Sulu belt,China

Composite granite–quartz veins occur in retrogressed ultrahigh pressure (UHP) eclogite enclosed in gneiss at General's Hill in the central Sulu belt, eastern China. The granite in the veins has a high‐pressure (HP) mineral assemblage of dominantly quartz+phengite+allanite/epidote+garnet that yields pressures of 2.5–2.1 GPa (Si‐in‐phengite barometry) and temperatures of 850–780°C (Ti‐in‐zircon thermometry) at 2.5 GPa (~20°C lower at 2.1 GPa). Zircon overgrowths on inherited cores and new grains of zircon from both components of the composite veins crystallized at c. 221 Ma. This age overlaps the timing of HP retrograde recrystallization dated at 225–215 Ma from multiple localities in the Sulu belt, consistent with the HP conditions retrieved from the granite. The ε_Hf(t) values of new zircon from both components of the composite veins and the Sr–Nd isotope compositions of the granite consistently lie between values for gneiss and eclogite, whereas δ¹⁸O values of new zircon are similar in the veins and the crustal rocks. These data are consistent with zircon growth from a blended fluid generated internally within the gneiss and the eclogite, without any ingress of fluid from an external source. However, at the peak metamorphic pressure, which could have reached 7 GPa, the rocks were likely fluid absent. During initial exhumation under UHP conditions, exsolution of H₂O from nominally anhydrous minerals generated a grain boundary supercritical fluid in both gneiss and eclogite. As exhumation progressed, the volume of fluid increased allowing it to migrate by diffusing porous flow from grain boundaries into channels and drain from the dominant gneiss through the subordinate eclogite. This produced a blended fluid intermediate in its isotope composition between the two end‐members, as recorded by the composite veins. During exhumation from UHP (coesite) eclogite to HP (quartz) eclogite facies conditions, the supercritical fluid evolved by dissolution of the silicate mineral matrix, becoming increasingly solute‐rich, more ‘granitic’ and more viscous until it became trapped. As crystallization began by diffusive loss of H₂O to the host eclogite concomitant with ongoing exhumation of the crust, the trapped supercritical fluid intersected the solvus for the granite–H₂O system, allowing phase separation and formation of the composite granite–quartz veins. Subsequently, during the transition from HP eclogite to amphibolite facies conditions, minor phengite breakdown melting is recorded in both the granite and the gneiss by K‐feldspar+plagioclase+biotite aggregates located around phengite and by K‐feldspar veinlets along grain boundaries. Phase equilibria modelling of the granite indicates that this late‐stage melting records P–T conditions towards the end of the exhumation, with the subsolidus assemblage yielding 0.7–1.1 GPa at <670°C. Thus, the composite granite–quartz veins represent a rare example of a natural system recording how the fluid phase evolved during exhumation of continental crust. The successive availability of different fluid phases attending retrograde metamorphism from UHP eclogite to amphibolite facies conditions will affect the transport of trace elements through the continental crust and the role of these fluids as metasomatic agents interacting with the mantle wedge in the subduction channel.     

矿石中金的在线固相萃取及缝管火焰原子吸收测定

介绍了将流动注射在线因相萃取预浓集与石英缝管火焰原子吸收相结合测定矿石中金的方法，用ＸＡＤ－８吸附树脂填充的微型柱（１００μｌ）在６ｍｌ／ｍｉｎ的流速下，从０．５ｍｏｌ／ＬＨＣｌ介质的试样溶液中浓集金氯络合物，再用乙醇洗脱，最后由火焰原子吸收检测，在采样频率为１０３样／ｈ的流速下灵敏度提高４７倍，分析精度为１．３％，检出限为１．０μｇ／Ｌ；在６５样／ｈ的采样频率下灵敏度提高９５倍，检出限可达０．７     

西藏尼木县岗讲铜钼矿找矿方向研究

通过对岗讲矿区100多个钻孔资料的对比研究,三维模拟和区域矿床(点)对比分析,提出了岗讲铜钼矿床的成矿模型为,四周以"井字型"断裂环绕,平面以"似环状"形态分布,核部主体为不含矿英云闪长玢岩,并以30°~50°夹角从"柱状"体向四周以岩枝形态侵入,上部呈"蘑菇状"覆盖含矿二长花岗斑岩,在英云闪长玢岩与二长花岗斑岩接触带常伴随强烈的断裂破碎和泥化现象,二长花岗斑岩体内常形成一定规模的斑岩铜钼矿体。根据其成矿模型,寻找闪长玢岩(或者英云闪长玢岩)与二长花岗斑岩接触带及断裂构造交汇部位是今后找矿勘查工作的关键所在。     

The Miduk porphyry Cu deposit,Kerman, Iran: A geochemical analysis of the potassic zone including halogen element systematics related to Cu mineralization processes

Miduk hypogene and supergene porphyry Cu–Mo mineralization occurs within the Miocene porphyritic quartz–diorite and host Eocene plagioclase–hornblende phyric andesitic pyroclastic and flow sequence. Both the host rocks were extensively altered by hydrothermal fluids to dominantly potassic, phyllic, and argillic with interstitial to distal propylitic types.     

The magmatic–hydrothermal transition—evidence from quartz phenocryst textures and endoskarn abundance in Cu–Zn skarns at the Empire Mine, Idaho, USA

Information about the magmatic to hydrothermal transition is preserved in late-stage features of quartz phenocrysts and endoskarn alteration in some Cu–Zn skarn deposits such as the Empire Mine in Idaho. Important features include: (1) quartz phenocrysts with strong resorption textures such as vermicular zones of igneous groundmass cutting primary quartz cathodoluminescence banding, (2) anomalous amounts of endoskarn (more than 50% of mineralized rock), (3) high F activities as evidenced by fluorite as an accessory mineral in igneous rocks, in alteration assemblages, and in fluid inclusions and by high F in hydroxyl sites in igneous biotite and amphibole, and (4) direct association of Zn, which normally is deposited distally at low temperature, with Cu in proximal locations and in endoskarn. These features are explained by the following model: (1) F lowers the solidus temperature of the magma, thus changing the timing, temperature, and duration of hydrothermal fluid exsolution. (2) Upon magmatic vapor saturation the F-rich hydrothermal fluids form bubbles that adhere to quartz phenocrysts and chemically corrode/tunnel into the quartz forming vermicular resorption textures. (3) F-rich hydrothermal fluids also promote the formation of endoskarn; silicic rocks are attacked by F-rich fluids in the same sense that carbonate wall rocks are dissolved by weakly to moderately acidic hydrothermal fluids. (4) Low fluid exsolution temperature facilitated by high F activity promotes high Zn/Cu ratios in proximal locations due to the solubility of Zn relative to Cu at lower temperatures. This model may be applicable at other localities such as the world-class Cu–Zn skarn Antamina mine, as well as some tin and rapakivi granites.     

南天山基性麻粒岩中变形石英和石榴子石的TEM研究

基性麻粒岩产于大陆地壳深部,它的研究可以为大陆岩石圈的性质、组成、演化和深部动力学过程提供重要信息。南天山库米什榆树沟地区发育总厚达1000多米的基性麻粒岩构造岩片,走向南东,朝北东推覆。剖面上和石炭纪蛇绿混杂岩共存,并发生了石榴子石的旋转变形和强烈的石英-长石矿物相韧性变形。然而它们的变形条件至今尚未被研究。本文运用透射电镜(TEM)超微组构技术对榆树沟基性麻粒岩中石英和石榴子石进行了详细研究,结果表明,石英中存在着丰富的超显微变形构造,自由位错、亚颗粒和位错网非常发育,这表明研究区基性麻粒岩在折返抬升过程中曾遭受过较强的石英-长石相韧性变形作用;石榴子石中的超微变形构造则极为少见,只在其中发现几根自由位错,并在其颗粒边缘发现少量亚颗粒构造,说明该矿物主体属于脆性变形。这两种矿物变形性质的差异,反映了石榴子石的晶体结构在该条件下比石英更稳定,而且说明石榴子石的变质温度没有超过900℃,也就是说,本区麻粒岩的变质作用并非发生在极高温度的条件下。     

成矿溶液电导度和红外光谱在金矿找矿评价中的应用

电导度是溶液导电能力的相对尺度,电导度的大小能直接反映出成矿溶液浓度的高低.实验证明,成矿溶液相对高浓度聚集区,往往也是矿床的主矿体或富矿体赋存处.石英是刺猬沟和三道湾子金矿重要的脉石矿物,也是金的主要载体.借助于成矿溶液电导度和红外光谱方法对刺猬沟和三道湾子金矿区石英进行了分析.结果表明,成矿溶液电导度和红外光谱测定的DCO2与石英中Au含量呈正相关关系.成矿溶液电导度＞40.1μS,DCO2＞0.2矿化好.上述研究获得的信息对中生代陆相火山岩区寻找和评价石英脉型矿床具有指导意义.