雾化进样石墨炉原子吸收光谱法的研究 Ⅰ.直接雾化进样装置及其性能

介绍一种自行设计和加工的直接雾化石墨炉进样装置的结构、工作原理和操作方法。该装置由微机控制与石墨炉加热程序同步工作,可以实现自动控制和自动测量。对雾化进样石墨炉分析的仪器参数和实验条件进行了研究和选择。结果表明,该装置与石墨炉结合具有自动化程度高、重现性好、样品利用率高和分析速度快等特点。     

Vertical structures of PM10 and PM 2.5 and their dynamical character in low atmosphere in Beijing urban areas

The vertical structures and their dynamical character of PM2.5 and PM10 over Beijing urban areas are revealed using the 1 min mean continuous mass concentration data of PM2.5 and PM10 at 8, 100, and 320 m heights of the meteorological observation tower of 325 m at Institute of Atmospheric Physics, Chinese Academy of Sciences (IAP CAS tower hereafter) on 10―26 August, 2003, as well as the daily mean mass concentration data of PM2.5 and PM10 and the continuous data of CO and NO2 at 8, 100 (low layer), 200 (middle layer), and 320 m (high layer) heights, in combination with the same period meteorological field observation data of the meteorological tower. The vertical distributions of aerosols observed on IAP CAS tower in Beijing can be roughly divided into two patterns: gradually and rapidly decreasing patterns, I.e. The vertical distribution of aerosols in calm weather or on pollution day belongs to the gradually decreasing pattern, while one on clean day or weak cold air day belongs to the rapidly decreasing pattern. The vertical distributive characters of aerosols were closely related with the dynamical/thermal structure and turbulence character of the atmosphere boundary layer. On the clean day, the low layer PM2.5 and PM10 concentrations were close to those at 8 m height, while the concentrations rapidly decreased at the high layer, and their values were only one half of those at 8 m, especially, the concentration of PM2.5 dropped even more. On the clean day, there existed stronger turbulence below 150 m, aerosols were well mixed, but blocked by the more stronger inversion layer aloft, and meanwhile, at various heights, especially in the high layer, the horizontal wind speed was larger, resulting in the rapid decrease of aerosol concentration, I.e. Resulting in the obvious vertical difference of aerosol concentrations between the low and high layers. On the pollution day, the concentrations of PM2.5 and PM10 at the low, middle, and high layers dropped successively by, on average, about 10% for each layer in comparison with those at 8 m height. On pollution days, in company with the low wind speed, there existed two shallow inversion layers in the boundary layer, but aerosols might be, to some extent, mixed below the inversion layer, therefore, on the pollution day the concentrations of PM2.5 and PM10 dropped with height slowly; and the observational results also show that the concentrations at 320 m height were obviously high under SW and SE winds, but at other heights, the concentrations were not correlated with wind directions. The computational results of footprint analysis suggest that this was due to the fact that the 320 m height was impacted by the pollutants transfer of southerly flow from the southern peripheral heavier polluted areas, such as Baoding, and Shijiazhuang of Hebei Province, Tianjin, and Shandong Province, etc., while the low layer was only affected by Beijing's local pollution source. The computational results of power spectra and periods preliminarily reveal that under the condition of calm weather, the periods of PM10 concentration at various heights of the tower were on the order of minutes, while in cases of larger wind speed, the concentrations of PM2.5 and PM10 at 320 m height not only had the short periods of minute-order, but also the longer periods of hour order. Consistent with the conclusion previously drawn by Ding et al., that air pollutants at different heights and at different sites in Beijing had the character of "in-phase" variation, was also observed for the diurnal variation and mean diurnal variation of PM2.5 and PM10 at various heights of the tower in this experiment, again confirming the "in-phase" temporal/spatial distributive character of air pollutants in the urban canopy of Beijing. The gentle double-peak character of the mean diurnal variation of PM2.5 and PM10 was closely related with the evident/similar diurnal variation of turbulent momentum fluxes, sensible heat fluxes, and turbulent kinetic energy at various heights in the urban canopy. Besides, under the condition of calm weather, the concentration of PM2.5 and PM10 declined with height slowly, it was 90% of 8 m concentration at the low layer, a little lesser than 90% at the middle layer, and 80% at the high layer, respectively. Under the condition of weak cold air weather, the concentration remarkably dropped with height, it was 70% of 8 m concentration at the low layer, and 20%―30% at the middle and high layers, especially the concentration of PM2.5 was even lower.     

Upwelling of Deep-seated Fluid in the Sikhote-Alin Region,Far East of the Eurasian Plate

Aquatic Geochemistry - Spring waters with high-pCO2 content are widely distributed in the Sikhote-Alin region in Russia. Mukhen spa is one such spring located in the northern Sikhote-Alin region....     

灌淤土壤可溶性盐分空间变异性与棉花生长关系研究

运用地统计学方法,在灌淤土壤上进行了棉田土壤可溶性盐分的空间变异规律与棉花生长关系系统研究。传统统计学分析表明土壤盐分测试数据基本符合正态分布;在一定取样间距下,土壤可溶性盐分的田间合理取样数目为27。半方差分析显示：土壤可溶性盐分具中等的水平变异性,但随着聚样深度的增加未表现出明显的垂直变异特性;随着棉花的生长发育,土壤可溶性盐分呈现出逐渐减弱的时间变异规律,采用直线或曲线拟合方程估计了可溶性盐分的半方差图及其参数,并绘制了其相应的等值线图。土壤可溶性盐分与棉花产量之间的相关分析表明：可溶性盐分含量与棉花产量之间呈显著负相关关系,且花铃期的相关性较播前显著。研究结果为提高田间试验有效性以及盐渍化土壤改良提供了科学依据与基础资料。     

一个高分辨对流层物质交换模式

在区域酸沉积模式(RADM)基础上,设计了一个高分辨对流层(TL)物质交换模式(EM3)。EM3在以下五个方面明显不同于RADM:第一,增加行星边界层(PBL)的垂直网格层次;第二、TL内考虑分层的垂直涡旋扩散系数型;第三,使用TL内分层的水平涡旋扩散系数型;第四,采用包含有植物冠层垂直结构影响的新干沉积速度型;第五,使用数值扩散小的二阶矩守恒平流格式.用EM3和RADM对OSCAR Ⅳ实例作对比模拟,结果表明EM3能更好地预测出TL内的三维物质分布规律,在同样条件下,两模式预测的PBL低层中心浓度比值均大于1.8,最大值可大于3。     

CORROSION AND ADHERENCE AT SEA OIL-PLATFORM

Measurements of the adhesive corrosion and protective potentials of 3 Bohai Sea oilplatforms under different cathodic protection showed corrosion still occurred on these platforms undertheir designed protective potentials. Preliminary conclusions from indoor experiments on the relation betweenadhesive corrosion and cathodic protection showed adhering organisms caused the corrosion onthese platforms.     

基于实际材料图的三维断层模型动态构建方法

三维地质模型是地质调查信息表达从传统二维平面向三维空间转变的一次重大突破。中国正在开展的三维地质填图作为国家的重要基础地质调查工作部署,将调查与研究相结合,在推动三维地质建模从研究走向实践具有重大意义。三维地质填图过程中如何准确、快速地构建三维断层模型是其中的关键点及难点。通过对数字填图过程不同阶段数据源的分析,详细分析了实际材料图建立断层数据以及与野外路线数据的关系映射规则,提出并实现了由线及面的断层模型构建方法。该方法强调断层模型构建与业务流程的一致性、动态性和快速性,构建模型的数据源始于野外第一手资料,充分利用填图业务过程中不同阶段数据的关联、约束与继承关系,能够满足在填图过程中根据地质认识的深入快速、动态地重构模型的要求,同时也可根据直观的三维断层模型时时验证地质连图的合理性。算法已在实际野外三维地质填图工作进行了多次实验,获得较好的成果。实验说明,基于实际材料图的三维断层模型构建方法与实际业务过程同步,具有操作便捷性,可直接应用于三维地质填图的实际工作要求。     

2017年8月9日精河6.6级地震烈度分布与房屋震害特征分析

通过对2017年8月9日精河6.6级地震灾区内共计355个调查点的实地调查,确定了此次地震的烈度分布。灾区最高烈度为Ⅷ度（8度）,灾区面积15623km²,灾区总人口487696人,其中,受灾人口133695人,地震共造成36人受伤;对各烈度区内不同结构类型房屋的震害现象进行了整理,分析了不同结构类型房屋的抗震能力与震害原因,结果显示,土木结构房屋倒塌及屋檐塌落是导致人员受伤的主要原因;砖木结构房屋缺乏抗震设施,破坏形式多样;砖混结构房屋在高烈度区破坏较重;框架结构房屋主体完好但填充墙普遍出现破坏。安居富民房屋抗震性能良好。     

方解石脉双晶纹方法在工程勘察中的应用

在工程区基岩被第四纪土、江水等覆盖的情况下，如何充分利用好获得的钻孔岩芯来分析断层的发育和活动性情况就显得非常重要。为此，地基勘察中引入一种显微构造分析方法，即方解石脉双晶纹分析方法。方解石脉双晶纹能解决断层的活动期次、每一期次的强度、断层应力场、断层性质、断层活动时的环境条件和最后一次活动的时代等问题。由于方解石脉双晶纹发育的广泛性，使之具有推广价值。