草簇状石墨烯片限域Pd纳米粒子及其催化应用(英文)

通过氨基离子液体改性石墨烯,并将其固载于堇青石表面,作为负载型Pd催化剂的载体.所制备的Pd催化剂经加氢老化后,表面石墨烯呈草簇状结构,将Pd纳米粒子限域于片层内,有效防止了Pd的流失和团聚.在重要的工业反应对羧基苯甲醛(4-CBA)加氢中,此结构催化剂与传统的钯碳催化剂相比,表现出很好的稳定性     

内蒙赤峰莲花山金矿田石英脉的红外光谱成矿信息及定量预测

测试了１３０余件含金石英脉及不含金石英脉的红外光谱试样,查明了该区含金石英脉的红外光谱特征,同时配合其它预测含金石英脉的测量方法,提出了该区含金石英脉的预测靶区,经过初步验证,预测基本上是准确的。     

Oxidative–reductive photodecomposition of perfluorooctanoic acid in water

This article aims to elucidate on usefulness of vacuum ultraviolet (VUV) for photoreductive degradation of perfluorooctanoic acid (PFOA), a representative perfluorinated compound (PFC), in water for the first time. Bench-scale tests were conducted on oxidative and reductive (with aquated electron: e _aq ^? ) mineralization of PFOA using low-pressure UV (LPUV) lamps and potassium iodide. Unlike with 254 nm wavelength (UVC), the reductive mineralization with VUV was very inefficient compared to the corresponding oxidative mineralization. The inefficiency is attributed to low reactivity of e _aq ^? with PFOA and its fluorinated products than that of 185 nm photons. Direct VUV photolysis of PFOA and its products in reductive reaction conditions was not apparent due to a very big difference in reactivity of 185 and 254 nm photons with iodide. The results demonstrated that highly energetic VUV photons are not suitable for photoreductive degradations of PFCs involving e _aq ^? , but they can be best used for oxidative degradations. These findings should serve as an important reference on VUV usage to decompose refractory micropollutants.     

Borehole diffusive flux apparatus for characterizing diffusive mass-transfer in subsurface systems

The concept of the Borehole Diffusive Flux Apparatus (BDFA) is presented herein. The BDFA is an innovative apparatus designed to provide continuous direct access to an undisturbed column of sediment that can be monitored at multiple discrete vertical intervals to provide high-resolution characterization of local-scale mass transfer and attenuation. The conceptual basis and technical design of the device are presented, along with an example of borehole design and installation at a field site. Mathematical simulations are used to illustrate its application for two scenarios. The results of these simulations indicate that test periods of several weeks to a few months should be sufficient to obtain robust results. The device has the potential to improve our ability to characterize critical mass-transfer and attenuation processes and to quantify the associated rates. This information is key to the evaluation of remediation alternatives, for enhancing the accuracy of mathematical models, and to support more effective long-term management of large groundwater contaminant plumes present at many sites.     

建筑密集区高倾角三维地震勘探效果

高倾角地区(地层倾角40～70°)一直是三维地震勘探的难题,特别是在地表建筑物极复杂区(占工区的95%)实施三维地震勘探,显得难度更大。本文从观测系统设计、炮点、检波器的特殊布设及特观设计上,论证了其可行性。对高倾角且建筑物密集区的三维地震勘探进行了探索,并取得了可喜的成果。     

海南岛陆地区重力场变化与地震关系研究

研究反映测区重力场变化的两种方式:重力段差的时序变化图及测区重力场的平面变化图.结果表明,地震的孕育和发生伴随着重力场的变化.     

Effects of vegetation restoration on soil physical properties of abandoned farmland on the Loess Plateau,China

To improve the ecological environment in China, the Chinese government implemented a country-wide ecological protection and reforestation project (namely the “Grain for Green Project”) in 1999 to return cultivated land with slopes of 25° or more to perennial vegetation. Vegetation restoration reduces soil erosion mainly by changing the soil physical properties. Different vegetation restoration methods might produce different impacts on soil physical properties. In this study, two vegetation restoration methods (i.e., natural restoration and artificial restoration) were compared on abandoned farmland in the typically hilly and gullied areas of the Loess Plateau of Northwest China. In the natural restoration method, the farmland was abandoned to natural vegetation succession without irrigation, fertilization or other artificial disturbances. In the artificial restoration method, the farmland was planted with black locust (Robinia pseudoacacia L.) and watered and cultivated for the first two years. Three soil physical properties (i.e., soil moisture, bulk density and aggregation) were investigated under the two vegetation restoration methods. The results showed that the soil moisture and soil bulk density were higher under artificial restoration than under natural restoration within the first three years of vegetation restoration. By the fourth year, the soil moisture and soil bulk density were higher under natural restoration than under artificial restoration. For the stability of soil aggregates?>?0.25 mm, the soil aggregates in the 0-20 cm soil layer were more stable under artificial restoration than under natural restoration, while the results were the opposite for the 40-60 cm soil layer. Overall, the soil physical properties were continuously improved during the restoration of vegetation on abandoned farmland. In choosing between vegetation restoration methods, natural restoration is preferable to artificial restoration, but artificial intervention is needed during the first three years.     

Synthesis of zeolites using fly ash and their application in removing heavy metals from waters

Fly ash is the solid waste of thermal power plants where coal is used as fuel, and its management and utilization have been of environmental concern for decades. Since the technique of synthesizing zeolite from coal fly ash was introduced by Holler[1] (19…